2016 Vol. 37, No. 3

Separating and Extracting of Vanadium and Titanium
Research on Oxidization-reduction-hydrochloric Acid Leaching Process to Prepare Titanium-rich Material with Ilmenite
Lü Bin, Ding WeiZhong, Shang XingFu, Tan DingSheng, Guo ShuQiang
2016, 37(3): 1-6. doi: 10.7513/j.issn.1004-7638.2016.03.001
Abstract(25) PDF(1)
Abstract:
The process of oxidization-reduction-hydrochloric acid leaching was adopted to selectively leach the ilmenite from Panxi area.The effect of oxidization-reduction pretreatment on the grain size,surface morphology and microstructure of the ilmenite,and the influence of leaching conditions on the leaching rate of Fe and Ti from the ilmenite,TiO2 content in the leaching residue were investigated in this paper.The results indicate that after oxidization and reduction both the surface roughness and grain size of the ilmenite increase.The optimum leaching conditions are as follows:5:1 of liquid-solid ratio,4 mol/L of hydrochloric acid concentration,90℃ of leaching temperature for 5 h,with the ilmenite oxidized at 1 000℃ for 1 h and reduced at 800℃ for 1 h by hydrogen as raw materials for leaching.The leaching ratios of Fe and Ti under the optimal conditions are respectively 93.89% and 3.28%.The titanium-rich material with 87.51% TiO2 can be finally obtained with particle size of ilmenite well maintained.
Study on the Milling-leaching Coupled Digestion of Panzhihua Ilmenite
Peng Kun, Yuan ShaoJun, Wang XiaoMei, Du Jun, Du ZhangShan, Liang Bin
2016, 37(3): 7-14. doi: 10.7513/j.issn.1004-7638.2016.03.002
Abstract(17) PDF(1)
Abstract:
The sulfate process of manufacturing TiO2 pigments based on the Ti resources in Panxi area usually discharges 6 to 8 tons of dilute waste acid(20% concentration) per ton of products,which inevitably causes serious environmental problems.The dilute acid digestion of ilmenites can effectively reuse the waste acid to avoid discharge and reduce acid consumption for production.In this study,a milling-leaching reactor was designed to accommodate the coupled process of mechanical activation and dilute acid leaching.The optimum conditions of the reactor was determined as follows:70 r/min of stirring speed,10:1 of ball/ore ratio,1.5:1 of acid/ore ratio,60% of the initial concentration for sulfuric acid and 70℃ of reaction temperature.Under the conditions mentioned above,the Ti leaching ratio from the ilmenites can reach as high as 80%,the concentration of Ti solution was 130 g/L with an F value of about 3,and the stability of Ti solution was more than 350 mL.The obtained Ti solution satisfied the industrial standard for TiO2 production by sulfate process.The milling-leaching coupled process,which uses the ball grinding to mechanically activate ilmenites,can effectively increase the leaching rate of ilmenite and enhance the mass transfer between solid and liquid phases in the reaction process.This dilute acid leaching process not only saves the acid consumption by completely recycling waste acid,but also reduces the acid fog pollution in leaching process.It offers a novel potential technology to circumvent the pollution problems in TiO2 pigment production by sulfate process.
Occurrence State of CaO in Panzhihua Ilmenite and Its Influence on the Quality of Synthetic Rutile
Ye EnDong
2016, 37(3): 15-18,23. doi: 10.7513/j.issn.1004-7638.2016.03.003
Abstract(32) PDF(2)
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The phase structure and morphology of Panzhihua ilmenite and the synthetic rutile produced by Panzhihua ilmenite were deeply analyzed by XRD and SEM.It shows that CaO mainly dissolves with SiO2,MgO,FeO and TiO2 in silicate accompanying phase of the ilmenite.During the production of synthetic rutile,the silicate cannot be destructed by high-temperature redox modification and hydrochloric acid leaching,which leads to the enrichment of CaO in synthetic rutile and further influence on the quality of synthetic rutile.It is proposed that CaO in the ilmenite can be effectively removed and high-quality synthetic rutile can be produced by deeply grinding and adjusting the beneficiation parameters for the ilmenite.Cao component can also be separated by high gradient magnetic concentration of titanium-rich material to produce synthetic rutile satisfying the requirements for international large-scale boiling chlorination furnace.
