Study on speciation analysis of vanadate

Pu Yuwen; Liu Xi; Tang Kang; Xu Zongyuan; Zheng Guocan; Chen Yan; Liu Zuohua; Du Jun; Peng Yi; Tao Changyuan

doi:10.7513/j.issn.1004-7638.2023.06.003

Volume 44 Issue 6

Dec. 2023

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Pu Yuwen, Liu Xi, Tang Kang, Xu Zongyuan, Zheng Guocan, Chen Yan, Liu Zuohua, Du Jun, Peng Yi, Tao Changyuan. Study on speciation analysis of vanadate[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(6): 17-23. doi: 10.7513/j.issn.1004-7638.2023.06.003

Citation:

Pu Yuwen, Liu Xi, Tang Kang, Xu Zongyuan, Zheng Guocan, Chen Yan, Liu Zuohua, Du Jun, Peng Yi, Tao Changyuan. Study on speciation analysis of vanadate[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(6): 17-23. doi: 10.7513/j.issn.1004-7638.2023.06.003

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Study on speciation analysis of vanadate

doi: 10.7513/j.issn.1004-7638.2023.06.003

1.
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China
2.
Analysis and Testing Center of Chongqing University, Chongqing 401331, China
3.
Pangang Group Panzhihua Iron and Steel Research Institute Co., Ltd., Panzhihua 617000, Sichuan, China

Received Date: 2023-04-04
Available Online: 2024-01-11
Publish Date: 2023-12-30

Abstract

Abstract

In the typical calcium calcination–acid leaching process of converter vanadium slag, the leaching solution contains many impurities, and the change of vanadium phase in this process will directly affect the overall recovery rate of vanadium. It is a great challenge to determine the migration and transformation of vanadium phase in the leaching process under different conditions. Therefore, the effects of different conditions on vanadium speciation and transformation rules were studied. The results show that the software Visual MINTEQ 3.1 simulates and calculates the structural change of polyvanadate, which provides a theoretical basis for the precipitation of vanadium at different pH. The matrix assisted laser desorption time-of-flight mass spectrometer (MALDI-TOF-MS) was used to detect the existing form of vanadium. The test results showed that when the pH value was low, V₁₀O₂₈⁶⁻was the main substance. With the increase of the pH value, the content of VO₃⁻ and V₄O₁₂⁴⁻ increased and became one of the main substances. The concentration causes changes of the relative content, i.e., the lower the concentration, the less the VO₃⁻ content and the more the V₁₀O₂₈⁶⁻ content, while different anions and cations have no significant effect on vanadium morphology. This result enriches the study of vanadium morphology, provides a theoretical basis for the directional conversion of vanadium elements in vanadium slag, and also provides a basis for the subsequent vanadium precipitation process to improve the vanadium extraction efficiency of converter vanadium slag.
- vanadium extrantion,
- vanadate,
- morphological analysis,
- mass spectrometry,
- Visual MINTEQ 3.1 simulatio

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References(30)

