Fu Zibi, Jiang Lin, Rao Yuzhong. Separation of Vanadium and Chromium from Vanadium-chromium Solution by Calcium Salt Precipitation[J]. IRON STEEL VANADIUM TITANIUM, 2020, 41(5): 37-40,50. doi: 10.7513/j.issn.1004-7638.2020.05.006
Citation:
Fu Zibi, Jiang Lin, Rao Yuzhong. Separation of Vanadium and Chromium from Vanadium-chromium Solution by Calcium Salt Precipitation[J]. IRON STEEL VANADIUM TITANIUM, 2020, 41(5): 37-40,50. doi: 10.7513/j.issn.1004-7638.2020.05.006
Fu Zibi, Jiang Lin, Rao Yuzhong. Separation of Vanadium and Chromium from Vanadium-chromium Solution by Calcium Salt Precipitation[J]. IRON STEEL VANADIUM TITANIUM, 2020, 41(5): 37-40,50. doi: 10.7513/j.issn.1004-7638.2020.05.006
Citation:
Fu Zibi, Jiang Lin, Rao Yuzhong. Separation of Vanadium and Chromium from Vanadium-chromium Solution by Calcium Salt Precipitation[J]. IRON STEEL VANADIUM TITANIUM, 2020, 41(5): 37-40,50. doi: 10.7513/j.issn.1004-7638.2020.05.006
Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China
Vanadium and chromium were selectively separated from the vanadium-chromium solution by calcium salt precipitation.The effects of CaO dosage,precipitation temperature and time on vanadium precipitation and the removal of chromium from calcium vanadate were studied.The results show that a precipitation rate of 99.89% and 1.26% respectively for vanadium and chromium can be obtained at 90~95 ℃ for 60~90 min with the ratio of actual amount of CaO to theoretical amount of CaO at 1.17~1.25.After beating and washing at room temperature,the content of chromium in calcium vanadate is about 0.06%,leaving the main phase of Ca10V6O25.