Citation: | WANG Zhenghao. Recent progress developments on vanadium and chromium separation in vanadium extraction leachate from vanadium slag[J]. IRON STEEL VANADIUM TITANIUM, 2025, 46(1): 10-19. doi: 10.7513/j.issn.1004-7638.2025.01.002 |
[1] |
GUO A Q, WANG Z H, CHEN L, et al. A comprehensive review of the mechanism and modification strategies of V2O5 cathodes for aqueous zinc-ion batteries[J]. ACS Nano, 2024,18:27261-27286. doi: 10.1021/acsnano.4c09899
|
[2] |
ZUO G. Thinking on the problem of stable supply of scarce strategic metal resources in china—take tantalum, niobium, chromium and cobalt for example[J]. Natural Resource Economics of China, 2023,36(9):4-13. (左更. 我国稀缺性战略金属资源保供稳供问题的思考—以钽、铌、铬、钴为例[J]. 中国国土资源经济, 2023,36(9):4-13.
ZUO G. Thinking on the problem of stable supply of scarce strategic metal resources in china—take tantalum, niobium, chromium and cobalt for example[J]. Natural Resource Economics of China, 2023, 36(9): 4-13.
|
[3] |
CHEN H B, ZHOU Z H, ZHANG Z J, et al. Research progress in the comprehensive recovery of vanadium-titanium magnetite[J]. Modern Mining, 2023,39(1):7-9. (陈海彬, 周振华, 张作金, 等. 钒钛磁铁矿综合回收研究进展[J]. 现代矿业, 2023,39(1):7-9. doi: 10.3969/j.issn.1674-6082.2023.01.002
CHEN H B, ZHOU Z H, ZHANG Z J, et al. Research progress in the comprehensive recovery of vanadium-titanium magnetite[J]. Modern Mining, 2023, 39(1): 7-9. doi: 10.3969/j.issn.1674-6082.2023.01.002
|
[4] |
LIU S Y, XUE W H, AND WANG L J. Extraction of the rare element vanadium from vanadium-containing materials by chlorination method: a critical review[J]. Metals, 2021,11.8:1301-1310.
|
[5] |
WANG L Z, JIANG C L, ZHU J X, et al. Study on the occurrence state of iron and chromium in Hongge vanadium-titanomagnetite ore[J]. Iron Steel Vanadium Titanium, 2024,45(2):102-107. (王利珍, 姜楚灵, 朱家祥, 等. 红格钒钛磁铁矿中铁、铬的赋存状态研究[J]. 钢铁钒钛, 2024,45(2):102-107. doi: 10.7513/j.issn.1004-7638.2024.02.015
WANG L Z, JIANG C L, ZHU J X, et al. Study on the occurrence state of iron and chromium in Hongge vanadium-titanomagnetite ore[J]. Iron Steel Vanadium Titanium, 2024, 45(2): 102-107. doi: 10.7513/j.issn.1004-7638.2024.02.015
|
[6] |
GAO G J. Study on comprehensive utilization of high-chromium vanadium slag[D]. Beijing: University of Chinese Academy of Sciences. 2017. (高官金. 高铬钒渣综合利用研究[D]. 北京: 中国科学院大学, 2017.
GAO G J. Study on comprehensive utilization of high-chromium vanadium slag[D]. Beijing: University of Chinese Academy of Sciences. 2017.
|
[7] |
CHEN L. Basic research on the direct recovery of low valence vanadium from vanadium slag[D]. Chengdu: Sichuan University. 2021. (陈良. 从钒渣中直接回收低价态钒的基础研究[D]. 成都: 四川大学, 2021.
CHEN L. Basic research on the direct recovery of low valence vanadium from vanadium slag[D]. Chengdu: Sichuan University. 2021.
