Review of progress in synthesis of M phase VO<sub>2</sub> powders

Zhang Kun; Mei Jing; Wang Dan; Jiang Peng; Yuan Xinqiang; Zhang Wei

doi:10.7513/j.issn.1004-7638.2021.02.004

Volume 42 Issue 2

Apr. 2021

Turn off MathJax

Article Contents

Article Navigation > IRON STEEL VANADIUM TITANIUM > 2021 > 42(2): 15-22

Zhang Kun, Mei Jing, Wang Dan, Jiang Peng, Yuan Xinqiang, Zhang Wei. Review of progress in synthesis of M phase VO2 powders[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(2): 15-22. doi: 10.7513/j.issn.1004-7638.2021.02.004

Citation:

Zhang Kun, Mei Jing, Wang Dan, Jiang Peng, Yuan Xinqiang, Zhang Wei. Review of progress in synthesis of M phase VO₂ powders[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(2): 15-22. doi: 10.7513/j.issn.1004-7638.2021.02.004

Citation:

PDF( 674 KB)

Review of progress in synthesis of M phase VO₂ powders

doi: 10.7513/j.issn.1004-7638.2021.02.004

Zhang Kun^1
,,
Mei Jing¹,
Wang Dan¹,
Jiang Peng^{1, 2},
Yuan Xinqiang^{1, 2
,
,},
Zhang Wei¹

1.
School of Materials Science and Engineering, Shanxi University of Technology, Hanzhong 723000, Shanxi, China
2.
National and Local Joint Engineering Laboratory for Slag Comprehensive Utilization and Environmental Technology, Hanzhong 723000, Shanxi, China

Received Date: 2020-10-13
Publish Date: 2021-04-10

Abstract

Abstract

Vanadium dioxide (VO₂) has the semiconductor-metal phase transition characteristics. It has the mutation property of infrared light transmittance/reflectivity at 68 ℃. Using tungsten, fluorine and other elements for single element or multi-element doping can effectively reduce the phase transition temperature of VO₂(M), and VO₂(M) with room temperature phase transition feature can be developed, which can greatly broaden its application in the intelligent windows. The progress in synthesis of VO₂(M) and doped VO₂(M) powders from vanadium pentoxide (V₂O₅) was reviewed, the advantages and disadvantages of different synthesis methods were compared, and the feasibility and prospect of their application in smart plexiglass were analyzed.
- VO₂(M),
- V₂O₅,
- powder synthesis,
- plexiglass,
- smart thermal insulation

FullText(HTML)

References(48)

