Review on research progress of high purity vanadium pentoxide preparation by chlorination process

Li Zhuochen; Du Guangchao; Fan Chuanlin; Zhu Qingshan

doi:10.7513/j.issn.1004-7638.2021.01.002

Volume 42 Issue 1

Feb. 2021

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Li Zhuochen, Du Guangchao, Fan Chuanlin, Zhu Qingshan. Review on research progress of high purity vanadium pentoxide preparation by chlorination process[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(1): 8-15, 92. doi: 10.7513/j.issn.1004-7638.2021.01.002

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Li Zhuochen, Du Guangchao, Fan Chuanlin, Zhu Qingshan. Review on research progress of high purity vanadium pentoxide preparation by chlorination process[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(1): 8-15, 92. doi: 10.7513/j.issn.1004-7638.2021.01.002

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Review on research progress of high purity vanadium pentoxide preparation by chlorination process

doi: 10.7513/j.issn.1004-7638.2021.01.002

Li Zhuochen^{1, 2
,},
Du Guangchao^{1, 2},
Fan Chuanlin^{1
,
,},
Zhu Qingshan^{1, 2}

1.
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 2020-12-18
Publish Date: 2021-02-10

Abstract

Abstract

As a crucial raw material for all-vanadium redox flow battery(VRFB), the high purity vanadium pentoxide (V₂O₅) is under an increasingly urgent demand with the rapid development of VRFB in recent years. Based on this background, a plenty of processes have been proposed for high purity V₂O₅ preparation, among which the chlorination process is paid more and more attentions due to the remarkable advantages of high efficiency, favorable selectivity, high purity of products and eco-friendly feature. In this paper, we reviewed the research progress with relevant literatures concentrated on the three key procedures of high purity V₂O₅ preparation via chlorination process, including thermodynamics, kinetics and processes of chlorination of raw materials, purification of crude vanadium oxytrichloride (VOCl₃) and conversion of VOCl₃ into V₂O₅. The high-efficient utilization of secondary vanadium resources, the selective hydrolysis of crude vanadium oxychloride to remove TiCl₄ and conversion of VOCl₃ into V₂O₅ by catalytic oxidation are proposed as the development trends of the corresponding key procedures. Finally, carrying out the pilot test and developing the key equipment for preparing high-purity vanadium pentoxide by chlorination process are the key and difficult points for realizing the industrial production in the future.
- high purity vanadium pentoxide,
- chlorination process,
- vanadium oxytrichloride,
- purification,
- fluidization

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References(33)

References

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