|
[8] |
AN Y R, MA B Z, LI X, et al. A review on the roasting-assisted leaching and recovery of V from vanadium slag[J]. Process Safety and Environmental Protection, 2023,173:263-276. doi: 10.1016/j.psep.2023.03.013
|
[9] |
CHANG F Z, ZHAO B B, LI L J, et al. Research status and prospect of vanadium extraction from vanadium titano-magnetite[J]. Iron Steel Vanadium Titanium, 2018,39(5):71-78. (常福增, 赵备备, 李兰杰, 等. 钒钛磁铁矿提钒技术研究现状与展望[J]. 钢铁钒钛, 2018,39(5):71-78. doi: 10.7513/j.issn.1004-7638.2018.05.013
CHANG F Z, ZHAO B B, LI L J, et al. Research status and prospect of vanadium extraction from vanadium titano-magnetite[J]. Iron Steel Vanadium Titanium, 2018, 39(5): 71-78. doi: 10.7513/j.issn.1004-7638.2018.05.013
|
[10] |
LEE J C, KUR N W, KIM E Y, et al. A review on the metallurgical recycling of vanadium from slags: towards a sustainable vanadium production[J]. Journal of Materials Research and Technology, 2021,12:343-364. doi: 10.1016/j.jmrt.2021.02.065
|
[11] |
LIU S Y, WANG L J, HE X B, et al. Insight into the oxidation mechanisms of vanadium slag and its application in the separation of V and Cr[J]. Journal of Cleaner Production, 2023,405:136981. doi: 10.1016/j.jclepro.2023.136981
|
[12] |
LI H Y, FANG H X, WANG K, et al. Asynchronous extraction of vanadium and chromium from vanadium slag by stepwise sodium roasting–water leaching[J]. Hydrometallurgy, 2015,156:124-135. doi: 10.1016/j.hydromet.2015.06.003
|
[13] |
FU Z B, JIANG L, LI M, et al. Simultaneous extraction of vanadium and chromium from canadium-chromium slag by sodium roasting[J]. Iron Steel Vanadium Titanium, 2020,41(4):1-6. (付自碧, 蒋霖, 李明, 等. 钒铬渣钠化焙烧同步提取钒和铬[J]. 钢铁钒钛, 2020,41(4):1-6.
FU Z B, JIANG L, LI M, et al. Simultaneous extraction of vanadium and chromium from canadium-chromium slag by sodium roasting[J]. Iron Steel Vanadium Titanium, 2020, 41(4): 1-6.
|
[14] |
WANG Y H, WANG Y F, LI Y T, et al. A review on vanadium extraction techniques from major vanadium-containing resources[J]. Rare Metals, 2024,43(9):4115-4131. doi: 10.1007/s12598-024-02721-w
|
[15] |
WANG Z H, CHEN L, ALDAHRIB T, et al. Direct recovery of low valence vanadium from vanadium slag — Effect of roasting on vanadium leaching[J]. Hydrometallurgy, 2020,191:105156. doi: 10.1016/j.hydromet.2019.105156
|
[16] |
WANG Z H, CHEN L, QIN Z F, et al. A green and efficient route for simultaneous recovery of low valence of vanadium and chromium, titanium and iron from vanadium slag[J]. Resources, Conservation and Recycling, 2022,178:106046. doi: 10.1016/j.resconrec.2021.106046
|
[17] |
CHEN L, WANG Z H, ZHU Y M, et al. Innovative strategy for comprehensive utilization of vanadium slag: Maximizing valuable metals recovery and minimizing hazardous waste generation[J]. Process Safety and Environmental Protection, 2024,188:13-24. doi: 10.1016/j.psep.2024.05.064
|
[18] |
WANG Z H, QIN Z F, CHEN L, et al. Recovery of low valence vanadium from vanadium slag for the preparation of VOSO4 electrolyte[J]. Process Safety and Environmental Protection, 2023,174:298-309. doi: 10.1016/j.psep.2023.03.040
|
[19] |
WANG Z H, CHEN L, YIN R T, et al. Preparation of vanadyl sulfate electrolyte for vanadium flow battery from vanadium slag using calcium salt precipitation, sodium carbonate leaching and solvent extraction[J]. Hydrometallurgy, 2023,222:106146. doi: 10.1016/j.hydromet.2023.106146
|
[20] |
WEN J, JIANG T, XU Y Z, et al. Efficient extraction and separation of vanadium and chromium in high chromium vanadium slag by sodium salt roasting-(NH4)2SO4 leaching[J]. Journal of Industrial and Engineering Chemistry, 2019,71:327-335. doi: 10.1016/j.jiec.2018.11.043
|
[21] |