References

[1]	（钟莉. 二氧化钒纳米材料的水热合成、物相演化和相变性能[D]. 合肥: 中国科学技术大学, 2017.） Zhong Li. Hydrothermal synthesis, phase evolution and phase transition performance of vanadium dioxide nanomaterials[D]. Hefei: University of Science and Technology of China, 2017.
[2]	Chen Chang, Cao Chuanxiang, Luo Hongjie, et al. Vanadium dioxide intelligent energy-saving window: Integrated window from coated glass to energy-saving power generation[J]. Science Bulletin, 2016,61(15):1661−1678. (陈长, 曹传祥, 罗宏杰, 等. 二氧化钒智能节能窗: 从镀膜玻璃到节能发电一体化窗[J]. 科学通报, 2016,61(15):1661−1678.
[3]	Gao Y F, Cao C X. Nanoceramic VO₂ thermochromic smart glass: A review on progress in solution processing[J]. Nano Energy, 2012,1(2):221−246. doi: 10.1016/j.nanoen.2011.12.002
[4]	Pacheco-Torgal F, Diamanti M V, Nazari A, et al. Nanotechnology in eco-efficient construction materials, processes and applications[M]. 2nd Edition. UK: Woodhead Publishing, 2018: 503-524.
[5]	Wang Chao, Zhao Li, Wang Shimin, et al. Research progress of vanadium dioxide thin film intelligent window[J]. Materials Bulletin, 2017,(S1):257−262, 272. (王超, 赵丽, 王世敏, 等. 二氧化钒薄膜智能窗的研究进展[J]. 材料导报, 2017,(S1):257−262, 272.
[6]	Zhu J, Huang A, Ma H, et al. Composite film of vanadium dioxide nanoparticles and ionicÂ liquid-nickel-chlorine complexes with excellent visible thermochromic performance[J]. ACS Appl Mater Interfaces, 2016,8(43):29742−29748. doi: 10.1021/acsami.6b11202
[7]	Yang Y S, Zhou Y, Chiang F B Y, et al. Tungsten doped VO₂/microgels hybrid thermochromic material and its smart window application[J]. Rsc Advances, 2017,7(13):7758−7762. doi: 10.1039/C6RA24686A
[8]	Schläefer J, Sol C, Li T, et al. Thermochromic VO₂-SiO₂ nanocomposite smart window coatings with narrow phase transition hysteresis and transition gradient width[J]. Solar Energy Materials and Solar Cells, 2019,200:109944. doi: 10.1016/j.solmat.2019.109944
[9]	Ji Y X, Mattsson A A, Niklasson G, et al. Synergistic TiO₂/VO₂ window coating with thermochromism, enhanced luminous transmittance, and photocatalytic activity[J]. Joule, 2019,3(10):2457−2471. doi: 10.1016/j.joule.2019.06.024
[10]	Liu Peng, Liang Liping, Xu Yao. Preparation and properties of thermochromic SiO₂/VO₂ double-layer membranes for smart windows[J]. Journal of Optics, 2019,39(4):0416001−0416008. (刘鹏, 梁丽萍, 徐耀. 智能窗用热致变色SiO₂/ VO₂双层膜的制备与性能[J]. 光学学报, 2019,39(4):0416001−0416008.
[11]	Chen Xuerong, Hu Junzhi, Han Wenzheng. Research progress in the structure, optical properties and application of VO₂ thin films[J]. Materials Bulletin, 2007,21(11):16−19, 29. (陈学荣, 胡军志, 韩文政. VO₂薄膜的结构、光学特性及其应用研究进展[J]. 材料导报, 2007,21(11):16−19, 29. doi: 10.3321/j.issn:1005-023X.2007.11.005
[12]	Cao X, Chang T C, Shao Z W, et al. Challenges and opportunities toward real application of VO₂-based smart glazing[J]. Matter, 2020,2(4):862−881. doi: 10.1016/j.matt.2020.02.009
[13]	Won Youn J, Lee S J, Kim K S, et al. Adhesion characteristics of VO₂ ink film sintered by intense pulsed light for smart window[J]. Applied Surface Science, 2018,441(31):508−514.
[14]	Wu Ming. Market prospect of organic glass[J]. Building Materials Industry Information, 2002,(5):22. (伍明. 有机玻璃市场前景看好[J]. 建材工业信息, 2002,(5):22.
[15]	Liu Y X, Xu Z W, Charpentier A P. Synthesis of VO₂/poly(MMA-co-dMEMUABr) antimicrobial/thermochromic dual-functional coatings[J]. Progress in Organic Coatings, 2020,142:105589. doi: 10.1016/j.porgcoat.2020.105589
[16]	Tang Lu, Huang Wanxia, Wen Hao, et al. Study on thermal insulation performance of nano-VO₂ modified plexiglass[J]. Iron Steel Vanadium Titanium, 2019,40(5):55−60. (唐露, 黄婉霞, 文皓, 等. 纳米VO₂改性有机玻璃的隔热性能研究[J]. 钢铁钒钛, 2019,40(5):55−60.
