Neutral TiO2 sol is prepared with H2TiO3 as raw material through hydrolysis,growth of crystal lattice and crystallization in low temperature.The sol is characterized by XRD,SEM,TEM,absorption spectrometry and so on.The results show that the diameter of La-TiO2 is about 11.6 nm and the absorption edges of La-TiO2 sol shifts to 545 nm.The La-TiO2 sol has good photocatalytic activity for formaldehyde since wet-electron states come into form at interfaces of nanometer TiO2 and H2O molecules layer,however this photocatalytic performance is deeply affected by environmental humidity.