Research progress on V<sub>2</sub>O<sub>5 </sub> extraction from vanadium-bearing shale

Kang Xuanxiong; Ye Guohua; Zhu Siqin; Liang Xueyin

doi:10.7513/j.issn.1004-7638.2022.02.005

Volume 43 Issue 2

May 2022

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Article Navigation > IRON STEEL VANADIUM TITANIUM > 2022 > 43(2): 25-34

Kang Xuanxiong, Ye Guohua, Zhu Siqin, Liang Xueyin. Research progress on V2O5 extraction from vanadium-bearing shale[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(2): 25-34. doi: 10.7513/j.issn.1004-7638.2022.02.005

Citation:

Kang Xuanxiong, Ye Guohua, Zhu Siqin, Liang Xueyin. Research progress on V₂O₅ extraction from vanadium-bearing shale[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(2): 25-34. doi: 10.7513/j.issn.1004-7638.2022.02.005

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Research progress on V₂O₅ extraction from vanadium-bearing shale

doi: 10.7513/j.issn.1004-7638.2022.02.005

Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China

Received Date: 2022-01-14
Available Online: 2022-05-11
Publish Date: 2022-04-28

Abstract

Abstract

The main links of vanadium extraction from vanadium-bearing shale were introduced, including pre-enrichment, roasting, leaching, etc. The advantages and disadvantages of each step were analyzed and discussed. Pre-enrichment of vanadium-bearing shale can improve the grade of vanadium in the raw ore, reduce ore processing capacity, and increase the effective utilization of vanadium-bearing shale resources, but requires high ore properties. Roasting can effectively destroy the crystal structure of vanadium-bearing shale and promote the conversion of vanadium from low valence to high valence. Nevertheless, there are some problems such as low efficiency, high energy consumption and potential pollution. The direct acid leaching process can effectively extract vanadium in the form of adsorption from vanadium-containing shale, but the applicability to vanadium-bearing shale with isomorphism in the mica crystal lattice is poor. Recently new occurring leaching technologies, such as ultrasonic leaching, microwave leaching, microbial leaching, etc., can strengthen the destruction of the crystal structure of vanadium-bearing minerals. However, these processes have not been well used in industry at present due to limited development level of technology and equipment.
- vanadium extraction,
- vanadium-bearing shale,
- pre-enrichment,
- roasting,
- leaching

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References(57)

