苯甲羟肟酸浮选钛铁矿的作用机理

杨招君; 王丰雨; 钟森林; 梁焘茂

doi:10.7513/j.issn.1004-7638.2022.04.004

苯甲羟肟酸浮选钛铁矿的作用机理

doi: 10.7513/j.issn.1004-7638.2022.04.004

杨招君^{1, 2, 3,},
王丰雨^{1, 2, 3, ,},
钟森林^{1, 2, 3},
梁焘茂^{1, 2, 3}

1.
广东省科学院资源利用与稀土开发研究所, 广东广州 510651
2.
稀有金属分离与综合利用国家重点实验室, 广东广州 510651
3.
广州粤有研矿物资源科技有限公司, 广东广州 510651

基金项目: 广东省科学院发展专项资金项目（2022GDASZH-2022010104）

详细信息

作者简介:
杨招君（1971—），女，工程师，主要从事矿物加工工程及资源综合利用方面的研究，E-mail：mimiyzj@163.com

通讯作者:
王丰雨（1978—），男，高级工程师，E-mail：gzwfy2007@163.com

中图分类号: TF823, TD924
计量
- 文章访问数: 98
- HTML全文浏览量: 19
- PDF下载量: 37
- 被引次数: 0
出版历程
- 收稿日期: 2022-06-07
- 刊出日期: 2022-09-14

Flotation mechanism of ilmenite with benzohydroxamic acid

Yang Zhaojun^{1, 2, 3
,},
Wang Fengyu^{1, 2, 3
, ,},
Zhong Senlin^{1, 2, 3},
Liang Taomao^{1, 2, 3}

1.
Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou 510651,Guangdong, China
2.
State Key Laboratory of Separation and Comprehensive Utilization of Rare Metal, Guangzhou 510651, Guangdong, China
3.
Guangzhou Yueyouyan Mineral Resources Technology Co., Ltd., Guangzhou 510651, Guangdong, China

摘要

摘要: 浮选是回收钛铁矿的有效手段，其中捕收剂起着关键作用。目前对钛铁矿捕收剂的研究主要集中在以油酸、羟肟酸等为代表的捕收剂方面，其中苯甲羟肟酸类捕收剂以其高选择性备受关注，但其在对钛铁矿的浮选作用机理方面的研究甚少。从钛铁矿界面性质研究出发，通过单矿物浮选试验、红外光谱、接触角及动电位测定解释了苯甲羟肟酸与钛铁矿的浮选作用机理。
- 钛铁矿 /
- 浮选 /
- 苯甲羟肟酸 /
- 作用机理
Abstract: Flotation is an effective means to recover ilmenite, in which collector plays a key role. At present, the research on ilmenite flotation collectors mainly focuses on the collectors including oleic acid and hydroxamic acid. Among them, benzohydroxamic acid based collectors have attracted much attention because of their high selectivity, however, there is little research on the flotation mechanism of ilmenite. Based on the study of the interface properties of ilmenite, the flotation mechanism of benzohydroxamic acid and ilmenite was revealed by means of single mineral flotation test, infrared spectroscopy, contact angle and potentiodynamic test.
- ilmenite /
- flotation /
- benzo hydroxamic acid /
- mechanism

HTML全文

图 1 pH值对钛铁矿回收率的影响

Figure 1. Effect of pH value on ilmenite recovery

下载: 全尺寸图片幻灯片

图 2 捕收剂BHA用量对回收率的影响

Figure 2. Effect of concentration of collector benzohydroxamic acid on recovery

下载: 全尺寸图片幻灯片

图 3 钛铁矿与BHA作用前后的红外光谱

Figure 3. Infrared spectra of ilmenite before and after interaction with benzohydroxamic acid

下载: 全尺寸图片幻灯片

图 4 BHA与钛铁矿作用前后的电位

Figure 4. Potential before and after interaction between benzohydroxamic acid and ilmenite

下载: 全尺寸图片幻灯片

图 5 不同条件下钛铁矿的接触角

(a)钛铁矿与BHA作用前；(b)钛铁矿与BHA作用后

Figure 5. Contact angle of ilmenite under different conditions

下载: 全尺寸图片幻灯片

表 1 钛铁矿的化学成分

Table 1. Chemical composition of ilmenite %

TiO₂ Fe₂O₃ FeO MgO MnO Al₂O₃ CaO SiO₂

51.8 5.82 35.94 4.77 0.13 0.44 0.25 0.85

下载: 导出CSV

参考文献(9)

