Hydrothermal synthesis and phase transformation properties of W-doped VO2(M) nanoparticles
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摘要: 以偏钒酸铵为钒源,水合肼为还原剂,偏钨酸铵为掺杂剂,采用一步水热法在280 ℃制备了掺W量(原子分数表示)从0到2.0%的VO2粉体,并将其加入到聚氨酯中,制备VO2/PU复合薄膜。通过XRD、TEM、XPS、DSC对合成的样品进行了物相组成、形貌、元素价态和相变性能分析,利用紫外-可见-近红外光谱仪测定了薄膜的透射率。结果表明:随着W掺杂量从0增加到2.0%,二氧化钒升温时的相变温度从61.8 ℃降低至15 ℃。基于掺杂1.0%的二氧化钒粉体制备的VO2/PU复合薄膜,ΔTsol可达11.7%,基本满足智能窗的实际应用要求。Abstract: In this paper, using ammonium metavanadate as the vanadium source, hydrazine monohydrate as the reducing agent and ammonium metatungstate as the dopant, the VO2 powder doped with W from 0.0 to 2.0 at% was prepared by one-step hydrothermal method at 280 ℃, and was added to polyurethane to prepare VO2/PU composite films. XRD, TEM, XPS and DSC were used to analyze the phase composition, morphology, element valence state and phase transformation performance of the synthesized samples. The transmittance of the films was measured by UV-Vis-NIR spectrometer. The results show that with W doping increasing from 0.0 to 2.0 at%, the phase transition temperature of vanadium dioxide decreases from 61.8 ℃ to 15 ℃. The composite film based on 1 at% W-doped vanadium dioxide powder shows a good solar modulating ability (ΔTsol = 11.7%), which meets the practical application requirements of intelligent windows.
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Key words:
- vanadium dioxide /
- one-step hydrothermal treatment /
- W-doped /
- phase transformation properties /
- films
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表 1 具有不同掺钨量的样品的金属-绝缘体相变温度汇总
Table 1. Summary of metal insulator transition temperatures for samples with different W-doping concentrations
掺钨量/% Tc-heating /℃ Tc-cooling /℃ Tc/℃ 热滞宽度/℃ ΔH−heating/
(J·g−1)ΔH−cooling/
(J·g−1)ΔH/(J·g−1) 0 61.8 33.1 47.5 28.7 30.19 −32.31 31.25 0.5 49.5 27.7 38.6 21.8 25.66 −26.22 25.94 1.0 40.3 19.4 29.9 20.9 23.36 −22.14 22.75 1.5 30.4 9.1 19.8 21.3 17.82 −16.39 17.11 2.0 25.3 4.7 15 20.6 13.96 −15.13 14.55 注:ΔH=(ΔH−heating+|ΔH−cooling|)/2 ; Tc= (Tc-heating + Tc-cooling)/2。 表 2 不同掺钨量VO2薄膜的热致变色性能
Table 2. Thermochromic properties of VO2 films with different W-doping concentrations
掺钨量/% 涂膜浆料体积/mL Tsol /% Tlum /% ΔTsol /% 20 ℃ 100 ℃ 20 ℃ 100 ℃ 0 0.8 57.5 43.7 53.0 52.3 13.8 0.5 0.8 53.6 45.3 51.2 54.6 8.3 0.4+0.4+0.4 39.4 26.7 32.4 34.1 12.7 1.0 0.8 49.8 42.7 46.8 49.5 7.1 0.4+0.4+0.4 41.8 30.1 37.1 37.9 11.7 1.5 0.8 43.5 42.4 41.4 46.3 1.1 0.4+0.4+0.4 34.5 31.4 31.6 35.9 3.1 -
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