References

[1]	Wen Jing, Jiang Tao, Zhou Wanying, et al. A cleaner and efficient process for extraction of vanadium from high chromium vanadium slag: Leaching in (NH₄)₂SO₄-H₂SO₄ synergistic system and NH₄⁺ recycle[J]. Separation and Purification Technology, 2019,(216):126−130.
[2]	Hu Pengcheng, Zhang Yiming, Liu Tao, et al. Source separation of vanadium over iron from roasted vanadium-bearing shale during acid leaching via ferric fluoride surface coating[J]. J. Clean. Prod., 2018,(181):399−407.
[3]	Liu Zhixun, Dai Hongzhang, Liu Jia, et al. Current situation and suggestions on the exploration, development and utilization of stone coal resources in China[J]. China Mining, 2016,25(S1):18−21. (刘志逊, 代鸿章, 刘佳, 等. 我国石煤资源勘查开发利用现状及建议[J]. 中国矿业, 2016,25(S1):18−21.
[4]	Hu Yibo, Ye Guohua, Wang Heng, et al. Vanadium market analysis and progress of vanadium extraction process from stone coal[J]. Iron Steel Vanadium Titanium, 2019,40(2):31−40. (胡艺博, 叶国华, 王恒, 等. 钒市场分析与石煤提钒工艺进展[J]. 钢铁钒钛, 2019,40(2):31−40. doi: 10.7513/j.issn.1004-7638.2019.02.006
[5]	Hu Yangjia, Zhang Yimin, Bao Shenxu, et al. Effects of the mineral phase and valence of vanadium on vanadium extraction from stone coal[J]. International Journal of Minerals Metallurgy and Materials, 2012,19(10):893−898. doi: 10.1007/s12613-012-0644-9
[6]	Xue Nannan, Zhang Yimin, Liu Tao, et al. Mechanism of vanadium extraction from stone coal via hydrating and hardening of anhydrous calcium sulfate[J]. Hydrometallurgy, 2016,166:48−56. doi: 10.1016/j.hydromet.2016.08.013
[7]	张一敏, 包申旭, 刘涛, 等. 石煤提钒[M]. 北京: 科学出版社, 2014. Zhang Yimin, Bao Shenxu, Liu Tao, et al. Vanadium extractionfrom stone coal[M]. Beijing: Science Press, 2014.
[8]	He Dongsheng, Li Qiaoshuang, Yang Cong, et al. Experimental study on pre separation of vanadium bearing stone coal[J]. Nonferrous Metals Mining and Metallurgy, 2013,29(6):23−25. (何东升, 李巧双, 杨聪, 等. 含钒石煤预分选试验研究[J]. 有色矿冶, 2013,29(6):23−25. doi: 10.3969/j.issn.1007-967X.2013.06.008
[9]	Zhao Yunliang, Zhang Yimin, Liu Tao, et al. Pre-concentration of vanadium from stone coal by gravity separation[J]. International Journal of Mineral Processing, 2013,121:1−5. doi: 10.1016/j.minpro.2013.02.014
[10]	Bian Ying, Zhang Yimin, Zhao Yunliang, et al. Shaking table pre tailing test of a decarburized stone coal in Hubei[J]. Metal Mine, 2013,(1):94−96,150. (边颖, 张一敏, 赵云良, 等. 湖北某脱碳石煤摇床预抛尾试验[J]. 金属矿山, 2013,(1):94−96,150. doi: 10.3969/j.issn.1001-1250.2013.01.027
[11]	Wang Li, Sun Wei, Liu Runqing, et al. Flotation recovery of vanadium from low-grade stone coal[J]. Transactions of Nonferrous Metals Society of China, 2014,24(4):1145−1151. doi: 10.1016/S1003-6326(14)63173-3
[12]	Lu Keke, Shi Zhuoxiong. Experimental study on flotation preconcentration of a low-grade stone coal vanadium ore[J]. Modern Mining, 2019,35(6):20−22. (卢可可, 施卓雄. 某低品位石煤钒矿浮选预富集试验研究[J]. 现代矿业, 2019,35(6):20−22. doi: 10.3969/j.issn.1674-6082.2019.06.006
[13]	Yan Mingtao, Li Guang, Liu Zhichao. Experimental study on beneficiation process of a vanadium ore in Shaanxi[J]. Hydrometallurgy, 2013,32(5):293−296. (闫明涛, 李广, 刘志超. 陕西某钒矿石选矿工艺试验研究[J]. 湿法冶金, 2013,32(5):293−296.
[14]	Hu Yang, He Dongsheng, Xie Zhihao, et al. Research status of preconcentration technology of stone coal vanadium ore[J]. Metal Mine, 2018,(12):73−79. (胡洋, 何东升, 谢志豪, 等. 石煤型钒矿预富集技术研究现状[J]. 金属矿山, 2018,(12):73−79.
[15]	Wei Min, Wu Dongyin, Zhang Yanjiao. Experimental study on scrubbing beneficiation of Xichuan vanadium ore[J]. Mineral Protection and Utilization, 2007,(2):34−36. (卫敏, 吴东印, 张艳娇. 淅川钒矿擦洗选矿试验研究[J]. 矿产保护与利用, 2007,(2):34−36. doi: 10.3969/j.issn.1001-0076.2007.02.010
