Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China
Efficient extraction and separation of vanadium from vanadium solution containing high concentration of chromium and sodium was investigated by hydrothermal-hydrolysis method to solve the treatment difficulties of wastewater with high concentration of Na+ and NH4+ produced in traditional vanadium precipitation by ammonium salts and provide favorable conditions for the following chromium extraction,according to the characteristics of vanadium-chromium solution obtained by process of sodium roasting-water leaching of high-chromium vanadium slag for vanadium and chromium extraction.The relationship between parameters (hydrolysis temperature,p H and reaction time) and rates of vanadium precipitation and chromium loss was studied.The results show that near 90% of vanadium precipitation rate and vanadium pentoxide (V2O5) satisfying YB/T 5304—2011 standard which is produced by calcination of the waterwashed hydrolysis product can be obtained with reaction at 120 ℃ for 180 min in p H = 1.8 system.