WEN J, JIANG T, ZHOU M, et al. Roasting and leaching behaviors of vanadium and chromium in calcification roasting–acid leaching of high-chromium vanadium slag[J]. International journal of minerals, metallurgy and materials, 2018,25(5):515-526. doi: 10.1007/s12613-018-1598-3
|
[22] |
WEN J, JIANG T, WANG J P, et al. An efficient utilization of high chromium vanadium slag: extraction of vanadium based on manganese carbonate roasting and detoxification processing of chromium-containing tailings[J]. Journal of Hazardous Materials, 2019,378:120733. doi: 10.1016/j.jhazmat.2019.06.010
|
[23] |
ZHANG G Q, ZHANG T A, LÜ G Z, et al. Extraction of vanadium from vanadium slag by high pressure oxidative acid leaching[J]. International Journal of Minerals, Metallurgy, and Materials, 2015,22(1):21-26. doi: 10.1007/s12613-015-1038-6
|
[24] |
LI H Y, CHENG J, WANG C J, et al. Ecofriendly selective extraction of vanadium from vanadium slag with high chromium content via magnesiation roasting–Acid leaching[J]. Metallurgical and materials transactions. B, Process metallurgy and materials processing science, 2022,53(1):604-616. doi: 10.1007/s11663-021-02402-4
|
[25] |
WANG X W, WANG M Y, FU Z B, et al. Present status and prospects of vanadium and chromium separation in vanadium extraction from vanadium-chromium slag[J]. Iron Steel Vanadium Titanium, 2017,38(6):1-5. (王学文, 王明玉, 付自碧, 等. 钒渣提钒工艺过程钒铬分离现状及展望[J]. 钢铁钒钛, 2017,38(6):1-5. doi: 10.7513/j.issn.1004-7638.2017.06.001
WANG X W, WANG M Y, FU Z B, et al. Present status and prospects of vanadium and chromium separation in vanadium extraction from vanadium-chromium slag[J]. Iron Steel Vanadium Titanium, 2017, 38(6): 1-5. doi: 10.7513/j.issn.1004-7638.2017.06.001
|
[26] |
LI X, WEI Y F, WU Y X, et al. A review on separation of vanadium and chromium in preparation of high-purity vanadium pentoxide[J]. Jiangxi Metallurgy, 2024,44(3):147-156. (李煊, 魏艳芳, 吴一玺, 等. 高纯五氧化二钒制备过程钒铬分离研究进展[J]. 江西冶金, 2024,44(3):147-156.
LI X, WEI Y F, WU Y X, et al. A review on separation of vanadium and chromium in preparation of high-purity vanadium pentoxide[J]. Jiangxi Metallurgy, 2024, 44(3): 147-156.
|
[27] |
WANG Z H, CHEN L, QIN Z F, et al. Tuning the nucleation rates for high-efficiency hydrolysis of sodium vanadate solution[J]. Industrial & engineering chemistry research, 2023,62(28):11128-11139.
|
[28] |
WU Z X. Research status of preparation of vanadium pentoxide from vanadium containing solution[J]. Iron Steel Vanadium Titanium, 2023,44(2):9-19. (伍珍秀. 含钒溶液制备五氧化二钒的研究现状[J]. 钢铁钒钛, 2023,44(2):9-19. doi: 10.7513/j.issn.1004-7638.2023.02.002
WU Z X. Research status of preparation of vanadium pentoxide from vanadium containing solution[J]. Iron Steel Vanadium Titanium, 2023, 44(2): 9-19. doi: 10.7513/j.issn.1004-7638.2023.02.002
|
[29] |
ZHANG Y, PENG X F, FAN B Q, et al. Sustainable valuable metal recovery from the V–Cr–Fe ternary slime via leaching-selective complexation[J]. ACS Sustainable Chemistry & Engineering, 2020,8(2):958-965.
|
[30] |
YIN R T, CHEN L, QIN Z F, et al. A novel complexation method for separation and recovery of low valence vanadium, iron and chromium from sulfuric acid solution[J]. Journal of cleaner production, 2022,373:133640. doi: 10.1016/j.jclepro.2022.133640
|
[31] |
HONG H J, YOO H J, JEON J, et al. Differential adsorption of vanadium(Ⅴ) and tungsten(W) on ion exchange resins: A novel approach for separation and recovery of spent catalyst leachate[J]. Journal of cleaner production, 2023,426:139157. doi: 10.1016/j.jclepro.2023.139157
|
[32] |
YANG X H, LI W, ZHU X B. Mechanism of adsorption of vanadium (Ⅳ) ions in acidic solution by D751 resin[J]. The Chinese Journal of Nonferrous Metals, 2022,32(12):3862-3870. (杨小慧, 李望, 朱晓波. D751螯合树脂吸附酸性溶液中钒(Ⅳ)离子的机制[J]. 中国有色金属学报, 2022,32(12):3862-3870.