Study on Reduction Mechanism of Vanadium Oxides in Lumpy Zone of Chengde Steel's Blast Furnace
Liu Ran, Zhao XiaoJie, Zhang ZhenFeng
2016, 37(3): 19-23. doi: 10.7513/j.issn.1004-7638.2016.03.004
Abstract(47) PDF(2)
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It is of great significance to investigate the behaviors of vanadium in the blast furnace(BF)with V-Ti magnetite as main raw materials.The reduction mechanism of vanadium in the lumpy zone of BF was explored by theoretical analysis and simulation experiments.It is indicated by the thermodynamic calculations that V and Fe can infinitely dissolve in each other,and the thermodynamic conditions for the reduction of vanadium oxides will be greatly improved with appearance of the iron phase.It is also confirmed by XPS and XRD that the valence state of V is +5 in the V-Ti sinter of Chengde Steel which mainly consists of titanic magnetite and titanium hematite with V and Ti dissolved in titanic magnetite.Through the reduction experiments for the V2O3 pure reagent,mixed reagent of Fe2O3 and V2O3(1:1)and V-Ti sinter of Chengde Steel,it is shown that V2O3 pure reagent cannot be restored by CO within 1000℃,and elemental V cannot be obtained from vanadium oxides by indirect reduction of BF lumpy zone.
Solubility and Dissolution Mechanism of V2O5 in NaCl-KCl-NaF Molten Salt System
Wu MingYu, Hu Kai, Xu MingYue, Wang Cong, Li YunGang
2016, 37(3): 24-29. doi: 10.7513/j.issn.1004-7638.2016.03.005
Abstract(42) PDF(2)
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The influence of temperature and molten salt component on the solubility of V2O5 in Na Cl-KCl-NaF molten salt system was researched by isothermal saturation method.The possible reactions between the materials in the molten salt system were calculated by using the thermodynamic software Factsage7.0,and the dissolution mechanism of V2O5 was finally determined by combination with the X-ray diffraction analysis of the rapid cooling samples of molten salt.The results show that V2O5 preferentially reacts with NaF in the molten salt system by the following dissolving mechanism of 4V2O5+ 6NaF=6NaVO3+2VF3+O2.The solubility of V2O5 increases with increase in temperature and NaF content in the molten salt system.
Study on the Green Preparation Technology of VOSO4 for Vanadium Battery
Wang YuanWang, Luo HaiBo, Peng RongHua
2016, 37(3): 30-34. doi: 10.7513/j.issn.1004-7638.2016.03.006
Abstract(32) PDF(1)
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VOSO4 used for vanadium battery was prepared by reduction of high purity V2O5 with H2O2,and the preparation technology and reaction mechanism were studied.The enthalpy and Gibbs free energy change of the reaction for preparing VOSO4 were calculated,and the charge and discharge performance testing were performed using the prepared VOSO4 as active material of vanadium battery.The results show that it's an exothermic reaction for VOSO4 formation and the dissolution of V2O5 is promoted by the reaction.This technology is characteristic of simple,green and environment-friendly with the best mole ratio of V2O5:H2O2:H2SO4=1:1.2~1.4:2.4~2.5.The V4+ content in the obtained VOSO4 accounts for 99.66% of total vanadium amount,with V5+ occupying 0.34%.The prepared VOSO4 has a good charge and discharge performance,which can be used as active material of vanadium battery electrolyte.
Application of Vanadium and Titanium
Structure Characteristics of Hydrated Alumina Coated on Titanium Dioxide and Its Effect on Water Dispersibility of Titanium Dioxide
Zhang RuHui, Zhou DaLi, Jiang FengZhou, Liang CaiHong, Zhou JiaBei, Lü Bo, Du JianQiao
2016, 37(3): 35-40,47. doi: 10.7513/j.issn.1004-7638.2016.03.007
Abstract(46) PDF(2)
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The alumina hydrates were obtained by hydrolysis at different pH with sodium metaaluminate as raw materials.The structure and morphology of the obtained alumina hydrates were characterized by XRD and SEM,and their hydrolysis processes were analyzed by combination with the advantage zones of various monomer aluminum ions existing in aqueous solution.Surface modification of titanium dioxide was carried out by coating sodium metaaluminate at different pH,and the water dispersibility and stability of the modified titanium dioxide were investigated.The results show that amorphous hydrated alumina is obtained at pH=4~5,which exists as aggregate structure with tens of nanometers.Boehmite hydrated alumina is precipitated at pH=6~10 with loose and flocculent morphology.Gibbsite with platy and prismlike structure is formed at pH > 10.Zeta potential on the surface of titanium dioxide varies with the pH value for coating,and the isoelectric point of the coated titanium dioxide is higher than that of the uncoated ones.In the aqueous solution of pH=10,the titanium dioxide modified at pH=4 and 5 has a poor water dispersibility and stability,while the water dispersibility and stability of the titanium dioxide coated at pH=9,10 and 10.5 are significantly improved with comparison to those of the uncoated ones.