[16]	Chen Xiaoqing, Yang Jinzhong, Mao Yilin, et al. Study on new technology of comprehensive utilization of low-grade clay vanadium ore resources[J]. Nonferrous Metals (Beneficiation), 2010,(5):9−12. (陈晓青, 杨进忠, 毛益林, 等. 低品位黏土型钒矿资源综合利用新技术研究[J]. 有色金属(选矿部分), 2010,(5):9−12.
[17]	Chen Chun, Zhang Yimin, Bao Shenxu, et al. Separation and enrichment of vanadium from acid leaching solution of stone coal by tertiary amine N235[J]. Rare Metals, 2017,41(4):422−428. (谌纯, 张一敏, 包申旭, 等. 叔胺N235从石煤酸浸液中分离富集钒[J]. 稀有金属, 2017,41(4):422−428.
[18]	Lin Hai, Li Jie, Dong Yingbo. Effect of particle size on Static Leaching of heavy metals from stone coal vanadium ore waste[J]. Rare Metals, 2017,41(6):693−700. (林海, 李洁, 董颖博. 粒度对石煤钒矿废石重金属静态淋溶的影响规律[J]. 稀有金属, 2017,41(6):693−700.
[19]	Huang Jun, Zhang Yimin, Huang Jing, et al. Study on vanadium extraction and impurity reduction by cyclic pressurized acid leaching of stone coal calcined samples[J]. Rare Metals, 2017,41(6):701−708. (黄俊, 张一敏, 黄晶, 等. 石煤焙烧样循环加压酸浸提钒降杂研究[J]. 稀有金属, 2017,41(6):701−708.
[20]	Li Jie, Ma Jing. Study on mechanical beneficiation and tailing technology of black rock vanadium ore[J]. Nonferrous Metals (Beneficiation), 2010,(4):25−28. (李洁, 马晶. 黑色岩系钒矿的机械选矿抛尾工艺研究[J]. 有色金属(选矿部分), 2010,(4):25−28.
[21]	Liu Yuanchao, Wang Li, Sun Wei, et al. Experimental study on beneficiation of low-grade siliceous stone coal vanadium ore[J]. Nonferrous Metals (Beneficiation), 2016,(2):47−51,84. (刘源超, 王丽, 孙伟, 等. 低品位硅质石煤钒矿的选矿试验研究[J]. 有色金属(选矿部分), 2016,(2):47−51,84.
[22]	Liu Xin, Zhang Yimin, Liu Tao, et al. Combined weight flotation pre tailing test of a mica vanadium bearing stone coal in Hubei[J]. Metal Mine, 2017,(5):93−98. (刘鑫, 张一敏, 刘涛, 等. 湖北某云母型含钒石煤重—浮联合预抛尾试验[J]. 金属矿山, 2017,(5):93−98. doi: 10.3969/j.issn.1001-1250.2017.05.019
[23]	Fu Lipan, Zhang Yimin, Liu Tao, et al. Effect of acid-base additives on roasting effect of siliceous vanadium bearing shale[J]. Metal Mine, 2012,(1):111−114. (付利攀, 张一敏, 刘涛, 等. 酸碱性添加剂对硅质含钒页岩焙烧效果的影响[J]. 金属矿山, 2012,(1):111−114. doi: 10.3969/j.issn.1001-1250.2012.01.029
[24]	Peng Hao. A literature review on leaching and recovery of vanadium[J]. Journal of Environmental Chemical Engineering, 2019,7(5):103313−103313. doi: 10.1016/j.jece.2019.103313
[25]	Zou Jianjun, Liu Xiaoxing. Research status of vanadium extraction from stone coal[J]. Scientific and Technological Innovation and Application, 2015,(28):22−23. (邹建军, 刘小星. 石煤提钒工艺研究现状[J]. 科技创新与应用, 2015,(28):22−23.
[26]	Deng Qingyun, Liu Songying. Experimental study on a new process of extracting vanadium from stone coal by sodium roasting, acid leaching and ion exchange[J]. Rare Metals and Cemented Carbides, 1993,(4):27−33. (邓庆云, 刘松英. 石煤钠化焙烧、酸浸、离子交换提钒新工艺的试验研究[J]. 稀有金属与硬质合金, 1993,(4):27−33.
[27]	Shi Ling, Wang Juan, Xie Jianhong. Study on technological conditions of vanadium extraction by sodium process[J]. Mining and Metallurgy Engineering, 2008,(1):58−61. (史玲, 王娟, 谢建宏. 钠化法提钒工艺条件的研究[J]. 矿冶工程, 2008,(1):58−61. doi: 10.3969/j.issn.0253-6099.2008.01.016
[28]	Zhang Yimin, Hu Yangjia, Bao Shenxu, et al. Vanadium emission during roasting of vanadium-bearing stone coal in chlorine[J]. Minerals Engineering, 2012,30:95−98. doi: 10.1016/j.mineng.2012.02.003
[29]	Zhang Ying, Zhang Ting^,an, David Dreisinger, et al. Recovery of vanadium from calcification roasted-acid leaching tailing by enhanced acid leaching[J]. Journal of Hazardous Materials, 2019,369:632−641. doi: 10.1016/j.jhazmat.2019.02.081
