二氧化钛在油墨中的应用性能研究

于耀杰; 宋悦; 董仕顺; 任秀莲; 魏琦峰

doi:10.7513/j.issn.1004-7638.2022.03.011

二氧化钛在油墨中的应用性能研究

doi: 10.7513/j.issn.1004-7638.2022.03.011

哈尔滨工业大学(威海)海洋科学与技术学院, 山东威海 264200

基金项目: 山东省重点研发计划(2017CXGC1002)。

详细信息

作者简介:
于耀杰（1988—），男，硕士研究生，主要研究方向为分离科学与技术及资源综合利用，E-mail: 5134659@qq.com

通讯作者:
魏琦峰，教授，博士生导师，研究方向为分离科学与技术及资源综合利用，E-mail: weiqifeng163@163.com

中图分类号: TF823
计量
- 文章访问数: 344
- HTML全文浏览量: 56
- PDF下载量: 39
- 被引次数: 0
出版历程
- 收稿日期: 2022-01-14
- 刊出日期: 2022-06-30

Research on application performance of titanium dioxide in ink

College of Marine Science and Technology, Harbin Institute of Technology, Weihai 264200, Shandong, China

摘要

摘要: 对二氧化钛在油墨中的应用性能进行了研究，通过对二氧化钛粗品进行不同条件的研磨分散、无机包覆处理，并进行颜料性能及油墨应用性能研究测试，总结归纳出适宜油墨应用的高遮盖力二氧化钛制备方案。其最佳工艺为：在浆料浓度为500 g/L条件下，研磨分散40 min，并进行氧化硅和氧化铝无机包覆，得到样品的二氧化钛含量达90.23%，L值为95.61，b值为1.82，油墨中的遮盖力达到最大值，具备最佳的油墨应用效果。
- 二氧化钛 /
- 油墨 /
- 遮盖力 /
- 研磨 /
- 分散 /
- 无机包覆
Abstract: In this paper, the application performance of titanium dioxide in ink was studied. Through the process of grinding, dispersing and inorganic coating of titanium dioxide crude products under different conditions, the study of pigment performance and application performance of ink was carried out, the preparation method of high hiding power titanium dioxide suitable for ink application was also summarized. The optimum technological conditions were obtained as follows: when the slurry concentration is 500 g/L, 40 min is ground and dispersed, and SiO₂-Al₂O₃ inorganic coating is carried out. The titanium dioxide content of the sample is 90.23%, L value is 95.61, b value is 1.82, the hiding power in the ink reaches the maximum, and has the best ink application effect.
- titanium dioxide /
- ink /
- hiding power /
- grinding /
- dispersing /
- inorganic coating

HTML全文

图 1 L 值、TCS 值随研磨时间变化曲线

Figure 1. L value and TCS value change curves with grinding time

下载: 全尺寸图片幻灯片

图 2 b 值、SCX 值随研磨时间变化曲线

Figure 2. b value and SCX value change curves with grinding time

下载: 全尺寸图片幻灯片

图 3 不同砂磨时间浆料粘度和筛余物的变化

Figure 3. Change of slurry viscosity and sieve residue at different grinding time

