Bai Tianjiao, Ding Weizhong, Shang Xingfu, Tan Dingsheng, Guo Shuqiang. Research on Reduction-rusting Process of Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 8-13,19. doi: 10.7513/j.issn.1004-7638.2016.04.002
Citation:
Bai Tianjiao, Ding Weizhong, Shang Xingfu, Tan Dingsheng, Guo Shuqiang. Research on Reduction-rusting Process of Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 8-13,19. doi: 10.7513/j.issn.1004-7638.2016.04.002
Bai Tianjiao, Ding Weizhong, Shang Xingfu, Tan Dingsheng, Guo Shuqiang. Research on Reduction-rusting Process of Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 8-13,19. doi: 10.7513/j.issn.1004-7638.2016.04.002
Citation:
Bai Tianjiao, Ding Weizhong, Shang Xingfu, Tan Dingsheng, Guo Shuqiang. Research on Reduction-rusting Process of Panzhihua Ilmenite[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 8-13,19. doi: 10.7513/j.issn.1004-7638.2016.04.002
State Key Laboratory of Advanced Special Steel Metallurgy and Preparation, Shanghai Key Laboratory of Technical Development and Application of Ferrous Metallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China
Received Date: 2016-04-14 Available Online:
2023-12-04
The separation effect of iron and titanium and the existence forms of iron byproducts in NH4Cl rusting solution for the reductive ilmenite which was obtained by oxidation at 1 000℃ for 1 h then reduction at 1 000℃ for 1 h with H2/CO mixed gas using Panzhihua ilmenite as raw material were studied in this paper.The results show that in an appropriate reduction-rusting system for the ilmenite with 92.40%metallization rate,the TiO2 concentration of Ti-rich material in the corrosion products can be increased to 75.12% and the addition of hydrochloric acid in the rusting solution can sequentially increase the TiO2 concentration of Ti-rich material to 81.76%.Pure Fe3O4 and γ-FeO(OH),or mixture composed of Fe2O3,γ-FeO(OH) and α-FeO(OH) in the iron byproducts for corrosion can be obtained.