Construction and growth mechanism analysis of nano oxide tubes on Ti-10Mo-28Nb-3Zr-6Ta alloy

Xu Ying; Xia Pengzhao; Wei Ziyan; Zhao Sitan; Cai Yanqing

doi:10.7513/j.issn.1004-7638.2021.03.011

Volume 42 Issue 3

Jun. 2021

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Xu Ying, Xia Pengzhao, Wei Ziyan, Zhao Sitan, Cai Yanqing. Construction and growth mechanism analysis of nano oxide tubes on Ti-10Mo-28Nb-3Zr-6Ta alloy[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(3): 74-81. doi: 10.7513/j.issn.1004-7638.2021.03.011

Citation:

Xu Ying, Xia Pengzhao, Wei Ziyan, Zhao Sitan, Cai Yanqing. Construction and growth mechanism analysis of nano oxide tubes on Ti-10Mo-28Nb-3Zr-6Ta alloy[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(3): 74-81. doi: 10.7513/j.issn.1004-7638.2021.03.011

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Construction and growth mechanism analysis of nano oxide tubes on Ti-10Mo-28Nb-3Zr-6Ta alloy

doi: 10.7513/j.issn.1004-7638.2021.03.011

Xu Ying^{1, 2
,},
Xia Pengzhao^{1
,
,},
Wei Ziyan²,
Zhao Sitan²,
Cai Yanqing²

1.
School of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, Hebei, China
2.
School of Materials Science and Engineering, North China University of Science and Technology, Tangshan 063210, Hebei, China

Received Date: 2021-03-24
Publish Date: 2021-06-10

Abstract

Abstract

Nano oxide tubes were formed on the surface of Ti-10Mo-28Nb-3Zr-6Ta alloy by anodic oxidation in a mixed solution containing 1 mol/L H₃PO₄ and 0.9 % NaF at 25 V DC voltage for 120 min. XRD and SEM were used to analyze the structure, morphology and composition of the nano oxide tubes. The results show that the diameter of the nano oxide tube on the surface of Ti-10Mo-28Nb-3Zr-6Ta alloy is 50～70 nm, the wall thickness is about 15 nm, and the length of the oxidation tube is 100 nm. The nanotubes are composed of amorphous titanium oxide and anatase titanium dioxide nanocrystals. HRTEM and EDS were used to analyze the growth mechanism of nano oxide tubes on the alloy surface. The results show that at the beginning of anodic oxidation process, a layer of amorphous titanium oxide is formed on the alloy surface, and then amorphous nano particles are formed on the surface of amorphous titanium oxide layer under the action of oxidation voltage and electrolyte. After high temperature treatment, partial amorphous nanotubes can be transformed into anatase TiO₂ nanocrystals.
- titanium alloy,
- surface modification,
- nano oxide tubes,
- anodic oxidation method,
- microstructure,
- growth mechanism

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References(27)

References

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