Volume 44 Issue 5
Oct.  2023
Turn off MathJax
Article Contents
Teng Fei, Guo Peimin, Zhu Deqing, Long Hongming, Li Kai, Wang Lei, Kong Lingbing. A new low carbon high value route for hydrogen reduction of zinc containing dust[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(5): 98-104. doi: 10.7513/j.issn.1004-7638.2023.05.015
Citation: Teng Fei, Guo Peimin, Zhu Deqing, Long Hongming, Li Kai, Wang Lei, Kong Lingbing. A new low carbon high value route for hydrogen reduction of zinc containing dust[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(5): 98-104. doi: 10.7513/j.issn.1004-7638.2023.05.015

A new low carbon high value route for hydrogen reduction of zinc containing dust

doi: 10.7513/j.issn.1004-7638.2023.05.015
  • Received Date: 2023-05-29
    Available Online: 2023-11-04
  • Publish Date: 2023-10-31
  • In this paper, the theory and technology of comprehensive utilization of zinc containing dust in steel plants at home and abroad are analyzed. The pyrometallurgical process is based on high-temperature carbon metallurgy with coal carrier. High energy consumption, enlarged carbon emission and serious pollution are its common problems that are difficult to avoid. At the same time, it also produces new problems such as high energy consumption and heavy environmental load caused by the recovery and utilization of secondary zinc oxide. According to the research experience of the research team and combined with the new requirements for low carbon at home and abroad, this paper puts forward a new technical idea of high-value utilization of low-carbon emission by hydrogen reduction: Iron and valuable metals such as zinc, lead and bismuth in zinc containing dust are reduced by hydrogen reduction, and the reduced zinc, lead and bismuth are taken away by hydrogen carrier in the form of gas to realize the separation of metal iron and non-ferrous metals. Non-ferrous metals such as zinc and lead are separated from hydrogen containing flue gas by step condensation. The preparation of pellets from zinc containing dust, hydrogen reduction theory and testing, theoretical analysis of zinc containing steam separation and metal ferromagnetic separation have been carried out, which provides a feasible and solid foundation for the proposal of this technical idea. The new technology is promising to realize low-carbon smelting of zinc containing dust in steel plants, and can also obtain metal zinc and other metal products with higher added value.
  • loading
  • [1]
    Antunano N, Cambra J F, Arias P L. Hydrometallurgical processes for Waelz oxide valorisation - An overview[J]. Process Safety and Environmental Protection, 2019,129:308−320. doi: 10.1016/j.psep.2019.06.028
    [2]
    She Xuefeng, Xue Qingguo, Wang Jingsong, et al. Comparison of zinc-bearing dust comprehensive utilization and treatment processes in iron and steel plant[J]. Ironmaking, 2010,29(4):56−62. (佘雪峰, 薛庆国, 王静松, 等. 钢铁厂含锌粉尘综合利用及相关处理工艺比较[J]. 炼铁, 2010,29(4):56−62.

    She Xuefeng, Xue Qingguo, Wang Jingsong, et al. Comparison of zinc-bearing dust comprehensive utilization and treatment processes in iron and steel plant [J]. Ironmaking, 2010, 29(4): 56-62.
    [3]
    Lv W, Gan M, Fan X H, et al. Recycling utilization of zinc-bearing metallurgical dust by reductive sintering: Reaction behavior of zinc oxide[J]. JOM, 2019,71(9):3173−3180. doi: 10.1007/s11837-019-03645-y
    [4]
    Zhang Shourong, Zhang Weidong. Solid waste resources treatment mode and development tendency of iron and steel enterprises in China[J]. Iron and Steel, 2017,52(4):1−6. (张寿荣, 张卫东. 中国钢铁企业固体废弃物资源化处理模式和发展方向[J]. 钢铁, 2017,52(4):1−6.

    Zhang Shourong, Zhang Weidong. Solid waste resources treatment mode and development tendency of iron and steel enterprises in China [J]. Iron and Steel, 2017, 52(4): 1-6.
    [5]
    Xu Lejiang. Face the challenge and achieve the transformation from a big steel country to a powerful steel country[J]. China Steel, 2012,(5):7−10. (徐乐江. 直面挑战—实现转型—由钢铁大国走向钢铁强国[J]. 中国钢铁业, 2012,(5):7−10.

    Xu Lejiang. Face the challenge and achieve the transformation from a big steel country to a powerful steel country [J]. China Steel, 2012(5): 7-10.
    [6]
    Zurner P, Frisch G. Leaching and selective extraction of indium and tin from zinc flue dust using an oxalic acid-based deep eutectic solvent[J]. ACS Sustainable Chemistry & Engineering, 2019,7(5):5300−5308.
    [7]
    Zhu Yaoping. Practice of recovery indium zinc and bismuth from gas ash from blast furnace[J]. Nonferrous Metals (Extractive Metallurgy), 2009,(6):14−16. (朱耀平. 高炉瓦斯灰中铟锌铋的回收实践[J]. 有色金属(冶炼部分), 2009,(6):14−16.