[30]	Wen Jing, Jiang Tao, Zhou Mi. Roasting and leaching behaviors of vanadium and chromium in calcification roasting–acid leaching of high-chromium vanadium slag[J]. International Journal of Minerals Metallurgy and Materials, 2018,25(5):515−526. doi: 10.1007/s12613-018-1598-3
[31]	Peng Hao, Guo Jing, Zheng Xiaogang, et al. Leaching kinetics of vanadium from calcification roasting converter vanadium slag in acidic medium[J]. Journal of Environmental Chemical Engineering, 2018,6(4):5119−5124. doi: 10.1016/j.jece.2018.08.003
[32]	汪博. 钙质焙烧添加剂对页岩提钒过程的影响及机理研究[D]. 武汉: 武汉科技大学, 2017. Wang Bo. Effect and mechanism of calcium roasting additives on vanadium extraction from shale[D] . Wuhan: Wuhan University of Science and Technology, 2017.
[33]	Zhang Xiaogang, Gao Yongbo, Xu Qiang, et al. Experimental study on alkali leaching of vanadium from stone coal vanadium ore by calcification roasting[J]. Applied Chemical Industry, 2013,42(6):1026−1028,1032. (张晓刚, 高永波, 徐强, 等. 石煤钒矿钙化焙烧碱浸提钒工艺的实验研究[J]. 应用化工, 2013,42(6):1026−1028,1032.
[34]	Zhang Yimin, Bao Shenxu, Liu Tao, et al. Thetechnology of extracting vanadium from stone coal in China: history, current status and future prospects[J]. Hydrometallurgy, 2011,109(1):116−124.
[35]	王学文, 王明玉, 李青刚, 等. 一种石煤提钒矿石分解方法: 中国, CN101260464[P]. 2008-09-10. Wang Xuewen, Wang Mingyu, Li Qinggang, et al. A decomposition method for extracting vanadium from stone coal: China, CN101260464 [P]. 2008-09-10.
[36]	Liang Huanlong, Xie Yingbang, He Hangjun, et al. A new process for extracting vanadium pentoxide from stone coal by sulfation and microwave roasting[J]. Nonferrous Metals (Smelting part), 2015,(8):39−42. (梁焕龙, 谢营邦, 何航军, 等. 石煤硫酸化微波焙烧提取五氧化二钒新工艺[J]. 有色金属(冶炼部分), 2015,(8):39−42.
[37]	Ye Guohua, Xie Yu, Hu Yibo, et al. Study on low temperature sulfation roasting water leaching of vanadium from low-grade stone coal vanadium ore[J]. Rare Metals, 2020,44(7):753−761. (叶国华, 谢禹, 胡艺博, 等. 低品位石煤钒矿低温硫酸化焙烧-水浸提钒研究[J]. 稀有金属, 2020,44(7):753−761.
[38]	何东升, 张泽强, 张汉泉, 等. 一种从含钒石煤中提取五氧化二钒的复合焙烧添加剂及其应用: 中国, CN102296192A[P]. 2011-12-28. He Dongsheng, Zhang Zeqiang, Zhang Hanquan, et al. A composite roasting additive for extracting vanadium pentoxide from vanadium bearing stone coal and its application: China, CN102296192A[P]. 2011-12-28.
[39]	Gao Feng, Hua Jun, Yan Wenbin, et al. Vanadium extraction process by clean roasting of stone coal[J]. Nonferrous Metal Engineering, 2020,10(5):44−48. (高峰, 华骏, 颜文斌, 等. 石煤清洁焙烧提钒工艺[J]. 有色金属工程, 2020,10(5):44−48. doi: 10.3969/j.issn.2095-1744.2020.05.009
[40]	Zhang Chengqiang, Sun Chuanyao, Yin Wanzhong, et al. Study on vanadium extraction process by roasting combined leaching of a illite vanadium bearing coal mine stone composite additive[J]. Metal Mine, 2018,(10):92−97. (张成强, 孙传尧, 印万忠, 等. 某伊利石型含钒石煤矿石复合添加剂焙烧—联合浸出提钒工艺研究[J]. 金属矿山, 2018,(10):92−97.
[41]	蒋谋锋. 云母型含钒石煤空白焙烧酸浸提钒机理研究[D]. 武汉: 武汉理工大学, 2015. Jiang Moufeng. Study on mechanism of vanadium extraction from mica vanadium bearing stone coal by blank roasting acid [D] . Wuhan: Wuhan University of Technology, 2015.
[42]	Pan Zhankai, Li Qingchun, Ye Shufeng, et al. Study on blank roasting leaching process of Fangshankou stone coal vanadium ore[J]. Computer and Applied Chemistry, 2014,31(12):1557−1560. (潘占开, 李青春, 叶树峰, 等. 方山口石煤钒矿空白焙烧—助浸剂浸出工艺研究[J]. 计算机与应用化学, 2014,31(12):1557−1560.
