Sun Zhenyu, Peng Cheng, Ma Shaobo, Han Qing. Preparation of Li4Ti5O12 by Mechanical Force-assisted Solid-state Method[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(3): 34-38. doi: 10.7513/j.issn.1004-7638.2019.03.007
Citation:
Sun Zhenyu, Peng Cheng, Ma Shaobo, Han Qing. Preparation of Li4Ti5O12 by Mechanical Force-assisted Solid-state Method[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(3): 34-38. doi: 10.7513/j.issn.1004-7638.2019.03.007
Sun Zhenyu, Peng Cheng, Ma Shaobo, Han Qing. Preparation of Li4Ti5O12 by Mechanical Force-assisted Solid-state Method[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(3): 34-38. doi: 10.7513/j.issn.1004-7638.2019.03.007
Citation:
Sun Zhenyu, Peng Cheng, Ma Shaobo, Han Qing. Preparation of Li4Ti5O12 by Mechanical Force-assisted Solid-state Method[J]. IRON STEEL VANADIUM TITANIUM, 2019, 40(3): 34-38. doi: 10.7513/j.issn.1004-7638.2019.03.007
Lithium titanate(Li4Ti5O12) samples were synthesized via mechanical force-assisted solid phase route using titanium dioxide and lithium carbonate as the initial titanium source and lithium source,respectively.The phase structure,morphology,particle size and electrochemical properties of the prepared Li4Ti5O12 were investigated respectively by TGA-DSC,XRD,SEM,granulometer and lithium battery tester.2032 button batteries were prepared using the Li4Ti5O12 samples,and the cycle performance and rate performance were studied.The results show that pure Li4Ti5O12 can be synthesized via mechanical force-assisted solid phase route at 750℃ for 3.5 h,with the uniform particle size of 0.6~2.5 μm,the initial discharge specific capacity of 152.02 mAh/g and 96.5% of the capacity retention rate after 20 times of charge-discharge cycle.