[1]	Chong Xiaoxiao, Luan Wenlou, Wang Fengxiang, et al. Overview of global titanium resources status and titanium consumption trend in China[J]. Conservationand Utilization of Mineral Resources, 2020,40(2):162−170. (崇霄霄, 栾文楼, 王丰翔, 等. 全球钛资源现状概述及我国钛消费趋势[J]. 矿产保护与利用, 2020,40(2):162−170. doi: 10.13779/j.cnki.issn1001-0076.2020.02.021 Chong Xiaoxiao, Luan Wenlou, Wang Fengxiang, et al. Overview of global titanium resources status and titanium consumption trend in China [J]. Conservationand Utilization of Mineral Resources, 2020, 40(2): 162-170. doi: 10.13779/j.cnki.issn1001-0076.2020.02.021
[2]	Li Zheng, Chen Congxi. Development status of global titanium resources industry[J]. Acta Geoscientica Sinica, 2021,42(2):245−250. (李政, 陈从喜. 全球钛资源行业发展现状[J]. 地球学报, 2021,42(2):245−250. doi: 10.3975/cagsb.2020.102001 Li Zheng, Chen Congxi. Development status of global titanium resources industry[J]. Acta Geoscientica Sinica, 2021, 42(2): 245-250 doi: 10.3975/cagsb.2020.102001
[3]	Xiao Wei, Shao Yanhai, Yu Jiayi, et al. Research status and prospect of ilmenite flotation reagents[J]. Conservation and Utilization of Mineral Resources, 2021,41(5):160−167. (肖玮, 邵延海, 尉佳怡, 等. 钛铁矿浮选药剂研究现状及展望[J]. 矿产保护与利用, 2021,41(5):160−167. doi: 10.13779/j.cnki.issn1001-0076.2021.05.022 Xiao Wei, Shao Yanhai, Yu Jiayi, et al. Research status and prospect of ilmenite flotation reagents[J]. Conservation and Utilization of Mineral Resources, 2021, 41(5): 160-167 doi: 10.13779/j.cnki.issn1001-0076.2021.05.022
[4]	Hu Yuehua, Han Haisheng, Tian Mengjie, et al. The application of metal-coordinated complexes in the flotation of oxide minerals and fundamental research of the adsorption mechanism[J]. Conservation and Utilization of Mineral Resources, 2018,(1):42−47,53. (胡岳华, 韩海生, 田孟杰, 等. BHA铅金属有机配合物在氧化矿浮选中的作用机理及其应用[J]. 矿产保护与利用, 2018,(1):42−47,53. Hu Yuehua, Han Haisheng, Tian Mengjie, et al. The application of metal-coordinated complexes in the flotation of oxide minerals and fundamental research of the adsorption mechanism[J]. Conservation and Utilization of MineralResources, 2018(1): 42-47, 53
[5]	Zhang Chaofan, Yu Qingyao, Cao Yijun, et al. Research progress of ilmenite flotation reagents and their surface modification methods[J]. The Chinese Journal of Nonferrous Metals, 2021,31(12):3675−3689. (张超凡, 余青瑶, 曹亦俊, 等. 钛铁矿浮选药剂及其表面改性的研究进展[J]. 中国有色金属学报, 2021,31(12):3675−3689. doi: 10.11817/j.ysxb.1004.0609.2021-36616 Zhang Chaofan, Yu Qingyao, Cao Yijun, etal. Research progress of ilmenite flotation reagents and their surface modification methods[J]. The Chinese Journal of Nonferrous Metals, 2021, 31(12): 3675−3689. DOI: 10.11817/j.ysxb.1004.0609.2021-36616.
[6]	Xu Caili, Chi Ru'an, Lv Renliang, et al. Progress in flotation behavior of octyl hydroxamic acid[J]. Journal of Wuhan Institute of Technology, 2019,(6):566−572. (徐彩丽, 池汝安, 吕仁亮, 等. 辛基羟肟酸浮选行为的研究进展[J]. 武汉工程大学学报, 2019,(6):566−572. Xu Caili, Chi Ru'an, Lü Renliang, et al. Progress in flotation behavior of octyl hydroxamic acid[J]. Journal of Wuhan Institute of Technology, 2019(6): 566-572
[7]	Wang Jun, Cheng Hongwei, Zhao Hongbo, et al. Flotation behavior and mechanism of rutile in presence of sodium oleate[J]. The Chinese Journal of Nonferrous Metals, 2014,(3):820−825. (王军, 程宏伟, 赵红波, 等. 油酸钠作用下金红石的浮选行为及作用机理[J]. 中国有色金属学报, 2014,(3):820−825. doi: 10.19476/j.ysxb.1004.0609.2014.03.033 Wang Jun, Cheng Hongwei, Zhao Hongbo, etal. Flotation behavior and mechanism of rutile in presence of sodium oleate[J]. The Chinese Journal of Nonferrous Metals, 2014(3): 820-825. doi: 10.19476/j.ysxb.1004.0609.2014.03.033
[8]	Zhu Shiman, Li Yifei, Zhang Zheyi, et al. Flotation characteristics and mechanism of rutile with hydroxamic acid collectors[J]. Conservationand Utilization of Mineral Resources, 2021,41(4):59−63. (朱诗曼, 李怡霏, 张喆怡, 等. 羟肟酸类捕收剂浮选金红石特性及其机理[J]. 矿产保护与利用, 2021,41(4):59−63. doi: 10.13779/j.cnki.issn1001-0076.2021.04.007 Zhu Shiman, Li Yifei, Zhang Zheyi, et al. Flotation characteristics and mechanism of rutile with hydroxamic acid collectors[J]. Conservationand Utilization of Mineral Resources, 2021, 41(4): 59-63 doi: 10.13779/j.cnki.issn1001-0076.2021.04.007
[9]	GaoYude, Qiu Xianyang, Han Zhaoyuan. Flotation mechanism of scheelite with hydroxamic acid[J]. The Chinese Journal of Nonferrous Metals, 2015,(5):1339−1344. (高玉德, 邱显扬, 韩兆元. 羟肟酸浮选白钨矿的机理[J]. 中国有色金属学报, 2015,(5):1339−1344. doi: 10.19476/j.ysxb.1004.0609.2015.05.029 GaoYude, Qiu Xianyang, Han Zhaoyuan. Flotation mechanism of scheelite with hydroxamic acid[J]. The Chinese Journal of Nonferrous Metals, 2015(5): 1339-1344 doi: 10.19476/j.ysxb.1004.0609.2015.05.029