Effect of Bath Temperature on Ni-Sn-Mn Alloy Coating Prepared by Pulse Electrodeposition
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摘要: 为了提高低碳钢在海洋环境下的耐蚀性, 采用脉冲电沉积法在Q235钢表面制备了Ni-Sn-Mn合金镀层。利用辉光放电光谱仪 (GDS) 、扫描电子显微镜 (SEM) 、Tafel极化曲线和电化学阻抗谱 (EIS) 考察了镀液温度对镀层元素含量、表面形貌、沉积速率、阴极电流效率和耐蚀性的影响。结果表明:随镀液温度的升高, 镀层Ni和Sn含量先降低后提高, Mn含量先增加后减少;沉积速率和阴极电流效率提高, 镀层耐蚀性先增强后减弱。镀液温度为30℃时, 所制备的Ni-Sn-Mn镀层均匀致密, 在3.5%NaCl电解液中具有最正的自腐蚀电位 (-0.374 V), 最低的自腐蚀电流密度 (4.266×10-8A·cm-2) 和最大的电荷转移电阻 (7 459Ω·cm2), 耐蚀性性最好。
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关键词:
- 低碳钢 /
- Ni-Sn-Mn合金镀层 /
- 脉冲电沉积 /
- 镀液温度 /
- 耐蚀性
Abstract: In order to improve the corrosion resistance of mild steel in marine environment,Ni-Sn-Mn alloy coatings were prepared on the surface of Q235 steel by pulse electrodeposition.The effect of bath temperature on coating element content,surface morphology,deposition rate,cathode current efficiency and corrosion resistance was investigated by glow discharge spectroscopy (GDS),scanning electron microscopy (SEM),Tafel curve and electrochemical impedance spectroscopy (EIS).The results showed that with the increasing bath temperature,the content of Ni and Sn decreased at first and then increased,while the content of Mn raised firstly and then dropped; coating deposition rate and cathode current efficiency increased; corrosion resistance of coatings strengthened firstly and then weakened. The coating prepared at the bath temperature of 30 ℃ was uniform and compact,and had the biggest corrosion potential(-0.374 V),the smallest corrosion current density(4.266×10-8 A·cm-2),the biggest charge transfer resistance(7 459 Ω·cm2) and exhibited the best corrosion resistance in 3.5% NaCl solution.
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