    Zhu yaoping. Practice of recovery indium zinc and bismuth from gas ash from blast furnace [J]. Nonferrous Metals (Extractive Metallurgy), 2009(6): 14-16.
    [8]
    郭培民. 钢厂含锌粉尘处理方式探讨[N]. 世界金属导报, 2017-6-27(B12).

    Guo Peimin. Discussion on disposal of zinc-bearing dust in iron and steel plant[N]. World Metals, 2017-6-27(B12).
    [9]
    Buzin P J W K, Heck N C, Vilela A C F. EAF dust: An overview on the influences of physical, chemical and mineral features in its recycling and waste incorporation routes[J]. Journal of Materials Research and Technology, 2017,6(2):194−202. doi: 10.1016/j.jmrt.2016.10.002
    [10]
    郭培民, 赵沛, 冶金资源高效利用[M]. 北京: 冶金工业出版社, 2012.

    Guo Peimin, Zhao Pei. Efficient utilization of metallurgical resources [M]. Beijing: Metallurgical Technology Press, 2012.
    [11]
    Hu Xiaojun, Liu Junbao, Guo Peimin, et al. Thermodynamic analysis of the reduction of zinc ferrite with CO-CO2[J]. Chinese Journal of Engineering, 2015,37(4):429−435. (胡晓军, 刘俊宝, 郭培民, 等. 铁酸锌气体还原的热力学分析[J]. 工程科学学报, 2015,37(4):429−435.

    Hu Xiaojun, Liu Junbao, Guo Peimin, et al. Thermodynamic analysis of the reduction of zinc ferrite with CO-CO2 [J]. Chinese Journal of Engineering, 2015, 37(4): 429-435.
    [12]
    Zhang H N, Li J L, Xu A J, et al. Carbothermic reduction of zinc and iron oxides in electric arc furnace[J]. Journal of Iron and Steel Research International, 2014,21(4):427−432. doi: 10.1016/S1006-706X(14)60066-2
    [13]
    Zhu D Q, Li S W, Pan J, et al. Migration and distributions of zinc, lead and arsenic within sinter bed during updraft pre-reductive sintering of iron-bearing wastes[J]. Powder Technology, 2019,342:864−872. doi: 10.1016/j.powtec.2018.10.050
    [14]
    Lu Hua, Wu Shengli, Zhang Jianliang, et al. Forming dynamics of pellet made frozinc-bearing dust in steel plant[J]. Iron and Steel, 2017,52(5):5−12. (鲁华, 吴胜利, 张建良, 等. 钢厂含铁粉尘动力学成球性能[J]. 钢铁, 2017,52(5):5−12.

    Lu Hua, Wu Shengli, Zhang Jianliang, et al. Forming dynamics of pellet made frozinc-bearing dust in steel plant [J]. Iron and Steel, 2017, 52(5): 5-12.
    [15]
    Wang Dongyan, Chen Weiqing, Zhou Rongzhang, et al. Basic properties and pellet making process for iron and steel plant Zn-Pb bearing dust[J]. Journal of University of Science and Technology Beijing, 1998,(2):113−116. (王东彦, 陈伟庆, 周荣章, 等. 钢铁厂含锌、铅粉尘基本物性及造球工艺[J]. 北京科技大学学报, 1998,(2):113−116.

    Wang Dongyan, Chen Weiqing, Zhou Rongzhang, et al. Basic properties and pellet making process for iron and steel plant Zn-Pb bearing dust [J]. Journal of University of Science and Technology Beijing, 1998(2): 113-116.
    [16]
    Wu Y L, Jiang Z Y, Zhang X X, et al. Process optimization of metallurgical dust recycling by direct reduction in rotary hearth furnace[J]. Powder Technology, 2018,326:101−113. doi: 10.1016/j.powtec.2017.12.063
    [17]
    He Huanyu, Chen Zhenhong, Cui Yifang, et al. Sediment of flus gas in direct reduction treated by zinc-bearing metallurgical dust[J]. Iron and Steel, 2015,50(12):80−84. (何环宇, 陈振红, 崔一芳, 等. 含锌冶金尘泥还原烟气沉积特性[J]. 钢铁, 2015,50(12):80−84.