Study on the Process and Mechanism of Coating Silica on Titanium Dioxide with Ethyl Orthosilicate
Li Wang, Liu Yong, Lu HouFang
2016, 37(3): 41-47. doi: 10.7513/j.issn.1004-7638.2016.03.008
Abstract(47) PDF(3)
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Dense SiO2 film was coated on TiO2 pigment by sol-gel method using ethyl orthosilicate(TEOS) as silica source.The effects of main factors on the coating process were studied.Through evaluating the coating results by SiO2 deposition quantity and acid solubility,the optimum parameters were determined.The most excellent coating effect can be obtained with amines as dispersant,parallel flow feeding mode,200 g/L of TiO2 concentration,60℃ of temperature,4% of ammonia amount added as catalyst and 1:6.9 of volume ratio of water to alcohol.Compared with the product coated by sodium silicate,the product coated with TEOS shows lower acid solubility and photocatalytic activity,indicating more compact film and better weatherability for the product coated with TEOS.SiO2 layer is proved to be coated on TiO2 particles via chemical bonding by fourier transformation infrared spectrum(FT-IR) and scanning electron microscopy(SEM) characterizations.Finally,the mechanism for coating process was analyzed based on the results of conductivity tests.
Effect of Current Density on Boriding on TC4 Titanium Alloy by Molten Salt Electrolysis
Feng Ce, Tang GuoZhang, Wang XinYue, Wang YanLi, Yang HaiLi
2016, 37(3): 48-51. doi: 10.7513/j.issn.1004-7638.2016.03.009
Abstract(34) PDF(1)
Abstract:
TC4 titanium alloy was borided by molten salt electrolysis.The effect of current density on the thickness,composition,microstructure,phase and hardness of borided layer was studied by glow discharge optical emission spectroscopy(GDOES),scanning electron microscopy(SEM),X-ray diffraction(XRD)and microhardness tester.The results show that,with current density increasing from 50 to 90 mA/cm2,the grain size of borided layer gradually becomes smaller,and the thickness of borided layer increases first and then decreases.When the current density is 60 mA/cm2,the thickness of borided layer reaches the maximum.The borided layer does not contain Al,and V dissolves in the borides to form solid solution.The borided layer consists of TiB and TiB2 with preferred orientation of(111) lattice plane.The microhardness of the borided layer is increased by 5 times than that of the matrix.
Effect of Cr Content on Technology and Properties of Ti Alloy for Automobile
Wang LiangLiang
2016, 37(3): 52-55. doi: 10.7513/j.issn.1004-7638.2016.03.010
Abstract(15) PDF(1)
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In this paper,the influence of Cr content on the microstructure and properties of TC4 alloy was studied.The results show that the Cr element can decrease the transition temperature of β phase in TC4 alloy.When the Cr content is lower than 3% TC4 alloy possesses duplex microstructure,while the phase transition of TC4 alloy is completed and the α phase continuously distributes in the boundaries of β phase with Cr content higher than 3%.The α and β phases coexist in the TC4 alloy with different Cr contents,and the content of β phase obviously increases with increase in Cr content.Both the tensile strength and yield strength of TC4 alloy gradually increase while its elongation percentage decreases,with increase of Cr content.When the Cr content is 4%,the TC4 alloy respectively has a maximum tensile strength and yield strength of 1 068 and 1 697 MPa,as well as a minimum elongation percentage of 9.94%.
