Liu Zhibin, Zhang Xidong, Ma Deng, Zhao Bin, Wu Wei. Vanadium Distribution between Slag and Iron at Blow End Point and Its Phase Analysis[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 25-28. doi: 10.7513/j.issn.1004-7638.2016.04.005
Citation:
Liu Zhibin, Zhang Xidong, Ma Deng, Zhao Bin, Wu Wei. Vanadium Distribution between Slag and Iron at Blow End Point and Its Phase Analysis[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 25-28. doi: 10.7513/j.issn.1004-7638.2016.04.005
Liu Zhibin, Zhang Xidong, Ma Deng, Zhao Bin, Wu Wei. Vanadium Distribution between Slag and Iron at Blow End Point and Its Phase Analysis[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 25-28. doi: 10.7513/j.issn.1004-7638.2016.04.005
Citation:
Liu Zhibin, Zhang Xidong, Ma Deng, Zhao Bin, Wu Wei. Vanadium Distribution between Slag and Iron at Blow End Point and Its Phase Analysis[J]. IRON STEEL VANADIUM TITANIUM, 2016, 37(4): 25-28. doi: 10.7513/j.issn.1004-7638.2016.04.005
The vanadium extraction in combination blowing converter was simulated by 500 kg scale intermediate frequency induction furnace with top and bottom combinational blowing function,and the vanadium distribution(Lv) between iron and slag phase at blow end point was investigated. The compositions of vanadium-iron spinel were also analyzed by X-ray diffraction(XRD).The results show that vanadium distribution Lv between slag and iron at the blow end point is 1.8~2.8,which is related to the FeO content in slag.To ensure the quality of vanadium slag and decrease the FeO content with lower iron loss,the content of vanadium at the blow end point should be controlled at an appropriate high level. The formula of vanadium-iron spinel in vanadium slag was Fe O(Fe,V)2O3 indicating +3 for the valence of vanadium in slag phase.A small amount of V2+ species was evidenced to exist in the vanadium slag at the initial stage of blowing and gradually decreased with increase in oxygen supply.