Zhang Jianbo. Preliminary Study of Preparing Macroporous Titanium Dioxide Material from Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(5): 31-36. doi: 10.7513/j.issn.1004-7638.2019.05.006
Citation:
Zhang Jianbo. Preliminary Study of Preparing Macroporous Titanium Dioxide Material from Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(5): 31-36. doi: 10.7513/j.issn.1004-7638.2019.05.006
Zhang Jianbo. Preliminary Study of Preparing Macroporous Titanium Dioxide Material from Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(5): 31-36. doi: 10.7513/j.issn.1004-7638.2019.05.006
Citation:
Zhang Jianbo. Preliminary Study of Preparing Macroporous Titanium Dioxide Material from Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(5): 31-36. doi: 10.7513/j.issn.1004-7638.2019.05.006
Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China
Macroporous TiO2,with the pore size higher than 50 nm,is an important material.This paper proposed and preliminarily studied a method for preparing macroporous titanium dioxide(rutile) from Panzhihua ilmenite by two steps of thermal pretreatment-hydrochloric acid leaching.The results show that both the two processes,weak oxidation(at 600~750℃)-atmospheric hydrochloric acid leaching and the oxidation at low and moderate temperature(such as 800℃)-weak reduction at low temperature(such as 600℃)-atmospheric hydrochloric acid leaching,can be used to prepare macroporous TiO2 with micrometer and submicron pores from Panzhihua ilmenite.The sizes of the TiO2 crystals and pores can be regulated by changing the temperature or time of roasting oxidation.When the oxidation temperature is higher or the oxidation time is longer,the sizes of the TiO2 crystals and pores for the obtained macroporous TiO2 are bigger.However,the TiO2 prepared by the methods usually contains some impurities of oxides for Si,Fe,etc.The macroporous TiO2 prepared by the oxidation at low and moderate temperature-weak reduction at low temperature-atmospheric hydrochloric acid leaching contains much fewer impurities.