酸性钒溶液中锰的脱除研究进展

张菊花; 梁月; 常雨微; 惠旭杰

doi:10.7513/j.issn.1004-7638.2022.01.004

酸性钒溶液中锰的脱除研究进展

doi: 10.7513/j.issn.1004-7638.2022.01.004

张菊花^{1, 2, 3,},
梁月^{1, 2, 3},
常雨微^{1, 2, 3},
惠旭杰^{1, 2, 3}

1.
武汉科技大学, 钢铁冶金及资源利用省部共建教育部重点实验室, 湖北武汉430081
2.
武汉科技大学, 省部共建耐火材料与冶金国家重点实验室, 湖北武汉430081
3.
武汉科技大学材料与冶金学院, 湖北武汉430081

基金项目: 国家自然科学基金青年基金(编号：51804230，51804228)；校青年科技骨干培育计划项目(编号：2017xz003)。

详细信息

作者简介:
张菊花（1985—），女，山西忻州人，副教授，研究方向为有色金属冶金，E-mail：zhangjuhua@wust.edu.cn

中图分类号: TF841.3
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- 被引次数: 0
出版历程
- 收稿日期: 2021-09-07
- 网络出版日期: 2022-04-24
- 刊出日期: 2022-02-28

Research progress on removal of manganese from acidic vanadium solution

Zhang Juhua^{1, 2, 3
,},
Liang Yue^{1, 2, 3},
Chang Yuwei^{1, 2, 3},
Hui Xujie^{1, 2, 3}

1.
Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China
2.
State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China
3.
School of Materials and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China

摘要

摘要: 钙化焙烧-酸浸是一种极具应用前景的清洁提钒工艺，但是所得酸性含钒溶液中锰的含量较高，严重影响钒产品的品质及其应用，因此,对酸性钒溶液中锰的脱除研究亟不可待。对近年来国内外不同溶液体系以及酸性钒溶液中锰的去除进行了综述，阐明了不同溶液锰的去除方法的原理、脱除条件以及除锰效果，并对酸性钒溶液中杂质锰的脱除方法进行了探讨，为高效、高选择性、低成本脱除酸性含钒溶液中的杂质锰提供理论和技术指导。基于酸性含钒溶液体系对除锰剂及除锰方法选择的具体要求，在理论上过硫酸铵氧化法、萃取法和离子交换法适用于该体系中杂质锰的脱除，但具体脱除效果、操作条件和作用机理需进一步研究。
- 提钒 /
- 酸性含钒溶液 /
- 除锰 /
- 化学沉淀 /
- 萃取 /
- 离子交换
Abstract: Calcification roasting-acid immersion is a very promising clean process for vanadium extraction, but the resultant acidic vanadium solution contains a higher content of manganese, which seriously affects the quality and application of vanadium products. Thus the removal of manganese from the acidic vanadium solution is urgently needed. This paper summarized the removal of manganese from different solution systems at home and abroad. The principles, operational conditions and efficiency of removing manganese from different solutions were expounded and the feasibility for removal of manganese from the acidic vanadium solution via different methods were discussed, which will provide a theoretical and technical guidance for removal of impurity manganese in acidic vanadium solution with high efficiency, high selectivity and low cost. Based on the specific requirements for selecting remover and methods to remove the manganese from the acidic vanadium solution, ammonium persulfate oxidation method, solvent extraction method and ion exchange method are theoretically suitable for removing impurity manganese from this solution system. However, the specific removing efficiency, operational conditions and acting mechanism need to be further studied.
- vanadium extraction /
- acidic vanadium solution /
- manganese removal /
- chemical precipitation /
- solvent extraction /
- ion exchange

HTML全文

图 1 25 ℃和100 ℃下的Mn-H₂O系E-pH关系

Figure 1. E-pH graph for Mn-H₂O system at 25 ℃ and 100 ℃

[Mn]= 1 mol/kg，100 kPa

下载: 全尺寸图片幻灯片

图 2 25 ℃下Me-H₂O系E-pH关系

Me=Ni、Co和Zn，[Me]= 1 mol/kg，100 kPa

Figure 2. E-pH graph for Me-H₂O system at 25 ℃

下载: 全尺寸图片幻灯片

图 3 25、55 ℃和100 ℃下的V-H₂O系E-pH关系

Figure 3. E-pH diagram for V-H₂O system at 25, 55 ℃ and 100 ℃

[V] =1 mol/kg, 100 kPa

下载: 全尺寸图片幻灯片

表 1 不同酸度水溶液中锰的吸附回收率

Table 1. Sorption recovery of manganese (II) from aqueous solutions with different acidity

离子交换树脂	试验类型	回收率/%	log D
KB-2D (DVB)	A	82 ± 5	3.82 ± 0.23
KB-2D (DVB)	B	78 ± 4	3.75 ± 0.22
KB-2M (DVEDEG)	A	～100	4.26 ± 0.26
KB-2M (DVEDEG)	B	～100	4.22 ± 0.25
KB-2M (DVETEG)	A	92 ± 5	4.02 ± 0.24
KB-2M (DVETEG)	B	90 ± 5	3.98 ± 0.19
KB-2M (DVEPG)	A	93 ± 5	4.11 ± 0.21
KB-2M (DVEPG)	B	90 ± 5	4.06 ± 0.24
KB-2T (TVEPE)	A	～100	4.25 ± 0.21
KB-2T (TVEPE)	B	～100	4.22 ± 0.25
KB-2S (DVS)	A	94 ± 5	4.07 ± 0.21
KB-2S (DVS)	B	92 ± 5	4.01 ± 0.19
注：其中，A代表Mn (II) + 0.001 M HCl; B代表Mn(II) + 0.5 M HCl。D=$ \dfrac{{EC}}{{C_{{\rm{eq}}}}} $（EC为树脂与锰的交换容量；C_eq为Mn(II)的平衡摩尔浓度); logD为离子交换平衡常数。

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