Volume 44 Issue 3
Jun.  2023
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Wen Li, Ai Liqun, Lei Yue, Li Yaqiang, Hong Lukuo, Zhu Guangpeng, Wang Xufeng. Thermodynamic study on equilibrium phase transformation and precipitation of 12Cr1MoVG steel[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(3): 183-190. doi: 10.7513/j.issn.1004-7638.2023.03.028
Citation: Wen Li, Ai Liqun, Lei Yue, Li Yaqiang, Hong Lukuo, Zhu Guangpeng, Wang Xufeng. Thermodynamic study on equilibrium phase transformation and precipitation of 12Cr1MoVG steel[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(3): 183-190. doi: 10.7513/j.issn.1004-7638.2023.03.028

Thermodynamic study on equilibrium phase transformation and precipitation of 12Cr1MoVG steel

doi: 10.7513/j.issn.1004-7638.2023.03.028
  • Received Date: 2022-09-24
  • Publish Date: 2023-06-30
  • The phase transformation and precipitation behavior of 12Cr1MoVG steel during cooling were studied by thermodynamic software JMatPro, and the effect of alloying elements in the steel on longitudinal crack sensitivity was analyzed. The results show that the transformation path of 12Cr1MoVG steel from 1600 ℃ to 400 ℃ is L→ L+δ→ L+δ+γ→ δ+γ→ γ→ γ+MnS→ γ+MnS+MN→ γ+MnS+M(C,N)→ γ+α+MnS+M(C,N)→ γ+α+MnS+M(C,N)+AlN→ γ+α+MnS+M(C,N)+M(C,N)+AlN+M23C6→ α+MnS+M(C,N)+M(C,N)+AlN+M23C6. With the increase of P, S, Mo, V and Cr contents in the steel, the longitudinal crack sensitivity increases. While, the longitudinal crack sensitivity decreases with the increase of Mn and Si contents. Based on the temperature range of the (α+γ) two-phase region and the precipitation behavior of M (C, N), the low-temperature brittleness temperature range is calculated to be in the range of 747.6~869 ℃, which is basically consistent with the tensile testing results.
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  • [1]
    Wang J, Sun J, Yu X, et al. Microstructures and mechanical properties of 12Cr1MoVG tube welded joints with/without post-weld heat treatment[J]. Journal of Materials Engineering and Performance, 2017,26(10):4659−4666. doi: 10.1007/s11665-017-2936-8
    [2]
    Harada N, Takuma M, Tsujikawa M, et al. Effects of V addition on improvement of heat shock resistance and wear resistance of Ni–Cr–Mo cast steel brake disc[J]. Wear, 2013, 302(s1–2): 1444-1452.
    [3]
    Samrout H, Abdi R E. Fatigue behaviour of 28CrMoV5-08 steel under thermomechanical loading[J]. International Journal of Fatigue, 1998,20(8):555−563. doi: 10.1016/S0142-1123(97)00130-8
    [4]
    Xia Yunfeng, Zhang Guangchuan, Zhao Weiguo, et al. The application of JMatPro in the design of heat treatment process of 4Cr5Mo2V steel[J]. New Technology and Process, 2019,(4):14−18. (夏云峰, 张光川, 赵卫国, 等. JMatPro在4Cr5Mo2V钢热处理工艺设计中的应用[J]. 新技术新工艺, 2019,(4):14−18.

    Xia Yunfeng, Zhang Guangchuan, Zhao Weiguo, et al. The application of JMatPro in the design of heat treatment process of 4 Cr5 Mo2 V steel [J]. New Technology and Process, 2019 (4): 14-18.
    [5]
    Wu Dan, Wang Fuming, Wang Chengming, et al. Thermodynamic study on Cr-Mo-V system high speed rail brake disc steel[J]. Journal of Material Heat Treatment, 2016,37(8):228−233. (吴丹, 王福明, 王程明, 等. Cr-Mo-V系高铁制动盘用钢的热力学研究[J]. 材料热处理学报, 2016,37(8):228−233.

