Volume 43 Issue 3
Jun.  2022
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Wang Haibo, Sun Ke, Cheng Xiaozhe, Wang Bin, Wu Xiaoping. Effect of biomass drying titanium concentrate on its acid hydrolysis performance[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(3): 33-39. doi: 10.7513/j.issn.1004-7638.2022.03.006
Citation: Wang Haibo, Sun Ke, Cheng Xiaozhe, Wang Bin, Wu Xiaoping. Effect of biomass drying titanium concentrate on its acid hydrolysis performance[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(3): 33-39. doi: 10.7513/j.issn.1004-7638.2022.03.006

Effect of biomass drying titanium concentrate on its acid hydrolysis performance

doi: 10.7513/j.issn.1004-7638.2022.03.006
  • Received Date: 2022-02-28
  • Publish Date: 2022-06-30
  • In view of the decline of acid hydrolysis performance of titanium concentrate directly dried by biomass, the influence of different drying methods on acid hydrolysis performance of titanium concentrate were found by comparing the difference of acid hydrolysis performance of titanium concentrate, and the exploration test of improving acid hydrolysis performance was carried out. The results show that after a small amount of biomass fuel and its combustion residues mixed into the titanium concentrate directly dried by biomass fuel, the acid hydrolysis rate and the filtration rate of titanium liquid in the titanium concentrate are lower than that of the titanium concentrate directly dried by coal gas. The larger the mixed amount, the greater the drop in the acid hydrolysis rate and the filtration rate of titanium liquid. When the C content of direct-drying titanium concentrate with biomass is 4 times that of the direct-drying titanium concentrate with coal gas and keep the conditions of reaction acid-ore ratio increasing 0.02, reaction acid concentration increasing 2%, ripening temperature increasing 10 °C and ripening time increasing 1 h, the acid hydrolysis rate of titanium concentrate dried by biomass fuel is 93.00%, which is higher than 90.91% of titanium concentrate dried by coal gas. But the extraction rate of 100 mL titanium liquid is 615 s lower than 122 s of the latter. With the increase of acid hydrolysis rate, the pumping speed of titanium liquid decreases. The titanium concentrate directly dried by biomass fuel and coal gas are mixed according to the mass ratio of 5:95, the acid hydrolysis rate of titanium concentrate and the filtration rate of titanium liquid are almost the same as those of gas-drying titanium concentrate.
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  • [1]
    Karimia L, Yazdanshenas M E, Khajavi R, et al. Optimizing the photocatalytic properties and the synergistic effects of graphene and nano titanium dioxide immobilized on cotton fabric[J]. Applied Surface Science, 2015,332:665−673. doi: 10.1016/j.apsusc.2015.01.184
    [2]
    Romanovska N I, Manoryk P A, Ermokhina N I, et al. Effect of structural and dimensional characteristics of TiO2 and its photocatalytic activity in the oxidation of tetracycline[J]. Theoretical and Experimental Chemistry, 2019,55(5):345−353. doi: 10.1007/s11237-019-09627-0
    [3]
    Sobczyk-guzenda Anna, Szymanski Witold, Jedrzejczak Anna, et al. Bactericidal and photowetting effects of titanium dioxide coatings doped with iron and copper/fluorine deposited on stainless steel substrates[J]. Surface & Coatings Technology, 2018,347:66−75.
    [4]
    Matsukura A, Onoda H. Influences of additives on phosphoric acid treatment of titanium dioxide as a novel white pigment[J]. Journal of Advanced Ceramics, 2015,4(3):211−216. doi: 10.1007/s40145-015-0151-3
    [5]
    Kang J, Okabe T H. Removal of iron from titanium ore by selective chlorination using TiCl4 under oxygen content atmosphere[J]. International Journal of Mineral Processing, 2016,149:111−118. doi: 10.1016/j.minpro.2016.02.014
    [6]
    Bi Sheng. Status of titanium dioxide industry in China and the development prospect[J]. Iron Steel Vanadium Titanium, 2021,42(2):1−4. (毕胜. 近年中国钛白粉行业基本状况及发展展望[J]. 钢铁钒钛, 2021,42(2):1−4. doi: 10.7513/j.issn.1004-7638.2021.02.001

    Bi Sheng. In recent years, the basic situation and development prospect of titanium dioxide industry in China [J]. Iron Steel Vanadium Titanium, 2021, 42 (2): 1-4. doi: 10.7513/j.issn.1004-7638.2021.02.001
    [7]
    Sneha, Samal. Synthesis and characterization of titanium slag from ilmenite by thermal plasma processing[J]. Journal of Metals, 2016,68(9):1−10.
    [8]
    Hu Kai, Zhang Run, Li Shengping, et al. Conductivity and melt structure of TiO2-FeO-X ( SiO2, CaO, MgO ) ternary high titanium slag[J]. China Journal of Nonferrous Metals, 2019,29(1):167−175. (胡凯, 张润, 李生平, 等. TiO2-FeO-X(SiO2, CaO, MgO)三元高钛渣导电特性及其熔体结构[J]. 中国有色金属学报, 2019,29(1):167−175.

