Piao Rongxun, Ma Lan, Yang Shaoli, Cao Daipeng. Experimental Study on Preparation of Cr-containing Ti-Al Based Alloys by Aluminothermic Reduction-remelting of Waste SCR Ti-based Denitration Catalyst[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(2): 79-86. doi: 10.7513/j.issn.1004-7638.2019.02.013
Citation:
Piao Rongxun, Ma Lan, Yang Shaoli, Cao Daipeng. Experimental Study on Preparation of Cr-containing Ti-Al Based Alloys by Aluminothermic Reduction-remelting of Waste SCR Ti-based Denitration Catalyst[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(2): 79-86. doi: 10.7513/j.issn.1004-7638.2019.02.013
Piao Rongxun, Ma Lan, Yang Shaoli, Cao Daipeng. Experimental Study on Preparation of Cr-containing Ti-Al Based Alloys by Aluminothermic Reduction-remelting of Waste SCR Ti-based Denitration Catalyst[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(2): 79-86. doi: 10.7513/j.issn.1004-7638.2019.02.013
Citation:
Piao Rongxun, Ma Lan, Yang Shaoli, Cao Daipeng. Experimental Study on Preparation of Cr-containing Ti-Al Based Alloys by Aluminothermic Reduction-remelting of Waste SCR Ti-based Denitration Catalyst[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(2): 79-86. doi: 10.7513/j.issn.1004-7638.2019.02.013
Ti-Al based alloys were prepared for the first time by aluminothermic reduction-remelting method using scrap selective catalytic reduction(SCR) catalyst as raw material.The effects of Cr on the microstructure,phase compositions and properties of the alloys were also studied by adding different contents of Cr.X-ray diffraction(XRD) and energy dispersive spectroscopy(EDS) analysis show that the phases observed in the alloys without adding Cr element are mainly composed of Ti0.8V0.2Al3,TiAl2,Ti3Al,TiAl,Ti5Si3,TiSi2,CaAl4O7,Ca2AlSiO5.5 and so on.Adding Cr element can reduce the formation of Al-rich titanium aluminide compounds,and reduce the content of Ca-Al oxides.It can also form Ti0.25Cr0.08Al0.67 phase,and increases the formation of Ti3Al and TiAl phases.The phase evolution calculation by Pandat thermochemical software shows that the addition of Cr can significantly reduce the phase ratio of Al3(Ti,V) and decrease a certain amount of(Ti,Cr)5Si3,and can increase the formation of TiAl phase.The hardness test results show that the hardness of the alloy increases with the increase of Cr content.This may be due to the uniform distribution of equiaxed TiAl-like phases and the decrease of(Ti,W)5Si3 phase.