Volume 42 Issue 3
Jun.  2021
Turn off MathJax
Article Contents
Ding Hongyu, Huang Xiuli. Preparation of heat-treated graphite felt electrode material modified by graphene oxide/graphene[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(3): 88-93. doi: 10.7513/j.issn.1004-7638.2021.03.013
Citation: Ding Hongyu, Huang Xiuli. Preparation of heat-treated graphite felt electrode material modified by graphene oxide/graphene[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(3): 88-93. doi: 10.7513/j.issn.1004-7638.2021.03.013

Preparation of heat-treated graphite felt electrode material modified by graphene oxide/graphene

doi: 10.7513/j.issn.1004-7638.2021.03.013
  • Received Date: 2021-04-06
  • Publish Date: 2021-06-10
  • Graphene oxide was prepared by heat treatment of the graphite felt, and the graphene was further obtained on basis of the graphene oxide. The cathode material of all-vanadium redox flow battery was finally prepared by compositing the graphene oxide, graphene and the heat-treated graphite felt. The surface morphologies and electrochemical properties of the composite electrode materials were characterized by scanning electron microscopy (SEM), Fourier transforms infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and charge-discharge test. The results show that the charge-discharge performances of composite electrode materials are improved. At the current density of 30 mA/cm2, the current efficiency of the graphene oxide/graphite felt composite electrodes reaches 94.713%, and the current efficiency of the graphene/graphite felt composite electrodes reaches 96.482%. The electrochemical activity of the graphite felt/graphene composite electrode is the best.
  • loading
  • [1]
    Xia Lixing, Liu Hao, Liu Lin, et al. Research progress of organic redox flow batteries[J]. Electrochemistry, 2018,24(5):466−487. (夏力行, 刘昊, 刘琳, 等. 有机氧化还原液流电池的研究进展[J]. 电化学, 2018,24(5):466−487.
    [2]
    Winsberg J, Hagemann T, Janoschka T, et al. Redox-flow batteries: From metals to organic redox-active materials[J]. Angewandte Chemie International Edition, 2017,56(3):686−711. doi: 10.1002/anie.201604925
    [3]
    Chen Jinqing, Wang Qian, Wang Baoguo. Research progress of key materials for all vanadium redox flow batteries[J]. Modern Engineering, 2006,26(9):21−24. (陈金庆, 汪钱, 王保国. 全钒液流电池关键材料研究进展[J]. 现代化工, 2006,26(9):21−24. doi: 10.3321/j.issn:0253-4320.2006.09.005
    [4]
    Zhang Huamin, Wang Xiaoli. The latest research progress of all-vanadium flow battery technology[J]. Energy Storage Science and Technology, 2013,3(2):281−288. (张华民, 王晓丽. 全钒液流电池技术最新研究进展[J]. 储能科学与技术, 2013,3(2):281−288.
    [5]
    Wang Gang, Chen Jinwei, Zhu Shifu. Activation of carbon electrodes for all vanadium redox flow batteries[J]. Progress in Chemistry, 2015,27(10):1343−1355. (王刚, 陈金伟, 朱世富. 全钒氧化还原液流电池碳素类电极的活化[J]. 化学进展, 2015,27(10):1343−1355. doi: 10.7536/PC150338
    [6]
    Qin Hongmei, Yue Luchao, Mi Jie. Research progress of supercapacitor electrode materials[J]. Journal of Taiyuan University of Science and Technology, 2018,39(6):435−442. (秦红梅, 岳鲁超, 米杰. 超级电容器电极材料的研究进展[J]. 太原科技大学学报, 2018,39(6):435−442. doi: 10.3969/j.issn.1673-2057.2018.06.005
    [7]
    Wu X, Xu H, Xu P, et al. Microwave-treated graphite felt as the positive electrode for all vanadium redox flow battery[J]. Journal of Power Sources, 2014,263:104−109. doi: 10.1016/j.jpowsour.2014.04.035
    [8]
    Li B, Gu M, Nie Z, et al. Bismuth nanoparticle decorating graphite felt as a high-performance electrode for an all-vanadium redox flow battery[J]. Nano Letters, 2013,13(3):1330−1335. doi: 10.1021/nl400223v
    [9]
    (许晓琪. 氧化石墨烯复合海绵制备及吸附性能研究[D]. 青岛: 青岛大学, 2016.)

    Xu Xiaoqi. Preparation and adsorption performance of graphene oxide composite sponge[D]. Qingdao: Qingdao University, 2016.
    [10]
    Yang Dezhi, Shen Jiani, Yang Xiaowei, et al. Research progress in graphene-based supercapacitors[J]. Energy Storage Science and Technology, 2014,3(1):1−8. (杨德志, 沈佳妮, 杨晓伟, 等. 石墨烯基超级电容器研究进展[J]. 储能科学与技术, 2014,3(1):1−8. doi: 10.3969/j.issn.2095-4239.2014.01.02
    [11]
    Zheng M, Zhao X, Li M, et al. Interconnected 3D network of carbon dots decorated reduced graphene oxide nanosheets for high-performance supercapacitors[J]. Chemsuschem, 2017,10(12):2626−2634. doi: 10.1002/cssc.201700474
    [12]
    Huang Y, Liang J J, Chen Y S. An overview of the applications of graphene-based materials in supercapacitors[J]. Small, 2012,8(12):1805−1834. doi: 10.1002/smll.201102635
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(5)  / Tables(2)

    Article Metrics

    Article views (373) PDF downloads(51) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return