Experimental Study on Preparation of Vanadyl Oxalate
Wan LongFei
2016, 37(3): 56-59. doi: 10.7513/j.issn.1004-7638.2016.03.011
Abstract(35) PDF(4)
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Vanadyl oxalate with high quality was prepared using vanadium pentoxide and oxalic acid as raw materials,and the effects of reaction temperature and time,and adding coefficient of oxalic acid on the quality of vanadyl oxalate solution and reaction process were investigated.The results show that vanadyl oxalate solution satisfying the technical targets can be obtained under the following conditions:2:1 of mass ratio for oxalic acid to vanadium pentoxide and 50~60℃ of reaction temperature.The vanadyl oxalate solid was characterized by XRD,SEM and EDS.It is indicated that the XRD pattern fits well with that of VOC2O4·5H2O,and vanadyl oxalate with high quality can be prepared when the content of Na for raw materials is less than 0.01%.
Research on Heat Treatment of High Chromium Cast Iron Modified by Vanadium and Titanium Based on Neural Network Algorithm
Xia LuPeng, Ji ShuYan
2016, 37(3): 60-65. doi: 10.7513/j.issn.1004-7638.2016.03.012
Abstract(14) PDF(1)
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The neural network model of heat treatment process for high chromium cast iron modified by vanadium and titanium,which is the structure of 6×24×12×2,was established by the method of neural network algorithm,with vanadium content,titanium content,quenching temperature,tempering cooling mode,tempering temperature and tempering cooling mode as input parameters and with wear resistance and impact toughness as output parameters.The average relative prediction errors of wear resistance and impact toughness were 2.8% and 2.5%,respectively.The neural network model has good prediction ability and high precision.Meanwhile,it has a favorable application effect in heat treatment production line,which could make the impact toughness,average grain size and wear volume of high chromium cast iron modified by vanadium and titanium online,increase by 62%,decrease by 32% and 50%,respectively.
Resources Environment and Energy Saving
Study on Antibacterial Properties of Blast Furnace Slag Containing Titanium
Zou Shuang, Wang Hui, Yang He
2016, 37(3): 66-69. doi: 10.7513/j.issn.1004-7638.2016.03.013
Abstract(10) PDF(1)
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The blast furnace slag containing titanium(BFST) was characterized by XRF,XRD,SEM and UV-Vis-DRS to determine its feasibility as photocatalyst,and the antibacterial effects of BFST on candida albicans(ATCC10231),escherichia coli(ATCC25922) and staphylococcus aureus(ATCC6538) were investigated by inhibition zone and flask oscillation methods,respectively.The results show that BFST has no significant antibacterial effect on escherichia coli and candida albicans,while it can restrain the staphylococcus aureus to some extent with 54.54% of antibacterial rate for 1 h of action.
Preparation and Performance Characterization of Photocatalytic Material of Blast Furnace Slag Fibre Loaded by SiO2 and TiO2
Xing HongWei, Gu ShaoPeng, Yang LiRong, Liu ZhiGang, Sun RuiJing, Wang NiNan
2016, 37(3): 70-75. doi: 10.7513/j.issn.1004-7638.2016.03.014
Abstract(21) PDF(1)
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Photocatalytic material of TiO2/SiO2/BFSF was prepared by loading SiO2 and TiO2 on the surface of blast furnace slag fibre(BFSF) in sequence using sol-gel process,with BFSF as the carrier.The effects of SiO2 loading,times of impregnation in TiO2 sol,calcination temperature and recycle times on photocatalytic activity of the prepared material were investigated.The microstructure and phase compositions of the obtained photocatalytic material were characterized by SEM and XRD,respectively.The photocatalytic activity of the material was evaluated by degradation of methylene blue(MB).The results show that SiO2 loaded on BFSF can inhibit the crystal growth of TiO2,increase loading capacity of TiO2 and enhance photocatalytic activity of the material.An uniform-compact anatase TiO2 layer was formed on the surface of TiO2/SiO2/BFSF with the most excellent photocatalytic activity under conditions of impregnation in TiO2 sol for 3 times and calcination at 450℃.With irradiation for 180 min under ultraviolet light,the degradation rate of MB can reach to 96.1% and maintain at 67% after 4 times of recycle of the TiO2/SiO2/BFSF photocatalytic material.
Experimental Study on the Direct Fibrosis of Quenched and Tempered Blast Furnace Slag
Li ZhiHui, Zhang YuZhu, Long Yue, Zhang LiangJin, Du PeiPei, Ren QianQian
2016, 37(3): 76-80. doi: 10.7513/j.issn.1004-7638.2016.03.015
Abstract(11) PDF(1)
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The fibrosis of molten blast furnace slag was studied by high speed air blowing method using the independently designed and built experimental platform.The fibrosis mechanism of the molten slag was discussed and the factors influencing the diameter and properties of the obtained fiber were analyzed.The results show that the fiber is formed through three processes of liquid membrane formation,bulge formation and bump drawing during the air blowing.The diameter of the fiber decreases with increase in gas pressure,and the fiber owning the most excellent properties can be obtained with 1.1~1.4 of acidity coefficient for the quenched and tempered slag at 1 350~1 500℃.This study can provide theoretical basis for expanded industrial production.