下载: 全尺寸图片幻灯片

图 4 不同砂磨时间浆料的粒径分布

Figure 4. Particle size distribution of slurry at different grinding time

下载: 全尺寸图片幻灯片

图 5 二氧化钛含量与吸油量对比

Figure 5. Comparison of titanium dioxide content and oil absorption figure

下载: 全尺寸图片幻灯片

图 6 遮盖力与总钛关系

Figure 6. Relationship between covering power and total titanium

下载: 全尺寸图片幻灯片

图 7 6^#样品TEM形貌

Figure 7. TEM of sample 6^#

下载: 全尺寸图片幻灯片

表 1 试验参考设备清单

Table 1. Experimental reference equipment list

设备名称	规格型号	生产厂家
实验室pH计	梅特勒-托利多FE20	梅特勒-托利多仪器
实验室电导率仪	梅特勒-托利多FE30	梅特勒-托利多仪器
分析天平	AL204	梅特勒-托利多仪器
RK打样机	KPP印刷验证机	RK公司
XRITE分光光度计	SP62	美国爱色丽公司
平磨仪	PM240-2	广西梧州市润训宝石机械厂
扫描电镜	JSM-5600 LV	日本电子光学公司
325目筛网	75 mm	顺兴化学试剂公司
600目筛网	75 mm	顺兴化学试剂公司
光泽度计	BGD516-3	广州标格达仪器有限公司
粘度杯	3^#	日本东洋rigosha
秒表	RESEE	RESEE生产
数显粘度计	NDJ-5S/8S	上海平轩科学仪器有限公司
粉碎机	nn-8000	上海比朗仪器有限公司
实验室砂磨机	VSM	无锡新光粉体
粒度仪	马尔文2000	英国马尔文
汽粉机	YQ50	上海塞山粉体机械制造有限公司
色差仪	Labscan XE	Hunter
XRF	TIGER-S8	德国布鲁克

下载: 导出CSV

表 2 无机包覆后组分含量及吸油量

Table 2. Content and oil absorption after inorganic coating

序号	w/%				吸油量（100 g）/g
序号	Al₂O₃	SiO₂	P₂O₅	TiO₂	吸油量（100 g）/g
1^#	1.1903	0.2619	0.1825	98.0366	16.2
2^#	3.0846	0.4637	0.1973	95.7897	18.5
3^#	2.1105	0.3528	0.1746	96.9831	17.6
4^#	3.8166	1.8577	0.1915	93.5388	20.1
5^#	3.4523	0.2871	0.1856	95.3974	19.3
6^#	3.6592	5.3619	0.1944	90.2327	21.3
7^#	2.7684	2.8417	0.1555	93.6834	20.8

下载: 导出CSV

表 3 颜料和聚氨酯油墨遮盖力指标

Table 3. Index of pigment and polyurethane ink covering power

序号	L	a	b	TCS	遮盖力/%	总钛/%
1^#	95.14	−1.11	1.85	2 030	57.3	98.0366
2^#	95.60	−1.14	1.75	2 057	58.5	95.7897
3^#	95.4	−1.08	1.81	2 045	57.9	96.9831
4^#	95.59	−1.12	1.79	2 058	58.9	93.5388
5^#	95.63	−1.08	1.74	2 006	58.2	95.3974
6^#	95.61	−1.11	1.82	2 023	59.7	90.2327
7^#	95.61	−1.10	1.77	2 003	58.4	93.6834

下载: 导出CSV

参考文献(21)