    Hu Kai, Zhang Run, Li Shengping, et al. Conductivity and melt structure of TiO2-FeO-X ( SiO2, CaO, MgO ) ternary high titanium slag [J]. China Journal of Nonferrous Metals, 2019, 29 (1) : 167-175.
    [9]
    Lu Changyuan, Zou Xingli, Lu Xionggang, et al. Hydrogen reduction kinetics of Panzhihua ilmenite[J]. The Chinese Journal of Nonferrous Metals, 2016,26(12):3266−3273. doi: 10.1016/S1003-6326(16)64460-6
    [10]
    Wu Ling, Chen Jiabin, Zhong Shengkui, et al. Effect of mechanical activation-hydrochloric acid atmospheric leaching of ilmenite[J]. China Journal of Nonferrous Metals, 2015,25(1):211−219. (伍凌, 陈嘉彬, 钟胜奎, 等. 机械活化-盐酸常压浸出钛铁矿的影响[J]. 中国有色金属学报, 2015,25(1):211−219. doi: 10.1016/S1003-6326(15)63598-1

    Wu Ling, Chen Jiabin, Zhong Shengkui, et al. Effect of mechanical activation-hydrochloric acid atmospheric leaching of ilmenite [J]. China Journal of Nonferrous Metals, 2015, 25(1): 211-219. doi: 10.1016/S1003-6326(15)63598-1
    [11]
    Li Yu, Lei Ying, Zhang Libo, et al. Microwave drying characteristics and kinetics of titanium concentrate[J]. Transactions of Nonferrous Metals Society of China, 2011,21(1):202−207. doi: 10.1016/S1003-6326(11)60700-0
    [12]
    Cai Ning, Chen Chaochun, Wang Yafu, et al. Heat transfer characteristics of vibrating fluidized bed for fine titanium concentrate[J]. Iron Steel Vanadium Titanium, 2001,22(2):33−36. (蔡宁, 陈朝春, 王亚夫, 等. 微细粒级钛精矿振动流化床的传热特性[J]. 钢铁钒钛, 2001,22(2):33−36. doi: 10.3969/j.issn.1004-7638.2001.02.006

    Cai Ning, Chen Chaochun, Wang Yafu, et al. Heat transfer characteristics of vibrating fluidized bed for fine titanium concentrate [J]. Iron Steel Vanadium Titanium , 2001 , 22(2): 33-36. doi: 10.3969/j.issn.1004-7638.2001.02.006
    [13]
    Sun Yu, Meng Changfang. Study on NO emission characteristics of biomass/bituminous coal powder fuel under air staged combustion[J]. Energy and Environmental Protection, 2021,43(10):1−6. (孙禹, 孟长芳. 生物质/烟煤粉体燃料在空气分级燃烧下NO排放特性研究[J]. 能源与环保, 2021,43(10):1−6.

    Sun Yu, Meng Changfang. Study on NO emission characteristics of biomass/bituminous coal powder fuel under air staged combustion [J]. Energy and Environmental Protection, 2021, 43 (10): 1-6.
    [14]
    Li Xian, Han Kuihua, Wang Xi, et al. Research progress of biomass briquette fuel additives[J]. Renewable Energy, 2021,39(12):1563−1569. (李贤, 韩奎华, 王茜, 等. 生物质成型燃料添加剂的研究进展[J]. 可再生能源, 2021,39(12):1563−1569. doi: 10.3969/j.issn.1671-5292.2021.12.001

    Li Xian, Han Kuihua, Wang Xi, et al. Research progress of biomass briquette fuel additives [J]. Renewable Energy, 2021, 39 (12): 1563-1569. doi: 10.3969/j.issn.1671-5292.2021.12.001
    [15]
    Liu Yufei, Tang Jie, Chen Xiaohui, et al. Estimation of thermodynamic properties of complex fuels[J]. Journal of Engineering Thermophysics, 2021,42(11):2775−2779. (刘宇飞, 唐洁, 陈小辉, 等. 复杂燃料热力学性质的估算研究[J]. 工程热物理学报, 2021,42(11):2775−2779.

    Liu Yufei, Tang Jie, Chen Xiaohui, et al. Estimation of thermodynamic properties of complex fuels [J]. Journal of Engineering Thermophysics, 2021, 42 (11) : 2775-2779.
    [16]
    Richard G Haverkamp, Desiderius Kruger, Ranjeeth Rajashekar. The digestion of New Zealand ilmenite by hydrochloric acid[J]. Hydrometallurgy, 2016,163:198−203. doi: 10.1016/j.hydromet.2016.04.015
    [17]
    Jonglertjunya, Woranart, Rattanaphan, et al. Kinetics of the dissolution of ilmenite in oxalic and sulfuric acid solutions[J]. Asia-Pacific Journal of Chemical Engineering, 2014,9(1):24−30. doi: 10.1002/apj.1742
    [18]
    Parapari, ParisaSemsari, Irannajad, et al. Modification of ilmenite surface properties by superficial dissolution method[J]. Minerals Engineering, 2016,9(2):160−167.
    [19]
    Wang Haibo, Wu Xiaoping, Gao Jian, et al. Kinetics of sulfuric acid leaching of ilmenite[J]. Iron Steel Vanadium Titanium, 2020,41(6):6−10. (王海波, 吴小平, 高健, 等. 硫酸浸取钛铁矿动力学研究[J]. 钢铁钒钛, 2020,41(6):6−10. doi: 10.7513/j.issn.1004-7638.2020.06.002

    Wang Haibo, Wu Xiaoping, Gao Jian, et al. Kinetics of sulfuric acid leaching of ilmenite[J]. Iron Steel Vanadium Titanium , 2020, 41 (6): 6-10. doi: 10.7513/j.issn.1004-7638.2020.06.002
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