Study on the Properties of Titanium Gypsum
Li Liang, Hou YongBin
2016, 37(3): 81-85. doi: 10.7513/j.issn.1004-7638.2016.03.016
Abstract(17) PDF(2)
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Titanium gypsum,which is a byproduct in titanium dioxide production by sulfuric acid method,causes environmental contamination during accumulation.Investigations on the properties and characters of titanium gypsum have important guiding significance on proper selection of recycle and utilization methods of titanium gypsum.The Phase component,anhydration temperature and time,and coagulation features of titanium gypsum were studied in this paper.It is shown that titanium gypsum is composed of calcium sulfate dihydrate as main phase and small quantity of dolomite.The feasible temperature and time for anhydration of the crystal water in titanium gypsum should be controlled at about 200℃ and 50 min,respectively.With addition of citric acid as retarder and calcination temperature increased from 120 to 200℃,the coagulation time of titanium gypsum can be decreased from 1 800 to 1 000 s,which satisfies the time requirement for pouring.
Ferrous Metallurgy and Materials
Optimization Practice of Wet Desulfurization Process Parameters for Vanadium Titanium bearing iron ore Sintering
Yuan PingGang
2016, 37(3): 86-90. doi: 10.7513/j.issn.1004-7638.2016.03.017
Abstract(10) PDF(1)
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In order to address the problems occurred during the wet desulfurization process for sintering vanadium titanium bearing iron ore,some measures had been taken,such as dismounting all flue gas bypass ducts,optimizing individual system operating parameters and Ca/S molar ratio,reducing the failure rate of mist eliminator,and improving the quality of gypsum byproduct,under which the synchronous operation rate between the sintering machine and desulfurization systems reached 100%,and Ca/S molar ratio decreased by 0.18,emissions compliance rate of sulfur dioxide in the outlet flue gas increased by 5.5%.Limestone-gypsum wet flue gas desulfurization has been proven a suitable technology for vanadium titanium bearing iron ore sintering process.
Settlement Process of Iron in Titania Bearing Blast Furnace Slag
Tian Ye, Chen ShuJun, Sun YanQin, Lü Qing, Qie YaNa, Liu XiaoJie
2016, 37(3): 91-97. doi: 10.7513/j.issn.1004-7638.2016.03.018
Abstract(23) PDF(1)
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The viscosity of the vanadium titano-magnetite slag from Chengde iron & steel company is bigger than the common slag,the separation of the slag-iron is difficult,and the iron content of the slag is about 2%,which not only makes the usage of the slag is difficult,but also leads to the higher producing costs of pig.The formation reason of iron bearing titano-magnetite slag was analysed,the behavior of the Fe precipitation in the titania bearing slag was studied,and the influences of the different dwell time,temperature and the viscosity of the slag on the settlement process of iron in titaniferous slag of blast furnace were explored.The results show that the dwell time of slag have a complex impact on the iron in the slag.When the dwell time is 20~30 min,the settlement of iron is obvious,and with the time extending,the settlement of iron has little change,while its location is lower and the granularity is bigger,as the dwell time is 40~80 min.The temperature of the slag sample has a significant impact on the iron content of the slag.With increasing dwell temperature,the iron content of the slag significantly decreases.When the temperature is 1 500℃,the iron content decreases from 2%to 0.4%.In addition,the viscosity have the close relationship with the iron content of slag.Adding the calcium fluoride into the slag would reduce the viscosity of the slag and promote the settlement process of iron.It is proposed to add 1% calcium fluoride which generates better settlement effect.