[1]	Lou Xiaojie. Production and application of titanium dioxide[J]. Chemical Enterprise Management, 2020,28:111−112. (娄晓杰. 钛白粉的生产及应用现状[J]. 化工管理, 2020,28:111−112. doi: 10.3969/j.issn.1008-4800.2020.13.063 Lou Xiaojie. Production and application of titanium dioxide [J]. Chemical Enterprise Management, 2020, 28 : 111-112. doi: 10.3969/j.issn.1008-4800.2020.13.063
[2]	Zhang Xiuzhen, Jiang Wenchuan, Lu Wei, et al. Development of preparation technology of rutile titanium dioxide with low oil absorption[J]. Chemical Engineering Design Communications, 2020,46(6):167−168,176. (张修臻, 姜文川, 鲁伟, 等. 低吸油量金红石钛白粉制备技术的研发[J]. 化工设计通讯, 2020,46(6):167−168,176. doi: 10.3969/j.issn.1003-6490.2020.06.106 Zhang Xiuzhen, Jiang Wenchuan, Lu Wei, et al. Development of preparation technology of rutile titanium dioxide with low oil absorption[J]. Chemical Engineering Design Communications, 2020, 46(6) : 167-168, 176. doi: 10.3969/j.issn.1003-6490.2020.06.106
[3]	Bi Sheng. Status of titanium dioxide industry in China and the development prospect[J]. Iron Steel Vanadium Titanium, 2021,42(5):99−108. (毕胜. 近年中国钛白粉行业基本状况及发展展望[J]. 钢铁钒钛, 2021,42(5):99−108. doi: 10.7513/j.issn.1004-7638.2021.05.016 Bi Sheng. Status of titanium dioxide industry in China and the development prospect[J]. Iron Steel Vanadium Titanium, 2021, 42(5): 99-108. doi: 10.7513/j.issn.1004-7638.2021.05.016
[4]	Zhang Wensheng, Zhu Zhaowu, Cheng Chuyong. A literature review of titanium metallurgical processes[J]. Hydrometallurgy, 2011,108(3-4):177−188. doi: 10.1016/j.hydromet.2011.04.005
[5]	Wang Yongshan. Research on the role of titanium dioxide in ink formulation[J]. Chemical Engineering Design Communications, 2021,47(2):67−68. (王永珊. 钛白粉在油墨配方中的作用[J]. 化工设计通讯, 2021,47(2):67−68. Wang Yongshan. Research on the role of titanium dioxide in ink formulation[J]. Chemical Engineering Design Communications, 2021, 47(2): 67-68.
[6]	邓捷, 吴立峰. 钛白粉应用手册[M]. 北京: 化学工业出版社, 2005. Deng Jie, Wu Lifeng. Titanium dioxide application manual[M]. Beijing: Chemical Industry Press, 2005.
[7]	Liu Y, Zhang Y, Ge C, et al. Evolution mechanism of alumina coating layer on rutile TiO₂ powders and the pigmentary properties[J]. Applied Surface Science, 2009,255(16):7427−7433. doi: 10.1016/j.apsusc.2009.04.013
[8]	Sun Zheyu, Xia Yuan, Zhou Lei, et al. Current status and development of China's titanium dioxide industry in 2020[J]. Coating and Protection, 2021,42(9):56−62. (孙哲宇, 夏渊, 周磊, 等. 2020年中国钛白粉行业发展现状分析[J]. 涂层与防护, 2021,42(9):56−62. Sun Zheyu, Xia Yuan, Zhou Lei, et al. Current status and development of China's titanium dioxide industry in 2020[J]. Coating and Protection, 2021, 42(9) : 56-62.
[9]	Shang Yumei. Brief development status of ink industry in China[J]. Printing Technology, 2019,(6):50−51. (尚玉梅. 简述我国油墨行业发展现状[J]. 印刷技术, 2019,(6):50−51. doi: 10.3969/j.issn.1003-1960.2019.06.014 Shang Yumei. Brief development status of ink industry in China[J]. Printing Technology, 2019 (6): 50-51. doi: 10.3969/j.issn.1003-1960.2019.06.014
[10]	Zhang Xiuzhen, Zhu Shizhong, Ma Zhengcheng, et al. Application of titanium dioxide in ink formulation[J]. China Petroleum and Chemical Standard and Quality, 2019,39(20):159−161. (张修臻, 朱士中, 马征程, 等. 钛白粉在油墨配方中的作用[J]. 中国石油和化工标准与质量, 2019,39(20):159−161. Zhang Xiuzhen, Zhu Shizhong, Ma Zhengcheng, et al. Application of titanium dioxide in ink formulation [J]. China Petroleum and Chemical Standard and Quality, 2019, 39(20): 159-161.
[11]	Zhang Benfa. Application of hydrophilic titanium dioxide in water based ink[J]. Petrochemical Industry Technology, 2016,23(11):30−33. (张本发. 亲水型钛白粉在水性油墨中的应用[J]. 石化技术, 2016,23(11):30−33. doi: 10.3969/j.issn.1006-0235.2016.11.016 Zhang Benfa. Application of hydrophilic titanium dioxide in water based ink[J]. Petrochemical Industry Technology, 2016, 23(11): 30-33. doi: 10.3969/j.issn.1006-0235.2016.11.016