[17]	（李寅瑞. 钨钼掺杂VO₂粉体及薄膜制备研究[D]. 武汉: 华中科技大学, 2016.） Li Yingrui. Study on the preparation of tungsten-molybdenum doped VO₂ powder and thin films[D]. Wuhan: Huazhong University of Science and Technology, 2016.
[18]	Wang S C, Owusu K A, Mai L Q, et al. Vanadium dioxide for energy conservation and energy storage applications: Synthesis and performance improvement[J]. Applied Energy, 2018,211(1):200−217.
[19]	Wang S F, Liu M S, Kong L B, et al. Recent progress in VO₂ smart coatings: Strategies to improve the thermochromic properties[J]. Progress in Materials Science, 2016,81:1−54. doi: 10.1016/j.pmatsci.2016.03.001
[20]	Zhong Cheng, Zhao Li, Wang Shimin, et al. Preparation and application of vanadium dioxide powder[J]. China Ceramics, 2015,51(9):1−4. (钟诚, 赵丽, 王世敏, 等. 二氧化钒粉体的制备及其应用研究[J]. 中国陶瓷, 2015,51(9):1−4.
[21]	Li S Y, Niklasson G A, Granqvist C G. Nanothermochromics: Calculations for VO₂nanoparticles in dielectric hosts show much improved luminous transmittance and solar energy transmittance modulation[J]. Journal of Applied Physics, 2010,108(6):063525. doi: 10.1063/1.3487980
[22]	Li S Y, Niklasson G A, Granqvist C G. Nanothermochromics with VO₂-based core-shell structures: Calculated luminous and solar optical properties[J]. Journal of Applied Physics, 2011,109(11):113515. doi: 10.1063/1.3592350
[23]	Bi Aihong, Dong Kuiyi, Zhu Jinhua. Study on the structure and kinetics of composite doped VO₂ powder prepared by thermal decomposition[J]. New Building Materials, 2014,(1):22−26. (毕爱红, 董奎义, 朱金华. 热分解法制备复合掺杂VO₂粉体的结构及动力学研究[J]. 新型建筑材料, 2014,(1):22−26. doi: 10.3969/j.issn.1001-702X.2014.01.006
[24]	Huang Boyun, Yan Wenbin, Yi Jing. Preparation of vanadium dioxide by reduction of vanadium pentoxide by activated carbon[J]. Fine Chemical Industry, 2018,35(4):564−568. (黄博云, 颜文斌, 易静. 活性炭还原五氧化二钒制备二氧化钒[J]. 精细化工, 2018,35(4):564−568.
[25]	Zhang Shaohong, Fu Juan, Su Qiucheng, et al. Preparation of ultrafine VO₂ powder and in situ characterization of its reversible phase transition[J]. Rare Metal Materials and Engineering, 2015,44(3):738−742. (张少鸿, 付娟, 苏秋成, 等. 超细VO₂粉末的制备及其可逆相变的原位表征[J]. 稀有金属材料与工程, 2015,44(3):738−742.
[26]	Chen Yichao, Yan Wenbin, Shi Aihua, et al. Preparation of M-phase vanadium dioxide powder by microwave-assisted heat-methanol reduction[J]. Materials Science and Technology, 2019,(3):41−46. (陈益超, 颜文斌, 石爱华, 等. 微波辅热-甲醇还原法制备M相二氧化钒粉体[J]. 材料科学与工艺, 2019,(3):41−46. doi: 10.11951/j.issn.1005-0299.20180040
[27]	Hou J W, Zhang J W, Wang Z P, et al. The phase transition of W-doped VO₂ nanoparticles synthesized by an improved thermolysis method[J]. Journal of Nanoscience & Nanotechnology, 2013,13(2):1543−1548.
[28]	Zhao Dong, Huang Wanxia, Cai Jinghan, et al. Thermochromic properties of tungsten doped VO₂/mica composite powders prepared by thermal decomposition and carbothermal reduction[J]. Journal of Inorganic Chemistry, 2013,29(1):103−110. (赵冬, 黄婉霞, 蔡靖涵, 等. 热分解法和碳热还原法制备掺钨VO₂/云母复合粉体的热致变色性能[J]. 无机化学学报, 2013,29(1):103−110. doi: 10.3969/j.issn.1001-4861.2013.00.025
[29]	Wu X Y, Weng X L, Yuan L, et al. Phase- and shape-controlled synthesis of VO₂ by a hydrothermal-calcination method[J]. Vacuum, 2020,176:109352. doi: 10.1016/j.vacuum.2020.109352
[30]	Zhang L M, Yao J N, Guo Y F, et al. VO₂(A) nanorods: One-pot synthesis, formation mechanism and thermal transformation to VO₂(M)[J]. Ceramics International, 2018,44:19301−19306. doi: 10.1016/j.ceramint.2018.07.157
[31]	Srinivasa, Rao, Popuri, et al. Rapid hydrothermal synthesis of VO₂ (B) and its conversion to thermochromic VO₂ (M1)[J]. Inorganic Chemistry, 2013,52:4780−4785.
[32]	Ji S D, Zhang F, Jin P. Preparation of high performance pure single phase VO₂ nanopowder by hydrothermally reducing the V₂O₅ gel[J]. Solar Energy Materials & Solar Cells, 2011,95:3520−3526.