[43]	Zhang Bo, Gao Zhaoguo, Liu Hongzhao, et al. Directacid leaching of vanadium from stone coal[J]. High Temperature Materials and Processes, 2017,36(9):877−883. doi: 10.1515/htmp-2016-0055
[44]	何伟. 粘土钒矿不磨不焙烧常压活化酸浸提钒的研究[D]. 昆明: 昆明理工大学, 2014. He Wei. Study on extraction of vanadium from clay vanadium ore by atmospheric pressure activated acid without grinding or roasting [D]. Kunming: Kunming University of Technology, 2014.
[45]	He Dongsheng, Li Qiaoshuang, Zhang Jiangang, et al. Study on leaching process of vanadium bearing stone coal flotation concentrate[J]. Rare Metals and Cemented Carbides, 2016,44(6):7−9. (何东升, 李巧双, 张建刚, 等. 含钒石煤浮选精矿浸出工艺研究[J]. 稀有金属与硬质合金, 2016,44(6):7−9.
[46]	Li Xin, Wang Yi, Zhu Jun. Study on direct acid leaching of vanadium from low-grade vanadium ore[J]. Iron Steel Vanadium Titanium, 2010,31(3):10−14. (李欣, 王毅, 朱军. 低品位钒矿直接酸浸提钒工艺研究[J]. 钢铁钒钛, 2010,31(3):10−14. doi: 10.7513/j.issn.1004-7638.2010.03.003
[47]	Zhang Xiaoyun, Yang Kang, Tian Xueda, et al. Vanadium leaching from carbonaceous shale using fluosilicic acid[J]. International Journal of Mineral Processing, 2011,100(3):184−187.
[48]	Zhang Chengqiang, Sun Chuanyao, Yin Wanzhong, et al. Acid leaching process of vanadium from a certain illite vanadium bearing stone coal with calcium fluoride as leaching aid[J]. Comprehensive Utilization of Minerals, 2019,(5):42−47. (张成强, 孙传尧, 印万忠, 等. 以氟化钙为助浸剂的某伊利石型含钒石煤酸浸提钒工艺[J]. 矿产综合利用, 2019,(5):42−47. doi: 10.3969/j.issn.1000-6532.2019.05.009
[49]	Tian Lei, Xu Zhifeng, Chen Lijie, et al. Effect of microwave heating on the pressure leaching of vanadium from converter slag[J]. Hydrometallurgy, 2018,184:45−54.
[50]	Huang Jun, Zhang Yimin, Huang Jing, et al. Study on roasting-pressure acid leaching of vanadium from stone coal[J]. Metal Mine, 2015,(10):85−89. (黄俊, 张一敏, 黄晶, 等. 石煤焙烧—加压酸浸提钒研究[J]. 金属加工, 2015,(10):85−89.
[51]	Deng Zhigan, Wei Chang, Fan Gang, et al. Extracting vanadium from stone-coal by oxygen pressure acid leaching and solvent extraction[J]. Transactions of Nonferrous Metals Society of China, 2010,20:118−122. doi: 10.1016/S1003-6326(10)60024-6
[52]	杨德芹. 石煤硫酸化焙烧—超声浸出提钒工艺的研究[D]. 绵阳: 西南科技大学, 2015. Yang Deqin. Study on extraction of vanadium from stone coal by sulfation roasting ultrasonic leaching[D] . Mianyang: Southwest University of Science and Technology, 2015.
[53]	Chen Bo, Bao Shenxu, Zhang Yimin, et al. A high-efficiency and sustainable leaching process of vanadium from shale in sulfuric acid systems enhanced by ultrasound[J]. Separation and Purification Technology, 2020,240(C):1−9.
[54]	Ouyang Guoqiang, Zhang Xiaoyun, Tian Xueda, et al. Effect of microwave roasting on vanadium extraction from stone coal[J]. Chinese Journal of Nonferrous Metals, 2008,(4):750−754. (欧阳国强, 张小云, 田学达, 等. 微波焙烧对石煤提钒的影响[J]. 中国有色金属学报, 2008,(4):750−754. doi: 10.3321/j.issn:1004-0609.2008.04.031
[55]	Li Yinli, Song Yonghui, Wang Kepeng, et al. Study on vanadium extraction from stone coal by microwave leaching[J]. Nonferrous Metals (Smelting part), 2016,(3):36−39. (李银丽, 宋永辉, 王科鹏, 等. 石煤微波浸出提钒工艺研究[J]. 有色金属(冶炼部分), 2016,(3):36−39.
[56]	Lin Hai, Wang Xin, Dong Yingbo, et al. Effect of heterotrophic bacteria on microbial leaching of vanadium bearing stone coal[J]. Rare Metals, 2017,41(9):1050−1055. (林海, 王鑫, 董颖博, 等. 异养细菌对含钒石煤微生物浸出效果的研究[J]. 稀有金属, 2017,41(9):1050−1055.
[57]	杨盟. 生物浸出法从含钒矿物中提取钒及选择性吸附富集研究[D]. 北京: 中国地质大学(北京), 2018. Yang Meng. Study on extraction of vanadium from vanadium bearing minerals by bioleaching and selective adsorption enrichment [D]. Beijing: China University of Geosciences (Beijing), 2018.