YANG X H, LI W, ZHU X B. Mechanism of adsorption of vanadium (Ⅳ) ions in acidic solution by D751 resin[J]. The Chinese Journal of Nonferrous Metals, 2022, 32(12): 3862-3870.
|
[33] |
FAN Y Y, WANG X W, WANG M Y. Separation and recovery of chromium and vanadium from vanadium-containing chromate solution by ion exchange[J]. Hydrometallurgy, 2013,136:31-35. doi: 10.1016/j.hydromet.2013.03.008
|
[34] |
WU B Y, LIU C P, FU C Y, et al. Selective separation of Cr(Ⅵ) and V(Ⅴ) from solution by simple pH controlled two-step adsorption/desorption process with ZrO2[J]. Chemical Engineering Journal, 2019,373:1030-1041. doi: 10.1016/j.cej.2019.05.131
|
[35] |
YUAN B, WU P, LIU C J, et al. Separation of high concentration V(Ⅴ) and Cr(Ⅵ) by amorphous hydrous zirconium oxide with high adsorption capacity and selectivity[J]. Separation and Purification Technology, 2025,354:128562. doi: 10.1016/j.seppur.2024.128562
|
[36] |
LI X B, DENG Z G, WEI C, et al. Solvent extraction of vanadium from a stone coal acidic leach solution using D2EHPA/TBP: Continuous testing[J]. Hydrometallurgy, 2015,154:40-46. doi: 10.1016/j.hydromet.2014.11.008
|
[37] |
ZHANG Y, ZHANG T A, LÜ G Z, et al. Separation between vanadium and iron in acid leaching solution of converter vanadium slag without calcination[J]. Journal of Northeastern University (Natural Science), 2015(10):1445-1448. (张莹, 张廷安, 吕国志, 等. 钒渣无焙烧浸出液中钒铁萃取分离[J]. 东北大学学报(自然科学版), 2015(10):1445-1448. doi: 10.3969/j.issn.1005-3026.2015.10.017
ZHANG Y, ZHANG T A, LÜ G Z, et al. Separation between vanadium and iron in acid leaching solution of converter vanadium slag without calcination[J]. Journal of Northeastern University (Natural Science), 2015(10): 1445-1448. doi: 10.3969/j.issn.1005-3026.2015.10.017
|
[38] |
DAN W J, XIAO L S, ZHANG G Q, et al. Selective separation of chromium(Ⅲ) and iron(Ⅱ) by extraction[J]. Nonferrous Metals Science and Engineering, 2017,8(3):35-41. (淡维杰, 肖连生, 张贵清, 等. 萃取法提取铬(Ⅲ)分离铁(Ⅱ)的研究[J]. 有色金属科学与工程, 2017,8(3):35-41.
DAN W J, XIAO L S, ZHANG G Q, et al. Selective separation of chromium(Ⅲ) and iron(Ⅱ) by extraction[J]. Nonferrous Metals Science and Engineering, 2017, 8(3): 35-41.
|
[39] |
SUN S X, GAO Z L, XI Z K, et al. Study on extraction of chromium with HEH[EHP][J]. Journal of Inorganic chemistry. 1987(1): 7-15. (孙思修, 高自立, 奚正楷, 等. HEH[EHP]萃取铬的研究[J]. 无机化学学报. 1987(1): 7-15.
SUN S X, GAO Z L, XI Z K, et al. Study on extraction of chromium with HEH[EHP][J]. Journal of Inorganic chemistry. 1987(1): 7-15.
