V<sub>2</sub>O<sub>5</sub>纳米纤维布的制备及其在电化学储能领域的研究进展

倪伟; 齐建玲; 樊河雲

doi:10.7513/j.issn.1004-7638.2022.05.010

V₂O₅纳米纤维布的制备及其在电化学储能领域的研究进展

doi: 10.7513/j.issn.1004-7638.2022.05.010

倪伟^{1, 2, ,},
齐建玲^{1, 2},
樊河雲^{1, 2}

1.
钒钛资源综合利用国家重点实验室, 四川攀枝花 617000
2.
攀钢集团研究院有限公司, 四川成都 610300

基金项目: 国家自然科学基金（51403193）资助

详细信息

作者简介:
倪伟，1982年出生，男，河南安阳人，理学博士，主要从事能源和环境功能材料研发，通讯作者，E-mail: niwei@iccas.ac.cn

通讯作者:
倪伟，1982年出生，男，河南安阳人，理学博士，主要从事能源和环境功能材料研发，通讯作者，E-mail: niwei@iccas.ac.cn

中图分类号: TF841.3,TM91
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- 文章访问数: 88
- HTML全文浏览量: 11
- PDF下载量: 22
- 被引次数: 0
出版历程
- 收稿日期: 2021-12-15
- 刊出日期: 2022-11-01

Recent progress on V₂O₅ nanowire nonwovens preparation and application in advanced electrochemical energy storage devices

Ni Wei^{1, 2
, ,},
Qi Jianling^{1, 2},
Fan Heyun^{1, 2}

1.
State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China
2.
Pangang Group Research Institute Co., Ltd., Chengdu 610300, Sichuan, China

摘要

摘要: 五氧化二钒纳米纤维作为重要的钒基功能材料，在电化学储能领域有着重要应用。通过分析一维五氧化二钒纳米纤维及其聚集态材料在先进电化学储能器件应用领域的研究进展，结合近期研究前沿比较了不同五氧化二钒纳米纤维布合成方法的优缺点，认为采用降低尺寸和增加比表面积的策略将使其在电化学储能方面有更好的性能。同时，展望了V₂O₅纳米纤维布在未来先进电化学储能领域的发展前景，提出了其主要的发展和研究方向。
- V₂O₅ /
- 纳米纤维布 /
- 一维纳米材料 /
- 纳米结构 /
- 电化学储能 /
- 柔性器件
Abstract: As an important V-based functional material, vanadium pentoxide (V₂O₅) nanofiber has a significant application in the field of electrochemical energy storage. We herein gave an overview of the one-dimensional (1D) V₂O₅-based materials for the application of advanced electrochemical energy storage and conversion, especially regarding the advantages and disadvantages of different synthetic methods of V₂O₅ nanowire nonwovens combined with recent research frontiers. It was considered that reducing the size and increasing the specific surface area will endow V₂O₅ with better performance in this field. Meanwhile, the development prospect of V₂O₅ nanofiber cloth in the field of advanced electrochemical energy storage in the future as well as the main development and research direction was provided.
- V₂O₅ /
- nanowire nonwovens /
- one-dimensional (1D) nanomaterials /
- nanostructures /
- electrochemical energy storage /
- flexible devices

HTML全文

图 1 V₂O₅纳米纤维布的宏观和微观形貌（500 ℃退火）

Figure 1. Digital optical photos of the V₂O₅ nanowire nonwoven fabrics (yellow color) and the corresponding SEM images (annealing at 500 ℃)

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图 2 高有序V₂O₅纳米纤维泡沫制备、结构及其优异阻尼性能

Figure 2. Formation, structure, and performances (relative Young’s modulus and damping capacities) of single V₂O₅ nanofibers based highly ordered all-ceramic scaffolds^[24]

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图 3 V₂O₅纳米纤维层状晶格结构、原位锂化表征及储锂机理

Figure 3. Structural and lithiation progression characterizations of the pristine V₂O₅ nanowire as well as the proposed lithiation mechanism^[39]

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图 4 V₂O₅纳米纤维及其自支撑柔性石墨烯复合膜结构及其全固态锂离子电池正极材料性能（80℃）

Figure 4. Structure of V₂O₅-nanowire, freestanding flexible rGO/V₂O₅ composite paper and the performance of the as-prepared all-solid-state lithium–vanadium (rGO/V₂O₅/PEO-MIL-53(Al)-LiTFSI/Li) battery^[6]

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图 5 双层结构V₂O₅纳米纤维晶格及其储镁结构表征

Figure 5. Structures of bilayered V₂O₅ nanoribbon and the related Mg storage performance^[48,32]

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图 6 高有序V₂O₅纳米纤维泡沫衍生膜及其铝离子电池性能

Figure 6. Structures of the creased highly porous scaffold comprised of V₂O₅ nanowires and its aluminum-ion batteries (AIBs) performances^[26]

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图 7 V₂O₅纳米纤维/碳纳米管复合膜及其钠离子非对称超级电容器性能

Figure 7. Structures of the layered-V₂O₅-nanowires/CNTs nanocomposite film and the performance of the as-prepared Na-ion asymmetric supercapacitor^[52]

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图 8 V₂O₅纳米纤维膜及其银掺杂衍生物(SVO)的结构和电致变色性能

Figure 8. Structures of the V₂O₅ nanowire thin film and its Ag-doped derivative (SVO) as well as their electrochromic performance^[10]

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