[12]	陈晓英. 凹版塑料油墨的现状及发展趋势[J]. 广东印刷, 2020 (5): 49-51. Chen Xiaoying. Present situation and development trend of gravure plastic ink[J]. Guangdong Print, 2020 (5): 49-51.
[13]	Yang Sen. Talk about the application of environmental protection ink in green cigarette packs[J]. Technology Wind, 2016,(2):97−97. (杨森. 浅谈环保油墨在绿色烟包中的应用[J]. 科技风, 2016,(2):97−97. doi: 10.3969/j.issn.1671-7341.2016.02.083 Yang Sen. Talk about the application of environmental protection ink in green cigarette packs[J]. Technology Wind, 2016 (2): 97-97. doi: 10.3969/j.issn.1671-7341.2016.02.083
[14]	石晶. 凹版印刷白色油墨性能研究[D]. 西安: 西安理工大学, 2018. Shi Jing. Study on properties of white ink for gravure printing[D]. Xi^,an: Xi’an University of Technology, 2018.
[15]	Xu Q, Zhao J, Xu H, et al. Dispersion of TiO₂ particles and preparation of SiO₂ coating layers on the surfaces of TiO₂[J]. Materials Research Innovations, 2015,19(S5):142−145.
[16]	Dong Xiongbo, Zhang Xiangwei, Liu Xiaorui, et al. Progress and development trend of inorganic coated titanium powder[J]. Inorganic Chemicals Industry, 2020,52(10):30−36. (董雄波, 张祥伟, 刘晓瑞, 等. 无机包覆钛白粉研究进展及发展趋势[J]. 无机盐工业, 2020,52(10):30−36. doi: 10.11962/1006-4990.2020-0494 Dong Xiongbo, Zhang Xiangwei, Liu Xiaorui, et al. Progress and development trend of inorganic coated titanium powder[J]. Inorganic Chemicals Industry, 2020, 52(10): 30-36. doi: 10.11962/1006-4990.2020-0494
[17]	Li Qin, Hu Hongfei, Hou Shengdong, et al. Research on quality of coating compact SiO₂ film on the surface of TiO₂[J]. Iron Steel Vanadium Titanium, 2008,29(1):48−53. (李琴, 胡鸿飞, 侯盛东, 等. TiO₂表面包覆致密SiO₂包膜量的研究[J]. 钢铁钒钛, 2008,29(1):48−53. doi: 10.7513/j.issn.1004-7638.2008.01.010 Li Qin, Hu Hongfei, Hou Shengdongi, et al. Research on quality of coating compact SiO₂ film on the surface of TiO₂[J]. Iron Steel Vanadium Titanium, 2008, 29(1): 48-53. doi: 10.7513/j.issn.1004-7638.2008.01.010
[18]	Zhang Ruhui, Zhou Dali, Jiang Fengzhou, et al. Structure characteristics of hydrated alumina coated on titanium dioxide and its effect on water dispersibility of titanium dioxide[J]. Iron Steel Vanadium Titanium, 2016,37(3):35−40,47. (张茹慧, 周大莉, 蒋凤舟, 等. 钛白粉铝包膜的结构特性及对水分散性的影响[J]. 钢铁钒钛, 2016,37(3):35−40,47. doi: 10.7513/j.issn.1004-7638.2016.03.007 Zhang Ruhui, Zhou Dali, Jiang Fengzhou, et al. Structure characteristics of hydrated alumina coated on titanium dioxide and its effect on water dispersibility of titanium dioxide[J]. Iron Steel Vanadium Titanium, 2016, 37(3): 35-40, 47. doi: 10.7513/j.issn.1004-7638.2016.03.007
[19]	Yu Yaojie. Abrasive properties of titanium dioxide crude on finished products performance impact[J]. China Petroleum and Chemical Standard and Quality, 2020,40(22):21−23. (于耀杰. 钛白粉粗品的可研磨性能对成品性能的影响[J]. 中国石油和化工标准与质量, 2020,40(22):21−23. doi: 10.3969/j.issn.1673-4076.2020.22.008 Yu Yaojie. Abrasive properties of titanium dioxide crude on finished products performance impact [J]. China Petroleum and Chemical Standard and Quality, 2020, 40(22): 21-23. doi: 10.3969/j.issn.1673-4076.2020.22.008
[20]	GB/T1706—2006. 二氧化钛颜料[S]. GB/T1706-2006. Titanium dioxide pigment[S].
[21]	Hu Zhongyuan, Zou Peng, Luo Xianping, et al. Design thoughts of low-grade interior wall latex coatings[J]. China Coatings, 2010,25(11):43−45. (胡中源, 邹鹏, 罗先平, 等. 低档内墙乳胶漆配方设计思路[J]. 中国涂料, 2010,25(11):43−45. doi: 10.3969/j.issn.1006-2556.2010.11.012 Hu Zhongyuan, Zou Peng, Luo Xianping, et al. Design thoughts of low-grade interior wall latex coatings [J]. China Coatings, 2010, 25(11): 43-45. doi: 10.3969/j.issn.1006-2556.2010.11.012