Lü Bo. Study on Microstructure and Photocatalytic Activity of TiO2 with Surface Modification by SiO2 and Al2O3[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(2): 55-61. doi: 10.7513/j.issn.1004-7638.2016.02.010
Citation:
Lü Bo. Study on Microstructure and Photocatalytic Activity of TiO2 with Surface Modification by SiO2 and Al2O3[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(2): 55-61. doi: 10.7513/j.issn.1004-7638.2016.02.010
Lü Bo. Study on Microstructure and Photocatalytic Activity of TiO2 with Surface Modification by SiO2 and Al2O3[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(2): 55-61. doi: 10.7513/j.issn.1004-7638.2016.02.010
Citation:
Lü Bo. Study on Microstructure and Photocatalytic Activity of TiO2 with Surface Modification by SiO2 and Al2O3[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(2): 55-61. doi: 10.7513/j.issn.1004-7638.2016.02.010
Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China
Sodium silicate and sodium metaaluminate were used for the inorganic surface modification of TiO2 matrix to block the electron-hole produced by light irradiation on TiO2,finally attempting to improve the weatherability and dispersity of TiO2.The growth of membrane layer on the surface of TiO2 particles was tested online by focused beam reflectance measurement(FBRM).The phase composition and micro/nano structure of TiO2 before and after modification were characterized and analyzed by X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),scanning electron microscope(SEM),transmission electron microscope(TEM) and specific surface area test(BET),respectively.The results show that a uniform and compact amorphous SiO2 and stable boehmite colloid membrane layer have been formed on the surface of TiO2 particles,which can fill the oxygen vacancies and make up the defects of photochemical activity for TiO2.It is also indicated through the test of photodegradation that the photocatalytic activity of TiO2 samples respectively with single silicon and silicon-aluminum binary modifications decrease with slower degradation rates,proving that TiO2 has gotten effective protection.