Preparation and properties of Ti<sub>4</sub>AlN<sub>3</sub> by powder metallurgy

Guo Hui; Li Xikun; Song Yuanyuan; Sun Qian; Huang Yiwen

doi:10.7513/j.issn.1004-7638.2021.05.008

Volume 42 Issue 5

Oct. 2021

Turn off MathJax

Article Contents

Article Navigation > IRON STEEL VANADIUM TITANIUM > 2021 > 42(5): 47-53

Guo Hui, Li Xikun, Song Yuanyuan, Sun Qian, Huang Yiwen. Preparation and properties of Ti4AlN3 by powder metallurgy[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(5): 47-53. doi: 10.7513/j.issn.1004-7638.2021.05.008

Citation:

Guo Hui, Li Xikun, Song Yuanyuan, Sun Qian, Huang Yiwen. Preparation and properties of Ti₄AlN₃ by powder metallurgy[J]. IRON STEEL VANADIUM TITANIUM, 2021, 42(5): 47-53. doi: 10.7513/j.issn.1004-7638.2021.05.008

Citation:

PDF( 1482 KB)

Preparation and properties of Ti₄AlN₃ by powder metallurgy

doi: 10.7513/j.issn.1004-7638.2021.05.008

School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110159, Liaoning, China

Received Date: 2021-09-09
Publish Date: 2021-10-30

Abstract

Abstract

The ternary layered cermet of Ti₄AlN₃ was prepared by powder metallurgy. The effects of raw powder, sintering temperature and holding time on the purity of Ti₄AlN₃ ceramic were studied. The samples were qualitatively analyzed by X-ray diffraction (XRD) and quantitatively analyzed by TOPAS based on Rietveld method. The microstructure and micro area composition of Ti₄AlN₃ were characterized by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The experimental results show that high purity Ti₄AlN₃ bulk can be prepared from Ti, Al and TiN powders. With the holding time of 2 h and the sintering temperature of 1 400 ℃, high purity Ti₄AlN₃ can be obtained (w_Ti₄AlN₃=98.03%). Compared with other Max phases, the hardness of Ti₄AlN₃ is lower. With the increase of load, the hardness of Ti₄AlN₃ is close to 2.8 GPa.
- ceramic,
- Ti₄AlN₃,
- powder metallurgy method,
- sintering temperature,
- holding time,
- purity,
- hardness

FullText(HTML)

References(26)