    Wu Dan, Wang Fuming, Wang Chengming, et al. Thermodynamic study on Cr-Mo-V system high speed rail brake disc steel [J] . Journal of Material Heat Treatment, 2016, 37 (8): 228-233.
    [6]
    Brimacombe J K, Sorimachi K. Crack formation in the continuous casting of steel[J]. Metallurgical Transactions B, 1977,8(2):489−505. doi: 10.1007/BF02696937
    [7]
    Samarasekera I V, Brimacombe J K. The thermal field in continuous-casting moulds[J]. Canadian Metallurgical Quarterly, 1979,18(3):251−266. doi: 10.1179/cmq.1979.18.3.251
    [8]
    Kim K, Yeo T J, Oh K H, et al. Effect of carbon and sulfur in continuously cast strand on longitudinal surface cracks[J]. ISIJ International, 1996,36(3):284−289. doi: 10.2355/isijinternational.36.284
    [9]
    Clyne T W, Wolf M, Kurz W. The effect of melt composition on solidification cracking of steel, with particular reference to continuous casting[J]. Metallurgical Transactions B, 1982,13(2):259−266. doi: 10.1007/BF02664583
    [10]
    Wang Yi, Sun Feng, Dong Xianping, et al. Thermodynamic study on equilibrium precipitation phases in a novel Ni-Co base superalloy[J]. Acta Metallurgica Sinica, 2010,46(3):334−339. (王衣, 孙锋, 董显平, 等. 新型Ni-Co基高温合金中平衡析出相的热力学研究[J]. 金属学报, 2010,46(3):334−339. doi: 10.3724/SP.J.1037.2010.00334

    Wang Yi, Sun Feng, Dong Xianping, et al. Thermodynamic study on equilibrium precipitation phases in a novel Ni-Co base superalloy [J]. Acta Metallurgica Sinica, 2010, 46(3): 334-339. doi: 10.3724/SP.J.1037.2010.00334
    [11]
    Wang Li, Zhou Zhongjiao, Zhang Shaohua, et al. Crack initiation and propagation around holes of Ni-based single crystal superalloy during thermal fatigue cycle[J]. Acta Metallurgica Sinica, 2015,51(10):1273−1278. (王莉, 周忠娇, 张少华, 等. 镍基单晶高温合金冷热循环过程中圆孔周围裂纹萌生与扩展行为[J]. 金属学报, 2015,51(10):1273−1278.

    Wang Li, Zhou Zhongjiao, Zhang Shaohua, et al. Crack initiation and propagation around holes of Ni-based single crystal superalloy during thermal fatigue cycle[J]. Acta Metallurgica Sinica , 2015, 51(10): 1273-1278.
    [12]
    Saunders N, Miodownik A P, Schillé J P. Modelling of the thermo-physical and physical properties for solidification of Ni-based superalloys[J]. Journal of Materials Science, 2004,39(24):7237−7243. doi: 10.1023/B:JMSC.0000048737.32055.7a
    [13]
    Saunders N, Guo U K Z, Li X, et al. Using JMatPro to model materials properties and behavior[J]. JOM, 2003,55(12):60−65. doi: 10.1007/s11837-003-0013-2
    [14]
    蔡开科. 连铸坯质量控制[M]. 北京: 冶金工业出版社, 2010.

    Cai Kaike. Quality control of continuous casting slab [M]. Beijing: Metallurgical Industry Press, 2010.
    [15]
    Dong Kai, Liu Jianhua, Zhang Pei, et al. Study on high temperature mechanical properties of continuous casting slab of 12Cr1MoVG steel[J]. Iron Steel Vanadium Titanium, 2020,41(5):124−129. (董凯, 刘建华, 张佩, 等. 12Cr1MoVG钢连铸坯高温力学性能研究[J]. 钢铁钒钛, 2020,41(5):124−129. doi: 10.7513/j.issn.1004-7638.2020.05.021

    Dong Kai, Liu Jianhua, Zhang Pei, et al. Study on high temperature mechanical properties of continuous casting slab of 12 Cr1 MoVG steel [J]. Iron Steel Vanadium Titanium, 2020, 41 (5): 124-129. doi: 10.7513/j.issn.1004-7638.2020.05.021
    [16]
    Li Yaqiang, Liu Jianhua, He Yang, et al. Surface defects analysis and mechanism research of 15CrMoG steel bars and process improvement[J]. Special Steel, 2019,40(6):1−6. (李亚强, 刘建华, 何杨, 等. 15CrMoG钢棒材表面缺陷机理分析和工艺改进[J]. 特殊钢, 2019,40(6):1−6. doi: 10.3969/j.issn.1003-8620.2019.06.001

    Li Yaqiang, Liu Jianhua, He Yang, et al. Surface defects analysis and mechanism research of 15 CrMoG steel bars and process improvement[J]. Special Steel, 2019, 40(6): 1-6. doi: 10.3969/j.issn.1003-8620.2019.06.001
    [17]
    李亚强. 亚包晶高压锅炉管钢凝固特性与固态相变研究[D]. 北京: 北京科技大学, 2021.

    Li Yaqiang. Study on solidification characteristics and solid phase transformation of hypoperitectic high pressure boiler tube steel [D]. Beijing: Beijing University of Science and Technology, 2021.
    [18]
    崔忠圻, 刘北兴. 金属学与热处理原理[M]. 哈尔滨: 哈尔滨工业大学出版社, 2004.

    Cui Zhongqi, Liu Beixing. Principles of metallography and heat treatment [M]. Harbin: Harbin University of Technology Press, 2004.
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