Effect of Potassium Hydroxide on Calcination of Metatitanic Acid
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摘要: 向偏钛酸中添加一定量的氢氧化钾,研究煅烧过程中钾盐对金红石转化率、平均粒径、样品形貌及晶体结构的影响,采用拉曼光谱仪、马尔文粒度仪和XRD对样品进行了表征。结果表明:偏钛酸中添加氢氧化钾的样品与空白样相比,金红石晶型转化率达到99%以上的温度由850℃提高至1 000℃,降低了锐钛晶型向金红石晶型转换的速度。氢氧化钾在偏钛酸煅烧过程中抑制了粒子的生长,较好地调整了晶粒结构避免了高温下颗粒烧结。添加氢氧化钾后金红石含量大于99%的样品晶胞参数a、b、c值与标准结构一样,氢氧化钾对晶胞参数无影响。Abstract: Potassium hydroxide was added into metatitanic acid during the calcination process,which aimed to study the effect of potassium salt on the rutile conversion,average particle size,morphology and crystal structure of the samples employing Raman spectroscopy,particle size analyzer and XRD characterizations.Compared with the blank sample,the temperature corresponding to over 99% of rutile conversion rate increased from 850 to 1 000 ℃,indicating a decrease in transition rate for anatase to rutile.The growth of grains during calcination of metatitanic acid was inhibited by potassium hydroxide,resulting in a well adjustment of the products’ crystal structure and avoiding the sintering at high temperature.The cell parameters a,b and c for the samples having more than 99% of rutile content with potassium hydroxide added,keep consistent with those of the standard structure,suggesting that the potassium hydroxide has no influence on the cell parameters of the products.
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Key words:
- titanium dioxide /
- metatitanic acid /
- calcination /
- potassium hydroxide /
- rutile
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