Preparation of lithium vanadate by solution combustion synthesis and its electrochemical properties

Chen Zongling; Cao Zhiqin; He Kui; Zhang Xuefeng

doi:10.7513/j.issn.1004-7638.2022.03.004

Volume 43 Issue 3

Jun. 2022

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Chen Zongling, Cao Zhiqin, He Kui, Zhang Xuefeng. Preparation of lithium vanadate by solution combustion synthesis and its electrochemical properties[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(3): 20-25. doi: 10.7513/j.issn.1004-7638.2022.03.004

Citation:

Chen Zongling, Cao Zhiqin, He Kui, Zhang Xuefeng. Preparation of lithium vanadate by solution combustion synthesis and its electrochemical properties[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(3): 20-25. doi: 10.7513/j.issn.1004-7638.2022.03.004

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Preparation of lithium vanadate by solution combustion synthesis and its electrochemical properties

doi: 10.7513/j.issn.1004-7638.2022.03.004

Chen Zongling¹,
Cao Zhiqin^{1, 2
,
,},
He Kui¹,
Zhang Xuefeng^{1, 3}

1.
College of Vanadiun and Titanium, Panzhihua University, Panzhihua 617000, Sichuan, China
2.
Vanadium and Titanium Resource Comprehensive Utilization Key Laboratory of Sichuan Province, Panzhihua 617000, Sichuan, China
3.
Sichuan Vanadiun & Titanium Industrial Technology Institute, Panzhihua 617000, Sichuan, China

Received Date: 2022-04-19
Publish Date: 2022-06-30

Abstract

Abstract

Using ammonium nitrate, ammonium metavanadate, lithium nitrate, glucose, citric acid and glycine as raw materials, LiVO₃ powder as cathode material for lithium-ion battery was successfully prepared by solution combustion synthesis. The effects of calcination temperature and calcination time on the preparation of LiVO₃ were investigated. The as-prepared LiVO₃ powder was used as active material for battery assembly, and its electrochemical performance as cathode material for lithium-ion battery was further explored. The results show that the LiVO₃ powder prepared at 400 ℃ for 1 h has the best electrochemical performance. At the charge discharge rate of 0.1 A/g, the first discharge specific capacity of the battery is 244.3 mAh/g, and after 50 cycles, the discharge specific capacity retains 193.6 mAh/g.
- lithium vanadate,
- lithium-ion battery,
- cathode material,
- solution combustion method,
- electrochemical performance

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References(13)