|
[40] |
WANG Y C, LIU Y H, MENG F C, et al. Efficient separation of vanadium and chromium by the complexation with sulfate ions in solvent extraction using EHEHPA[J]. Separation and Purification Technology, 2025,354:129281. doi: 10.1016/j.seppur.2024.129281
|
[41] |
THOMAS J, SURENDER G D, REDDY M L P. Solvent extraction separation of vanadium(Ⅴ) from multimetal chloride solutions using tributylphosphate[J]. Separation science and technology, 2003,38(15):3761-3774. doi: 10.1081/SS-120024228
|
[42] |
REMYA P N, SAJI J, REDDY M L P. Solvent extraction and separation of vanadium (Ⅴ) from multivalent metal chloride solutions by cyanex 923[J]. Solvent extraction and ion exchange, 2003,21(4):573-589. doi: 10.1081/SEI-120022522
|
[43] |
ZHAO L F, FEI D J, DANG Y G, et al. Studies on the extraction of chromium(Ⅲ) by emulsion liquid membrane[J]. Journal of Hazardous Materials, 2010,178(1-3):130-135. doi: 10.1016/j.jhazmat.2010.01.052
|
[44] |
TAN X W, YANG Y Q, DUAN Z K, et al. Extraction of chromium(Ⅵ) by TBP in hydrochloric acid[J]. Chemical Industry and Engineering Progress, 2003(12):1323-1326. (谭雄文, 杨运泉, 段正康, 等. 盐酸介质中磷酸三丁酯萃取分离铬(Ⅵ)[J]. 化工进展, 2003(12):1323-1326. doi: 10.3321/j.issn:1000-6613.2003.12.016
TAN X W, YANG Y Q, DUAN Z K, et al. Extraction of chromium(Ⅵ) by TBP in hydrochloric acid[J]. Chemical Industry and Engineering Progress, 2003(12): 1323-1326. doi: 10.3321/j.issn:1000-6613.2003.12.016
|
[45] |
YU S Q, MENG X S, CHEN J Y. Extraction of pentavalent vanadium from aqueous solutions with primary amines[J]. Chinese Science (Series B. Chemistry, Biology, Agronomy, Medicine, Geology), 1982(1):11-18. (于淑秋, 孟祥胜, 陈家镛. 用伯胺从水溶液中萃取五价钒[J]. 中国科学(B辑 化学 生物学 农学 医学 地学), 1982(1):11-18.
YU S Q, MENG X S, CHEN J Y. Extraction of pentavalent vanadium from aqueous solutions with primary amines[J]. Chinese Science (Series B. Chemistry, Biology, Agronomy, Medicine, Geology), 1982(1): 11-18.
|
[46] |
NING P G, CAO H B, LIU C M, et al. Characterization and prevention of interfacial crud produced during the extraction of vanadium and chromium by primary amine[J]. Hydrometallurgy, 2009,97(1-2):131-136. doi: 10.1016/j.hydromet.2009.01.007
|
[47] |
SUN P, HUANG K, LIU H Z. Separation of V and Cr in alkaline aqueous solution using acidified primary amine N1923[J]. Hydrometallurgy, 2016,165:370-380. doi: 10.1016/j.hydromet.2015.10.026
|
[48] |
QIN Z F, ZHANG G Q, XIONG Y J, et al. Recovery of vanadium from leach solutions of vanadium slag using solvent extraction with N235[J]. Hydrometallurgy, 2020,192:105259. doi: 10.1016/j.hydromet.2020.105259
|
[49] |
HU B, ZHANG C D, DAI Y Y, et al. Separation of vanadium and chromium in solution after vanadium precipitation by co-extraction with N263 and selective stripping with NaOH solution[J]. Hydrometallurgy, 2022,208:105798. doi: 10.1016/j.hydromet.2021.105798
|
[50] |
SUN P, HUANG K, WANG X Q, et al. Three-liquid-phase extraction and separation of V(Ⅴ) and Cr(Ⅵ) from acidic leach solutions of high-chromium vanadium–titanium magnetite[J]. Chinese Journal of Chemical Engineering, 2018,26(7):1451-1457. doi: 10.1016/j.cjche.2018.01.023
|
[51] |
ZHAO J M, HU Q Y, LI Y B, et al. Efficient separation of vanadium from chromium by a novel ionic liquid-based synergistic extraction strategy[J]. Chemical Engineering Journal 2015, 264: 487-496.
|
[52] |
NING P G, LIN X, CAO H B, et al. Selective extraction and deep separation of V(Ⅴ) and Cr(Ⅵ) in the leaching solution of chromium-bearing vanadium slag with primary amine LK-N21[J]. Separation and Purification Technology, 2014,137:109-115. doi: 10.1016/j.seppur.2014.08.033
|
[53] |
HU G P, CHEN D S, WANG L, et al. Extraction of vanadium from chloride solution with high concentration of iron by solvent extraction using D2EHPA[J]. Separation and Purification Technology, 2014,125:59-65. doi: 10.1016/j.seppur.2014.01.031
|
[54] |
YING Z W, HUO M X, WU G X, et al. Recovery of vanadium and chromium from leaching solution of sodium roasting vanadium slag by stepwise separation using amide and EHEHPA[J]. Separation and Purification Technology, 2021,269:118741. doi: 10.1016/j.seppur.2021.118741
|