Experimental Study on the Feasibility of Improving Blast Furnace's Basicity of Slag
Hao ZhongPing, Guo ZhuoTuan, Lian Hua, Xi Jun, Ma Xiang
2016, 37(3): 98-102. doi: 10.7513/j.issn.1004-7638.2016.03.019
Abstract(15) PDF(1)
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The viscosity,softening temperatue and melting temperature of blast furnace slag with different basicity had been investigated in this paper.The results show that Baogang's BF slag is typical of short slag,when the temperature is above 1 400℃,the slag has very low viscosity is very low(about 0.5 Pa·s) and good fluidity.The viscosity and the melting temperature increase with increasing the slag basicity up to 1.07.Further increasing basicity leads to the reduction in both viscosity and melting temperature.The equilibrium reaction and its phase diagram obtained by the Factsage thermodynamic software indicates that the slag basicity of 1.13 is in favor of reducing coke ratio.
Numerical Simulation of Three-phase Flow in a Top-blown Converter with a 4-hole Oxygen Lance
Wang JieJie, Chen Wei
2016, 37(3): 103-107. doi: 10.7513/j.issn.1004-7638.2016.03.020
Abstract(14) PDF(1)
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A three dimensional transient mathematical model for the 100 t oxygen top-blown converter has been carried out using the numerical simulation software fluent.The impact depth,impact area and molten bath velocity distribution had been obtained at different oxygen lance height and oxygen lance nozzle angle.It is found out that under the same condition,raising the lance position leads to larger diameter of pit created by jets,while the impact depth decreases.As the nozzle hole cone angle increases,the diameter of pit created by jets become larger,while the impact depth decreases.Low lance position is beneficial to increase flow velocity of the liquid steel at the upper molten bath,while high lance position is conducive to promote the liquid steel flow of the bottom bath.Increasing the nozzle hole cone angle promotes the large high-speed surface zone area,but the low speed zone area at the bottom of the molten bath has been increased as well.
Study on Diffusion Rate of Phosphor in CaO Solid Phase Particles in Dephosphorization Slag
Peng Jun, Liu Shuang, Liu LiXia, Guo Yong, An ShengLi
2016, 37(3): 108-114. doi: 10.7513/j.issn.1004-7638.2016.03.021
Abstract(13) PDF(1)
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There is some amount of solid particle of CaO in dephosphorizing slag of molten steel.In order to investigate the diffusion rate of phosphor in CaO particle,CaO particle suspending with wire of Mo were put into molten slag of CaO-SiO2-FetO-P2O5 at the temperature between 1 385℃ and 1 450℃,and then were taken out to cool down in the air after 10 s,20 s,30 s,60 s and 100 s of thermal insulation respectively.The distribution of phosphor in the experimental heterogeneous dephosphorizing slag between CaO particle and slag was measured by SEM-EDS and the diffusion coefficient was calculated in order to study the effect of temperature on diffusion velocity of phosphor in CaO solid particle.The result shows that at experimental temperature,phosphor can enter into CaO solid particle by diffusing,however,the further diffusing of phosphor is difficult to realize because of the reaction of CaO particle with other material in slag.The DP,diffusion velocity coefficient of phosphor in CaO solid particle,is 9.536×10-10m2/s at 1 400℃ and they are 5.757 49×10-10m2/s and 7.42×10-9m2/s respectively at 1 385℃ and 1 450℃.Between 1 380℃ and 1 450℃,the activation energy of diffusing in CaO particle of phosphor in slag of CaO-SiO2-FetO-P2O5 is 9.638×105 J/mol.
Practice of Sulfur Content Control During the Smelting of Ultra-low Sulfur X65QS Pipeline Steel
Li ShangBing, Zhang XinWen, Xue WeiJiang
2016, 37(3): 115-118. doi: 10.7513/j.issn.1004-7638.2016.03.022
Abstract(16) PDF(1)
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The production process of sulfur content control during the smelting of ultra-low sulfur X65QS pipeline steel in Yong Gang steel used 110 tons of electric furnace,LF refining,VD refining and continuous casting is present in this paper.The sulfur content at each individual process steep had been strictly controlled and average desulfurization rate is achieved at 16.35% for electric furnace.During tapping aluminum addition is 1 kg/t molten steel for deoxidation,at the same time the lime and synthetic slag for refining are added at rate of 6 kg/t and 2 kg/t,respectively.Al wire is used in the LF furnace,composited Si C and Al shot are added for the slag surface diffusion deoxidization.And the resulting high basicitgy white slag are used for deep deoxidization and desulphurization.Desulphurization rate averages at 89.2%for LF furnace.The average sulfur content is 0.000 93% after LF refining.The average resulfurization is 0.000 1% through the end of LF refining to continuous casting steps.And the end sulfur content is 0.000 9%.By controlling the sulfur content in the charge,improving deep desulfurization in the LF refining furnace,and preventing the resulfurization after refining,the sulfur content of X65QS round bloom is far below specified 0.002% level.