References

[1]	冀京润. 基于分数阶模型的锂离子电池参数辨识与荷电状态估计研究[D]. 西安: 西安理工大学, 2021. Ji Jingrun. Research on parameter identification and state of charge estimation of lithium ion battery based on fractional order model [D] . Xi'an: Xi'an University of Technology, 2021.
[2]	Dong Jingwei, Li Zhe, Zhang Bo, et al. Research progress in synthesis and modification of lithium vanadium phosphate cathode materials[J]. Guangzhou Chemical Industry, 2022,50(6):24−27. (董经纬, 李喆, 张博, 等. 磷酸钒锂正极材料的合成与改性研究进展[J]. 广州化工, 2022,50(6):24−27. doi: 10.3969/j.issn.1001-9677.2022.06.009 Dong Jingwei, Li Zhe, Zhang Bo, et al. Research progress in synthesis and modification of lithium vanadium phosphate cathode materials [J] . Guangzhou Chemical Industry, 2022, 50 (6): 24-27. doi: 10.3969/j.issn.1001-9677.2022.06.009
[3]	王韵珂. 锂离子电池高镍正极材料的合成、改性及电化学性能研究[D]. 昆明: 昆明理工大学, 2021. Wang Yunke. Synthesis, modification and electrochemical properties of high nickel cathode materials for lithium ion batteries [D]. Kunming: Kunming University of Science and Technology, 2021.
[4]	Wang Hao, Li Junfeng, Ma Yue, et al. Research progress of vanadium based electrode materials for lithium ion batteries[J]. Material Guide, 2021,35(21):21127−21142. (王皓, 李峻峰, 马悦, 等. 锂离子电池钒系电极材料的研究进展[J]. 材料导报, 2021,35(21):21127−21142. Wang Hao, Li Junfeng, Ma Yue, et al. Research progress of vanadium based electrode materials for lithium ion batteries [J] . Material Guide, 2021, 35 (21): 21127-21142.
[5]	Zhou Hongkong, Xiao Shanshan, Hou Wanjun, et al. Study on vanadium oxide as electrode material for lithium ion battery[J]. Chemical Technology and Development, 2021,50(6):41−45. (周香港, 肖姗姗, 侯婉君, 等. 钒氧化物作为锂离子电池电极材料的研究[J]. 化工技术与开发, 2021,50(6):41−45. doi: 10.3969/j.issn.1671-9905.2021.06.011 Zhou Hongkong, Xiao Shanshan, Hou Wanjun, et al. Study on vanadium oxide as electrode material for lithium ion battery [J]. Chemical Technology and Development, 2021, 50 (6): 41-45. doi: 10.3969/j.issn.1671-9905.2021.06.011
[6]	刘培琦. 堆垛结构富锂锰基正极材料Li_1.2Mn_0.54Ni_0.13Co_0.13O₂的制备和改性研究[D]. 深圳: 深圳大学, 2019. Liu Peiqi. Preparation and modification of lithium rich-manganese-based cathode materialS Li_1.2Mn_0.54Ni_0.13Co_0.13O₂[D]. Shenzhen: Shenzhen University, 2019.
[7]	Pralong V, Gopal V, Caignaert V, et al. Lithium-rich rock-salt-type vanadate as energy storage cathode: Li₂xVO₃[J]. Chemistry of Materials, 2011,24(1):12−14.
[8]	陈重学, 杨汉西, 艾新平, 等. 锂离子电池LiVO₃正极材料的改性研究[C]//第18届全国固态离子学学术会议暨国际电化学储能技术论坛论文集. 桂林: 中国硅酸盐学会固态离子学分会, 2016: 274. Chen Chongxue, Yang Hanxi, Ai Xinping, et al. Lithium ion battery LiVO₃ study on modification of cathode materials [C] / / Proceedings of the 18th National Conference on Solid State Ionics and International Electrochemical Energy Storage Technology Forum. Guilin: CSSI, 2016: 274.
[9]	Yan Danlin, Zeng Yingying. Prepared of cathode material LiVO₃ for lithium ion battery by sol gel method[J]. Guangdong Chemical Industry, 2019,46(14):15−16. (严丹林, 曾瑛英. 锂离子电池正极材料LiVO₃的溶胶凝胶法制备[J]. 广东化工, 2019,46(14):15−16. doi: 10.3969/j.issn.1007-1865.2019.14.008 Yan Danlin, Zeng Yingying. Prepared of cathode material LiVO_3 for lithium ion battery by sol gel method[J]. Guangdong Chemical Industry, 2019, 46 (14): 15-16. doi: 10.3969/j.issn.1007-1865.2019.14.008
[10]	郭广志. 层状结构LiV₃O₈正极材料的合成及其改性研究[D]. 大连: 大连海事大学, 2020. Guo Guangzhi. Layered structure LiV₃O₈ synthesis and modification of cathode materials[D]. Dalian: Dalian Maritime University, 2020.
[11]	孙永伟. 电极材料Li₃VO₄的制备及其电化学性能研究[D]. 秦皇岛: 燕山大学, 2020. Sun Yongwei. Study on preparation and electrochemical properties of Li₃VO₄ for electrode material[D]. Qinghuangdao: Yanshan University, 2020.
[12]	Ren Junfeng, Wang Haibing, Cao Haijing, et al. Preparation of MnSn(OH)₆ nano cubic electrode materials with carbon doped and their electrochemical properties in supercapacitors[J]. Micro Nano Electronic Technology, 2022,59(4):322−327, 378. (任俊锋, 王海兵, 曹海静, 等. 碳掺杂MnSn(OH)₆纳米立方电极材料的制备及其在超级电容器中的电化学性能[J]. 微纳电子技术, 2022,59(4):322−327, 378. doi: 10.13250/j.cnki.wndz.2022.04.004 Ren Junfeng, Wang Haibing, Cao Haijing, et al. Preparation of MnSn (OH)_6 nano cubic electrode materials with carbon doped and their electrochemical properties in supercapacitors [J] . Micro Nano Electronic Technology, 2022, 59 (4): 322-327 , 378. DOI: 10.13250/j.cnki.wndz.2022.04.004.
[13]	Zong Wenhui. Preparation and electrochemical properties of two kinds of graphene oxide and cobalt ferrite composites[J]. Fiber Composite, 2022,39(1):65−71,104. (宗文辉. 两种氧化石墨烯与铁酸钴复合材料的制备及电化学性能[J]. 纤维复合材料, 2022,39(1):65−71,104. Zong Wenhui. Preparation and electrochemical properties of two kinds of graphene oxide and cobalt ferrite composites [J] . Fiber Composite, 2022, 39 (1): 65-71 , 104.