References

[1]	Liu Yunlong, Zhu Degui, Hu Chunfeng. Preparation of Max phase coating by Max phase and spraying method[J]. Modern Technical Ceramics, 2017,38(1):21−28. (刘云龙, 朱德贵, 胡春峰. MAX相及喷涂法制备MAX相涂层[J]. 现代技术陶瓷, 2017,38(1):21−28.
[2]	Guo Qi. Microstructural analysis of Al₂O₃/Ti₂AlN composite materials[J]. Material Sciences, 2018,8(12):1088−1093. doi: 10.12677/MS.2018.812130
[3]	Chen Leilei, Deng Zixuan, Li Mian, et al. Phase diagram thermodynamic study of new Max phase[J]. Journal of Inorganic Materials, 2020,35(1):35−40. (陈雷雷, 邓子旋, 李勉, 等. 新型MAX相的相图热力学研究[J]. 无机材料学报, 2020,35(1):35−40.
[4]	Elodie Drouelle, Veronique Brunet, Jonathan Cormier, et al. Oxidation resistance of Ti₃AlC₂ and Ti₃Al_0.8Sn_0.2C₂ MAX phases: A comparison[J]. Journal of the American Ceramic Society, 2020,103(2):1270−1280. doi: 10.1111/jace.16780
[5]	Clark D W, Zinkle S J, Patel M K, et al. High temperature ion irradiation effects in MAX phase ceramics[J]. Acta Materialia, 2016,105:130−146. doi: 10.1016/j.actamat.2015.11.055
[6]	Gonzalez‐Julian J, Mauer G, Sebold D, et al. Cr₂AlC MAX phase as bond coat for thermal barrier coatings: Processing, testing under thermal gradient loading, and future challenges[J]. Journal of the American Ceramic Society, 2020,103(4):2362−2375. doi: 10.1111/jace.16935
[7]	Jin Sen, Su Taichao, Hu Qianku, et al. Thermal conductivity and electrical transport properties of double-A-layer MAX phase Mo₂Ga₂C[J]. Materials Research Letters, 2020,8(4):158−164. doi: 10.1080/21663831.2020.1724204
[8]	Sobolev K V, Kolincio K K, Emelyanov A, et al. Evolution of magnetic and transport properties in (Cr_1−xMn_x)₂AlCMAX-phase synthesized by arc melting technique[J]. Journal of Magnetism and Magnetic Materials, 2020,493:165642/1−7.
[9]	Xu J, Zhao M Q, Wang Y, et al. Demonstration of Li-ion capacity of MAX phases[J]. ACS Energy Letters, 2016,1(6):1094−1099. doi: 10.1021/acsenergylett.6b00488
[10]	Anasori B, Luhatskaya M R, Gogotsi Y. 2D metal carbides and nitrides(MXenes) for energy storage[J]. Nature Reviews Materials, 2017,2(2):1−17.
[11]	Hui Xiaobin, Ge Xiaoli, Zhao Ruizheng, et al. Interface chemistry on MXene‐based materials for enhanced energy storage and conversion performance[J]. Advanced Functional Materials, 2020,30(50):2005190/1−37.
[12]	Guo Z, Zhou J, Zhu L, et al. MXene: a promising photocatalyst for water splitting[J]. Journal of Materials Chemistry A. Materials for Energy and Sustainability, 2016,4(29):11446−11452. doi: 10.1039/C6TA04414J
[13]	Pang J, Mendes R G, Bachmatiuk A, et al. Applications of 2D MXenes in energy conversion and storage systems[J]. Chemical Society Reviews, 2019,48(1):72−133. doi: 10.1039/C8CS00324F
[14]	Wang Cong, Xu Jiawei, Wang Yunzheng, et al. MXene(Ti₂NT_x): Synthesis, characteristics and application as a thermo-optical switcher for all-optical wavelength tuning laser[J]. Science China Materials, 2020,64(1):1−7.
[15]	Yan Hanbing, Xu Jianguang, Wu Haijiang, et al. Synthesis of Ti₄AlN₃ powder by high energy ball milling combined with solid state reaction[J]. Mechanical Engineering Materials, 2014,38(2):36−38, 86. (严汉兵, 许剑光, 吴海江, 等. 高能球磨结合固相反应合成Ti₄AlN₃粉体[J]. 机械工程材料, 2014,38(2):36−38, 86.
[16]	Zhang Yanli. Study on microwave synthesis of titanium aluminum nitrogen materials[J]. Powder Metallurgy Technology, 2017,35(3):178−181, 201. (张艳丽. 微波合成钛铝氮材料的研究[J]. 粉末冶金技术, 2017,35(3):178−181, 201.
[17]	Wang Lei, Chen Nan. Preparation of Ti₂AlN ternary compound ceramics by optimizing powder metallurgy process[J]. Industrial Technology Innovation, 2017,4(3):100−101, 105. (王蕾, 陈楠. 优选粉末冶金工艺制备Ti₂AlN三元化合物陶瓷[J]. 工业技术创新, 2017,4(3):100−101, 105.
[18]	Muhammad Faraz Ud Din, Yang Chenhui, Tang Yi, et al. Efficient and cost-effective method to synthesize highly purified Ti₄AlN₃ and Ti₂AlN[J]. Journal of Advanced Dielectrics, 2019,9(1):1950008/1−4.
[19]	Yang Tengfei, Wang Chenxu, Liu Wulong, et al. Comparison of irradiation tolerance of two MAX phases-Ti₄AlN₃ and Ti₂AlN[J]. Journal of Nuclear Materials, 2018,513:120−128.
[20]	Firstov S A, Gorban V F, Pechkovskii I. Mechanical properties of porous Ti₃SiC₂/TiC, Ti₃AlC₂/TiC, and Ti₄AlN₃/TiN nanolaminates at 20 to 1 300 ℃[J]. Powder Metallurgy& Metal Ceramics, 2010,49(7-8):414−423.
[21]	Braverman B S, Lepakova O K, Maksimov Y M. Combustion of TiAl alloy in nitrogen[J]. Combustion Explosion & Shock Waves, 2015,51(4):457−461.
[22]	Barsoum M W, El-Raghy T, Procopio A. Synthesis of Ti₄AlN₃ and phase equilibria in the Ti-Al-N system[J]. Metallurgical and Materials Transactions A, 2000,31(2):373−378. doi: 10.1007/s11661-000-0273-1
[23]	Green L. Studies on the synthesis and microstructure of Ti₂AlN films and protective effect on ferritic steels[D]. Albert-Ludwigs University of Freiburg Doctoral Dissertation. 2020. (Grner L. Untersuchungen zur Synthese und Mikrostruktur von Ti₂AlN-Dünnschichten sowie deren Schutzwirkung auf ferritische Sthle[D]. Albert-Ludwigs-Universität FreiburgDoctoral Dissertation. 2020.)
[24]	Hossein-Zadeh M, Mirzaee O, Mohammadian-Semnani H. An investigation into the microstructure and mechanical properties of V₄AlC₃ MAX phase prepared by spark plasma sintering[J]. Ceramics International, 2019,45(6):7446−7457. doi: 10.1016/j.ceramint.2019.01.036
[25]	Zheng Liya, Zhou Yanchun, Feng Zhihai. Preparation, structure, properties and development trend of max phase ceramics[J]. Aerospace Materials Technology, 2013,43(6):1−23. (郑丽雅, 周延春, 冯志海. MAX相陶瓷的制备、结构、性能及发展趋势[J]. 宇航材料工艺, 2013,43(6):1−23. doi: 10.3969/j.issn.1007-2330.2013.06.001
[26]	Gu Jian, Jiang Xinyan, Guo Wenfei, et al. Research progress of ternary layered ceramics Nb₄AlC₃[J]. Jiangsu Ceramics, 2016,49(5):6−8, 19. (顾坚, 蒋鑫焱, 郭文飞, 等. 三元层状陶瓷Nb₄AlC₃的研究进展[J]. 江苏陶瓷, 2016,49(5):6−8, 19. doi: 10.3969/j.issn.1006-7337.2016.05.003