    He Huanyu, Chen Zhenhong, Cui Yifang, et al. Sediment of flus gas in direct reduction treated by zinc-bearing metallurgical dust [J]. Iron and Steel, 2015, 50(12): 80-84.
    [18]
    Lin X L, Peng Z W, Yan J X, et al. Pyrometallurgical recycling of electric arc furnace dust[J]. Journal of Cleaner Production, 2017,149:1079−1100. doi: 10.1016/j.jclepro.2017.02.128
    [19]
    Rieger J, Schenk J. Residual processing in the European steel industry: a technological overview[J]. Journal of Sustainable Metallurgy, 2019,5:295−309. doi: 10.1007/s40831-019-00220-2
    [20]
    Mager K, Meurer U, Garcia-Egocheaga B, et al. Recovery of zinc oxide from secondary raw materials: new developments of the Waelz process [C]//In: Stewart D L. , et al. (eds), Proceedings of the Fourth International Symposium on Recycling of Metals and Engineered Materials . The Minerals, Metals & Materials Society, 2000 : 329−344.
    [21]
    Takaya S, Kubota N, Watanabe H, et al. Recent development of EAF dust treating at Shisaka Smelting Co. , Ltd. [C]//In: Siegmund A. , et al. (eds), Pb Zn 2020: 9th International Symposium on Lead and Zinc Processing. The Minerals, Metals & Materials Series, Springer, Cham. 2020: 91−97.
    [22]
    Holtzer M, Kmita A, Roczniak A. The recycling of materials containing iron and zinc in the oxy cup process[J]. Arch. Foundry Eng, 2015,15:126−130.
    [23]
    Hillmann C, Sassen K J. Processing of zinc-bearing BOF dusts in a blast furnace[J]. World Steel, 2013,13(5):8−9, 54. (Hillmann C, Sassen K J. 高炉处理转炉含锌粉尘[J]. 世界钢铁, 2013,13(5):8−9, 54.

    Hillmann C , Sassen K J . Processing of zinc-bearing BOF dusts in a blast furnace [J]. World Steel, 2013, 13(5): 8-9;54.
    [24]
    Pang Jianming, Guo Peimin, Zhao Pei. Practice of new technology of treating blast furnace dust containing zinc and lead with rotary kiln[J]. China Nonferrous Metallurgy, 2013,42(3):19−24. (庞建明, 郭培民, 赵沛. 回转窑处理含锌、铅高炉灰新技术实践[J]. 中国有色冶金, 2013,42(3):19−24.

    Pang Jianming, Guo Peimin, Zhao Pei. Practice of new technology of treating blast furnace dust containing zinc and lead with rotary kiln [J]. China Nonferrous Metallurgy, 2013, 42(3): 19-24.
    [25]
    Wu Yuliang, Jiang Zeyi, Zhang Xinxin, et al. Numerical simulation of the direct reduction of pellets in a rotary hearth furnace for zinc-containing metallurgical dust treatment[J]. International Journal of Minerals Metallurgy and Materials, 2013,20(7):636−644. doi: 10.1007/s12613-013-0777-5
    [26]
    Lu Yongsuo, Ning Jianping, Ruan Haifeng, et al. Hydrometallurgical recovery of zinc and removal of chlorine and fluorine from zinc oxide dust[J]. Hydrometallurgy of China, 2016,35(5):422−426. (路永锁, 宁建平, 阮海丰, 等. 从次氧化锌烟尘中湿法回收锌及去除氟氯[J]. 湿法冶金, 2016,35(5):422−426.

    Lu Yongsuo, Ning Jianping, Ruan Haifeng, et al. Hydrometallurgical recovery of zinc and removal of chlorine and fluorine from zinc oxide dust[J]. Hydrometallurgy of China, 2016, 35(5): 422-426.
    [27]
    Luo Yongguang, Zhang Libo, Peng Jinhui, et al. Status and future trend of fluorine removal in hydrometallurgical process of zinc oxide dust[J]. China Nonferrous Metallurgy, 2013,42(4):39−43. (罗永光, 张利波, 彭金辉, 等. 氧化锌烟尘湿法冶炼过程除氟现状与发展趋势[J]. 中国有色冶金, 2013,42(4):39−43. doi: 10.3969/j.issn.1672-6103.2013.04.011

    Luo Yongguang, Zhang Libo, Peng Jinhui, et al. Status and future trend of fluorine removal in hydrometallurgical process of zinc oxide dust [J]. China Nonferrous metallurgy, 2013, 42(4): 39-43. doi: 10.3969/j.issn.1672-6103.2013.04.011
    [28]
    Antuñano N, Cambra J F, Arias P L. Fluoride removal from double leached Waelz oxide leach solutions as alternative feeds to zinc calcine leaching liquors in the electrolytic zinc production process[J]. Hydrometallurgy, 2016,161:65−70. doi: 10.1016/j.hydromet.2016.01.008
    [29]
    Li Z Q, Li J, Zhang L B, et al. Response surface optimization of process parameters for removal of F and Cl from zinc oxide fume by microwave roasting[J]. Trans. Nonferrous Met. Soc. China, 2015,25:973−980. doi: 10.1016/S1003-6326(15)63687-1
    [30]
    Xu Kuangdi. Low carbon economy and iron and steel industry[J]. Iron and Steel, 2010,45(3):1−9. (徐匡迪. 低碳经济与钢铁工业[J]. 钢铁, 2010,45(3):1−9.

    Xu Kuangdi. Low carbon economy and iron and steel industry [J]. Iron and Steel, 2010, 45(3): 1-9.
    [31]
    郭培民, 赵沛. 低温快速冶金理论及技术[M]. 北京: 冶金工业出版社, 2020.

    Guo Peimin, Zhao Pei. Theory and technology for fast metallurgy at low temperature [M]. Beijing: Metallurgical Technology Press, 2020.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(8)

    Article Metrics

    Article views (80) PDF downloads(10) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return