Ce对低碳高强度钢液夹杂物变性的研究

贺磊; 侯阳; 原春阳; 郭清理; 王社斌

doi:10.7513/j.issn.1004-7638.2013.03.014

Ce对低碳高强度钢液夹杂物变性的研究

doi: 10.7513/j.issn.1004-7638.2013.03.014

1. 太原理工大学材料科学与工程学院, 山西太原 030024;
2. 太原理工大学工程训练中心, 山西太原 030024;
3. 新材料界面科学与工程教育部重点实验室, 山西太原 030024

基金项目:

国家自然科学基金资助项目（No．51101110）。

详细信息

作者简介:
贺磊(1987-),男,浙江宁波人,硕士,主要从事钢铁洁净化的理论研究。

中图分类号: TG142.3,TF704.7
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出版历程
- 收稿日期: 2013-03-01
- 网络出版日期: 2023-12-04

Effect of Ce on the Purifying Degree and Inclusion modification of Low Carbon and High-Strength Steel

1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
2. Engineering Training Center, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;
3. Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan 030024, Shanxi, China

摘要

摘要: 用真空感应炉在800 Pa的Ar气氛中把3.0 kg工业纯铁与合金元素熔化，在1 873 K加入Ce元素精炼10min，制备4种0.08C-0.6Si-0.45Mn-0.3Cu-0.09P-xCe的钢样。用化学成分、SEM和EDS表征结果，研究该体系中洁净度和夹杂物的变化。结果表明[Ce]为0时，夹杂物为MnS-MgO-Al₂O₃系；[Ce]为0.008%～0.020%时，夹杂物为MgO-Al₂O₃-Ce₂O₂S系；[Ce]为0.043%时，夹杂物为FePCe-Ce₂O₃系，且把7μm以上形状不规则的夹杂物变为2μm球状，甚至转变为0.3μm以下的球形夹杂物，钢材基体上夹杂物残留面积减少58.1%，且尺度均小于3μm。钢液深度净化的原因是，Ce脱O、S后生成的夹杂物上浮、排除，不同类型夹杂物的成因与其形成的热力学条件相关。
- 低碳高强度钢 /
- Ce /
- 真空精炼 /
- 净化钢液 /
- 洁净度 /
- 夹杂物变性
Abstract: In order to improve the refining process of low carbon and high-strength container plates,four steel samples were prepared by adding Ce into the molten steel containing 0.08C-0.60Si-0.45Mn-0.3Cu-0.09P(mass%) at 1 873 K in a 3.0 kg vacuum induction furnace under Ar atmosphere(800 Pa).The chemical composition,SEM and EDS analytic results were obtained to study the cleanliness of 0.08C-0.60Si-0.45Mn-0.3Cu-0.09P-xCe(mass%)steel and the change of inclusions.When content was 0,the inclusions were MnS-MgO-Al₂O₃ system;when content was in the range of 0.008%~0.020%,the inclusions were MgO-Al₂O₃-Ce₂₂O₃>O₂S system;when content was 0.043%,the inclusions became FePCe-Ce₂₂O₃>O₂S system and spherical inclusions of 2 μm or even smaller than 0.3 μm were transformed from 7 μm inclusions with irregular shape.The residual area of inclusions in the steel matrix was reduced by 58.1% and the size of inclusions was below 3 μm approximately.The liquid steel was cleaned profoundly due to the floating up and removal of inclusions which were formed by Ce deoxidation and desulfuration.The formation of different kinds of inclusions was relevant to the relative thermodynamic conditions.
- low carbon and high strength steel /
- element Ce /
- vacuum refining /
- lcleaning of molten steel /
- cleanliness /
- modification of inclusions