Wu Jianchun, Lu Ruifang. Study on the Optically Variable Property of Nano-TiO2[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(1): 7-12. doi: 10.7513/j.issn.1004-7638.2019.01.002
Citation:
Wu Jianchun, Lu Ruifang. Study on the Optically Variable Property of Nano-TiO2[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(1): 7-12. doi: 10.7513/j.issn.1004-7638.2019.01.002
Wu Jianchun, Lu Ruifang. Study on the Optically Variable Property of Nano-TiO2[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(1): 7-12. doi: 10.7513/j.issn.1004-7638.2019.01.002
Citation:
Wu Jianchun, Lu Ruifang. Study on the Optically Variable Property of Nano-TiO2[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(1): 7-12. doi: 10.7513/j.issn.1004-7638.2019.01.002
Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China
The morphology and particle size of nano-TiO2 were analyzed by transmission electron microscopy(TEM),and the optically variable property of the automobile paint made of the nano-TiO2 was also analyzed by a five-angle colorimeter.The results show that the paint film containing single nano-TiO2 has no angle-dependent optical effect,showing white phase on the white substrate while blue phase on the black substrate.The automobile paint composed of nano-TiO2 and aluminum powder has an optically variable property.The particle size of TiO2 has a great influence on the optically variable property of the paint,where the aluminum paint modified by ordinary titanium white with an average particle size of 280 nm has no angle-dependent optical effect but it shows significant angle-dependent optical effect for the aluminum paint modified the nano-TiO2 with an average particle size of 35 nm.Furthermore,the color variation from different angles for the paint increases with increase of the nano-TiO2 addition.The angle-dependent optical effect is originated from Rayleigh scattering occurring on the surface of nano-TiO2 under illumination,exhibiting a golden yellow phase in the parallel direction with the incident light,blue phase perpendicular to the incident light and blue phase with different degrees in other directions dependent on the angles.