Temperature Field and Mechanical Properties for Products of Square Billet on Direct Rolling
Hao JinYang, Feng GuangHong, Zhang HongLiang
2016, 37(3): 119-123. doi: 10.7513/j.issn.1004-7638.2016.03.023
Abstract(12) PDF(1)
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The continuous casting square billets are directly transferred into rolling stands immediately after being cut off.An uneven temperature field occurs on the billet as a result of elimination of reheating step.The temperature field of billets being directly transferred into rolling line process and the first pass on direct rolling and conventionally rolling processes were investigated by finite element method.The results show that the average temperature of the 150 mm×150 mm billet within 300 s after being cutting off can still remain more than 1000℃,which is suitable for direct rolling.The reduction in the center of billet via direct rolling is bigger than that through conventional rolling.The results from industrially direct rolling test show a good agreement with the simulated result in terms of temperature field.The tensile test indicates scattered distribution of mechanical properties along the length of bar.After a period of 10-days aging,the change of yield strength and tensile strength along the length direction is in small range of 20 MPa,and total elongation increases obviously in the first ten days.
Optimal of Single Strand Tundish Field at High Casting Speed
Zhang CaiJun, Lü Da, Qiao ShiBin, Gu KeJing, Xiao PengCheng
2016, 37(3): 124-130. doi: 10.7513/j.issn.1004-7638.2016.03.024
Abstract(28) PDF(3)
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Hydraulic model and numerical simulation had been utilized to study the behavior of single strand tundish field of high speed casting tinplate.RTD curves had been obtained through the hydraulic model using impulse response method.The curves had been used to analyze the flow patterns of the tundish.The numerical simulation had been carried out by a Fluent commercial software to simulate tundish field and inclusion formation.Based on the RTD curve and simulation results a optimized casting plan had been established.The average residence time of the liquid steel has extended from 340.7 s to 545.3 s,increasing by 60.1%,while the dead zone volume ratio has decreased from 46.0% to 13.6%,reducing by 70.4%.With the help of modified casting process,the removal rate of micro inclusions and endogenous inclusions in the tundish has increased significantly.
Effect of Asymmetric Rolling on Microstructures,Texture and Formability of SUS430 Ferritic Stainless Steel
Li QiuHe, Wang Gang, Xing DeMao, Liang Shuang
2016, 37(3): 131-136. doi: 10.7513/j.issn.1004-7638.2016.03.025
Abstract(17) PDF(1)
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The effect of asymmetric rolling on microstructure,texture evolution,and formability of SUS430 ferritic stainless steel sheet has been investigated by using X-ray diffraction(XRD) and optical microscopy.The results showed that grains could be appropriately refined by asynchronous rolling,but the grain sizedistribution was not uniform.Texture evolution analysis indicated that uniform and complete γ fiber texture along thickness could be obtained after one-step rolling,but texture intensity is weak.However,applying two-step asynchronous rolling technology,recrystallization texture with nearly random orientation was achieved after double annealing processes.A comprehensive analysis further indicated that one-step rolling technology was beneficial to the performance improvement.
Effect of Cold-rolling Mode on Microstructure,Texture and Magnetic Properties of 50W470 Steel
Peng Kai, Xiang Li, Chou ShengTao, Zhang YingHui
2016, 37(3): 137-141. doi: 10.7513/j.issn.1004-7638.2016.03.026
Abstract(12) PDF(1)
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The influence of continuous cold rolling and reversible cold rolling processes on the microstructure,texture and magnetic properties of 50W470 steel had been investigated by metallographic microscope and XRD ray diffraction instrument.Optical observation showed that the average grain size of steel strip after annealing through continuous cold rolling was about 88 μm,while the value for reversible cold rolling was about 69 μm.The texture for bothcontinuous cold rolling and reversible cold rolling texture concentrated into α-fibre and γ-fible,the orientational density of the texture of continuous cold rolling and reversible cold rolling were obvious difference on α-fibre,Ø=15°bias {001} <110> and Ø=30°bias {112} <110>,while the orientational density of the γ-fible were small.The iron losses of steel sheet through continuous cold rolling was:P1.5/50=2.94 W/kg,the magnetic induction was:B5000=1.729 T,while the iron losses for the reversible cold rolling was:P1.5/50=3.04 W/kg,the magnetic induction was:B5000=1.729 T.
