VO<sub>2</sub>(M)粉体合成研究进展

张堃; 梅晶; 王丹; 蒋鹏; 袁新强; 张伟

doi:10.7513/j.issn.1004-7638.2021.02.004

VO₂(M)粉体合成研究进展

doi: 10.7513/j.issn.1004-7638.2021.02.004

张堃^1,,
梅晶¹,
王丹¹,
蒋鹏^{1, 2},
袁新强^{1, 2, ,},
张伟¹

1.
陕西理工大学材料科学与工程学院，陕西汉中 723000
2.
矿渣综合利用环保技术国家地方联合工程实验室，陕西汉中 723000

基金项目: 陕西省重大科技创新项目专项(2017ZKC04-84)；矿渣综合利用环保技术国家地方联合工程实验室开放课题(SLGPT2019KF01-06)；陕西理工大学基金项目(SLG1810)

详细信息

作者简介:
张堃(1997—)，女，陕西咸阳人，硕士研究生，主要从事VO₂(M)粉体制备研究，Email：1357956617@qq.com

通讯作者:
袁新强(1981—)，男，副教授，主要从事高分子材料改性及应用研究，Email：yxq_hb@126.com

中图分类号: TF841.3
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- 文章访问数: 577
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- 被引次数: 0
出版历程
- 收稿日期: 2020-10-13
- 刊出日期: 2021-04-10

Review of progress in synthesis of M phase VO₂ powders

Zhang Kun^1
,,
Mei Jing¹,
Wang Dan¹,
Jiang Peng^{1, 2},
Yuan Xinqiang^{1, 2
, ,},
Zhang Wei¹

1.
School of Materials Science and Engineering, Shanxi University of Technology, Hanzhong 723000, Shanxi, China
2.
National and Local Joint Engineering Laboratory for Slag Comprehensive Utilization and Environmental Technology, Hanzhong 723000, Shanxi, China

摘要

摘要: 二氧化钒(VO₂)是一种具有半导体-金属相变特性的金属氧化物，在68 ℃条件下，具有红外光透过率/反射率等的突变性能。采用钨、氟等元素进行单元素、多元素掺杂，可有效降低VO₂(M)相变温度，进而开发出具有室温相变特性的VO₂(M)，大幅提高其在智能窗领域的应用价值。综述了以五氧化二钒(V₂O₅)为钒源，VO₂(M)和掺杂VO₂(M)粉体合成研究进展，比较不同合成方法的优缺点，分析其在智能有机玻璃中应用的可行性与前景。
- VO₂(M) /
- V₂O₅ /
- 粉体合成 /
- 有机玻璃 /
- 智能隔热
Abstract: Vanadium dioxide (VO₂) has the semiconductor-metal phase transition characteristics. It has the mutation property of infrared light transmittance/reflectivity at 68 ℃. Using tungsten, fluorine and other elements for single element or multi-element doping can effectively reduce the phase transition temperature of VO₂(M), and VO₂(M) with room temperature phase transition feature can be developed, which can greatly broaden its application in the intelligent windows. The progress in synthesis of VO₂(M) and doped VO₂(M) powders from vanadium pentoxide (V₂O₅) was reviewed, the advantages and disadvantages of different synthesis methods were compared, and the feasibility and prospect of their application in smart plexiglass were analyzed.
- VO₂(M) /
- V₂O₅ /
- powder synthesis /
- plexiglass /
- smart thermal insulation

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参考文献(48)

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