[33]	Alie D, Gedvilas L, Wang Z W, et al. Direct synthesis of thermochromic VO₂through hydrothermal reaction[J]. Journal of Solid State Chemistry, 2014,212:237−241. doi: 10.1016/j.jssc.2013.10.023
[34]	Ji C H, Wu Z M, Wu X F, et al. Al-doped VO₂ films as smart window coatings: Reduced phase transition temperature and improved thermochromic performance[J]. Solar Energy Materials and Solar Cells, 2018,176:174−180. doi: 10.1016/j.solmat.2017.11.026
[35]	Liang Z H, Zhao L, Meng W F, et al. Tungsten-doped vanadium dioxide thin films as smart windows with self-cleaning and energy-saving functions[J]. Journal of Alloys and Compounds, 2017,694:124−131. doi: 10.1016/j.jallcom.2016.09.315
[36]	Zhang Zongtao, Luo Hongjie, Gao Yanfeng. VO₂ thermochromic materials: from nanoparticles to flexible laminae[J]. Science Bulletin, 2015,60(25):2425−2437. (张宗涛, 罗宏杰, 高彦峰. VO₂热致变色材料: 从纳米颗粒到柔性贴膜[J]. 科学通报, 2015,60(25):2425−2437.
[37]	（周甜甜. VO₂粉体水热法制备及稀土掺杂改性研究[D]. 西安: 西安建筑科技大学, 2018.） Zhou Tiantian. Hydrothermal preparation of VO₂ powder and study on rare earth doped modification[D]. Xi’an: Xi’an University of Architecture and Technology, 2018.
[38]	Zhou Q T, Lv W Z, Qiu Q, et al. Boron doped M-phase VO₂nanoparticles with low metal-insulator phase transition temperature for smart windows[J]. Ceramics International, 2020,46(4):4786−4794. doi: 10.1016/j.ceramint.2019.10.211
[39]	Yanase I, Mori Y, Kobayashi H. Hydrothermal synthesis and thermal change in IR reflectance of Al/W codoped VO₂ powder[J]. Materials Research Bulletin, 2018,100:243−248. doi: 10.1016/j.materresbull.2017.12.017
[40]	Li B, Tian S Q, Tao H Z, et al. Tungsten doped M-phase VO₂ mesoporous nanocrystals with enhanced comprehensive thermochromic properties for smart windows[J]. Ceramics International, 2019,45(4):4342−4350. doi: 10.1016/j.ceramint.2018.11.109
[41]	Lv Weizhong, Huang Dezhen, Luo Zhongkuan, et al. Hydrothermal preparation and characterization of vanadium dioxide doped with tungsten-fluorine[J]. Journal of Shenzhen University (Science and Technology Edition), 2015,32(4):385−389. (吕维忠, 黄德贞, 罗仲宽, 等. 钨-氟共掺杂二氧化钒的水热法制备及表征[J]. 深圳大学学报(理工版), 2015,32(4):385−389. doi: 10.3724/SP.J.1249.2015.04385
[42]	Chen Y X, Zeng X Z, Zhu J T, et al. High performance and enhanced durability of thermochromic films using VO₂@ZnO core-shell nanoparticles[J]. Applied Materials & Interfaces, 2017,9:27784−27791.
[43]	Tong K, Li R, Zhu J T, et al. Preparation of VO₂/Al-O core-shell structure with enhanced weathering resistance for smart window[J]. Ceramics International, 2017,43(5):4055−4061. doi: 10.1016/j.ceramint.2016.11.181
[44]	Li D B, Li M, Pan J, et al. Hydrothermal synthesis of Mo-doped VO₂/TiO₂ composite nanocrystals with enhanced thermochromic performance[J]. Applied Materials & Interfaces, 2014,(6):6555−6561.
[45]	Salamati M, Kamyabjou G, Mohamadi M, et al. Preparation of TiO₂@W-VO₂ thermochromic thin film for the application of energy efficient smart windows and energy modeling studies of the produced glass[J]. Construction and Building Materials, 2019,218:477−482. doi: 10.1016/j.conbuildmat.2019.05.046
[46]	（许鑫予. 掺杂二氧化钒纳米分散体的制备及在节能涂料中的应用研究[D]. 北京: 北京化工大学, 2018.） Xu Xingyu. Preparation of doped vanadium dioxide nanodispersion and its application in energy saving coatings[D]. Beijing: Beijing University of Chemical Technology, 2018.
[47]	（周莉. 掺杂二氧化钒超细粉体的制备及性能研究[D]. 大连: 大连理工大学, 2010.） Zhou Li. Preparation and properties of doped vanadium dioxide superfine powders[D]. Dalian: Dalian University of Technology, 2010.
[48]	Yuan Xinqiang, Jiang Peng, He Zhirong, et al. Application of infrared reflection pigment in plexiglass[J]. Plastic, 2017,46(1):26−28. (袁新强, 蒋鹏, 贺志荣, 等. 红外反射颜料在有机玻璃中的应用[J]. 塑料, 2017,46(1):26−28.