Processing Factors That Influence the Microstructure and Properties of High Strength Dual-phase Steels Produced Using CGL Simulations
Gong Yu, M.Hua, J.Uusitalo, A.J.Deardo
2016, 37(3): 142-150. doi: 10.7513/j.issn.1004-7638.2016.03.027
Abstract(12) PDF(1)
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The purpose of this paper is to present research whose goal was to improve the substrate in galvanized or galvannealed sheet steel,such that high strength can be obtained while maintaining good global formability(tensile ductility),local formability(sheared-edge ductility),and good spot weldability.It is well-known that the strength of DP steels is controlled by several factors,including the amount of fresh(untempered) martensite found in the final microstructure.However,the factors that control the amount of martensite in the final microstructure are not all together clear,and their identification represents a large portion of the research conducted in this program.The amount of fresh martensite found in the final microstructure can be considered equal to the amount of austenite formed in the intercritical anneal less the amount of austenite lost to various transformation products as the steel undergoes cooling from the intercritical annealing temperature(IAT) to 460℃,isothermal holding at 460℃,final cooling to RT and any remaining austenite retained at RT.Recent research has revealed that the amount of austenite formed during intercritical annealing of a given steel can be strongly influenced by the annealing temperature and the pre-annealing conditions of the hot band(coiling temperature) and cold band(% cold reduction).Current experiments have explored the combination of pre-annealing conditions and four annealing practices to help define the best thermal path needed to optimize the strength-formability balance in these higher strength DP steels.The steels used in these experiments contained(i) low carbon content for good spot weldability,(ii) the hardenability additions Mo and Cr for strength,and(iii) V for grain refinement,precipitation hardening and temper resistance.When processed correctly,these steels exhibited UTS levels up to 1 000 MPa,total elongation to 25%,reduction in area to 45%,and Hole Expansion ratios to 50%.The results of this program will be presented and discussed.
Study on the Inhomogeneous Defect and Corrosion Resistance Characteristic of 55%Al-43.4%Zn-1.6%Si Alloy Coating on the Steel Substrate
Song JinYing, Du GuoQiang, Wang YueHua, Zhang Yuan, Chen LianSheng, Tian YaQiang, Zhao DingGuo
2016, 37(3): 151-157. doi: 10.7513/j.issn.1004-7638.2016.03.028
Abstract(12) PDF(1)
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Spangle characteristic and distribution of alloying elements coating on the steel substrate of 55% Al-43.4% Zn-1.6% Si alloy are carried out by using OM,SEM and EDS testing means.Coating corrosion resistance behavior of different areas was studied by polarization curve,and the formation process of hot dip and evolution of microstructures in the process of corrosion has been discussed.The results show that the different sizes of spangle microstructures consist of vertical grid dendrites arms with same spacing and and the composition of the different size of spangle surface contains Al,Zn and trace amounts of Si element where the ratio of Al/Zn is about 2:1.It is found out that inhomogeneous distribution of spangle size is mainly caused by the different number of α-{Fe,Al,Si} in the metal compounds layer.The smaller spangle size generates more τ5 phase in the IMC layerand hence more shape nucleolinus in the solidification process,and the resulting spangle is much more fine.Multi-point statistical collection indicates that the different sizes of spangle have the same corrosion resistance behavior.
Analysis on Forming Reasons and Improvement Measures of Crack Defects on Bars
Cui JinZhong, Gao TianZuo
2016, 37(3): 158-162. doi: 10.7513/j.issn.1004-7638.2016.03.029
Abstract(14) PDF(1)
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Crack defects are commonly found on the steel bar products and caused by many factors.Analysis on the causes of the crack defect of bar products by means of the optical microscopy,scanning electron microscopy(SEM) and energy dispersive spectrum(EDS).It is found out that factors causing crack defects can be divided into four kinds:bar matrix in the presence of a large number of non metallic inclusions,surface decarburization,banded structure and sulfide inclusions.Therefore,the countermeasures have been developed through the optimization of steelmaking,continuous casting,electromagnetic stirring and desulfurization technology,and lead to a great increase in the yield rate of the finished products.
2016, 37(3): 163-164.
Abstract(25) PDF(1)
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