References

[1]	Li H Y, Wang C J, Yuan Y H, et al. Magnesiation roasting-acid leaching: A zero-discharge method for vanadium extraction from vanadium slag[J]. J Clean Prod, 2020,260:121091. doi: 10.1016/j.jclepro.2020.121091
[2]	Zhu X B, Li W, Zhang C X. Extraction and removal of vanadium by adsorption with resin 201*7 from vanadium waste liquid[J]. Environ Res, 2020,180:108865. doi: 10.1016/j.envres.2019.108865
[3]	Teng A J, Xue X X. A novel roasting process to extract vanadium and chromium from high chromium vanadium slag using a NaOH−NaNO₃ binary system[J]. J Hazard Mater, 2019,379:120805. doi: 10.1016/j.jhazmat.2019.120805
[4]	Xu Zhengzhen, Liang Jinglong, Li Hui, et al. Research status and prospects of vanadium recovery in vanadium containing wastes[J]. Multipurpose Util Miner Resour, 2020,(3):8−13. (徐正震, 梁精龙, 李慧, 等. 含钒废弃物中钒的回收研究现状及展望[J]. 矿产综合利用, 2020,(3):8−13. Xu Z Z, Liang J L, Li H, et al. Research status and prospects of vanadium recovery in vanadium containing wastes [J]. Multipurpose Util Miner Resour, 2020(3): 8.
[5]	Wu Enhui, Hou Jing, Li Jun. Experimental study on vanadium extraction from vanadium and chromium slag by oxidizing and calcifying roasting and acid leaching[J]. Rare Metals and Cemented Carbide, 2017,45(6):8−13. (吴恩辉, 侯静, 李军. 钒铬渣氧化钙化焙烧-酸浸提钒实验研究[J]. 稀有金属与硬质合金, 2017,45(6):8−13. Wu Enhui, Hou Jing, Li Jun. Experimental study on vanadium extraction from vanadium and chromium slag by oxidizing and calcifying roasting and acid leaching[J]. Rare Metals and Cemented Carbide, 2017, 45 (6): 8-13.
[6]	Xiao Xiudi, Zhang Hua, Chai Guanqi, et al. A cost-effective process to prepare VO₂ (M) powder and films with superior thermochromic properties[J]. Materials Research Bulletin, 2014,51:6−12. doi: 10.1016/j.materresbull.2013.11.051
[7]	Johann Nathan Nicholas, Gabriel Da Silva, Sandra Kentish, et al. Use of vanadium (V) oxide as a catalyst for CO₂ hydration in potassium carbonate systems[J]. Industrial & Engineering Chemistry Research, 2014,53:3029−3039.
[8]	Wu Gao, Pan Peng, Fan Helin, et al. Research status and development trend of vanadium extraction from vanadium slag[J]. Jiangxi Metallurgy, 2020,40(4):19−27. (吴诰, 潘鹏, 范鹤林, 等. 钒渣提钒研究现状及发展趋势[J]. 江西冶金, 2020,40(4):19−27. Wu Gao, Pan Peng, Fan Helin, et al. Research status and development trend of vanadium extraction from vanadium slag [J]. Jiangxi Metallurgy, 2020, 40 (4): 19-27.
[9]	Hong Ying, Guo Shuanghua, Li Yu, et al. Progress in vanadium extraction technology[J]. Guangzhou Chemical Industry, 2021,49(17):23−25. (洪颖, 郭双华, 李雨, 等. 提钒技术研究进展[J]. 广州化工, 2021,49(17):23−25. doi: 10.3969/j.issn.1001-9677.2021.17.008 Hong Ying, Guo Shuanghua, Li Yu, et al. Progress in vanadium extraction technology [J]. Guangzhou Chemical Industry, 2021, 49 (17): 23-25. doi: 10.3969/j.issn.1001-9677.2021.17.008
[10]	Xie Yu, Ye Guohua, Zuo Qi, et al. Study on the new process of vanadium extraction from vanadium-bearing steel slag[J]. Iron Steel Vanadium Titanium, 2019,40(1):69−77. (谢禹, 叶国华, 左琪, 等. 含钒钢渣提钒新工艺研究[J]. 钢铁钒钛, 2019,40(1):69−77. Xie Yu, Ye Guohua, Zuo Qi, et al. Study on the new process of vanadium extraction from vanadium-bearing steel slag [J]. Iron Steel Vanadium Titanium, 2019, 40 (1): 69-77
[11]	Chen Dongli, Tang Cheng. Research on the influence of vanadium precipitation conditions on vanadium precipitation rate[J]. Equipment Manufacturing Technology, 2016,(1):260−262. (陈冬丽, 唐铖. 沉钒条件对沉钒率的影响研究[J]. 装备制造技术, 2016,(1):260−262. doi: 10.3969/j.issn.1672-545X.2016.01.087 Chen Dongli, Tang Cheng. Research on the influence of vanadium precipitation conditions on vanadium precipitation rate [J]. Equipment Manufacturing Technology, 2016 (1): 260-262. doi: 10.3969/j.issn.1672-545X.2016.01.087
[12]	Zhang Juhua, Yan Zhefeng, Zhang Li. Influencing factors and kinetics of vanadium precipitation from calcified vanadium extraction solution[J]. Journal of Process Engineering, 2018,18(1):111−117. (张菊花, 严哲锋, 张力. 钙化提钒溶液沉钒的影响因素及沉钒动力学[J]. 过程工程学报, 2018,18(1):111−117. Zhang Juhua, Yan Zhefeng, Zhang Li. Influencing factors and kinetics of vanadium precipitation from calcified vanadium extraction solution [J]. Journal of Process Engineering, 2018, 18 (1): 111-117.
[13]	Zhang J H, Zhang W, Zhang L, et al. Mechanism of vanadium slag roasting with calcium oxide[J]. International Journal of Mineral Processing, 2015,138:20−29. doi: 10.1016/j.minpro.2015.03.007
[14]	Zhang J H, Zhang W, Xue Z L. Oxidation kinetics of vanadium slag roasting in the presence of calcium oxide[J]. Mineral Processing and Extractive Metallurgy Review, 2017,38(5):265−273. doi: 10.1080/08827508.2017.1289197
[15]	Liu H B, Du H, Wang D W, et al. Kinetics analysis of decomposition of vanadium slag by KOH sub-molten salt method[J]. Transactions of Nonferrous Metals Society of China, 2013,23(5):1489−1500. doi: 10.1016/S1003-6326(13)62621-7
[16]	Zhang G Q, Zhang T A, Li G Z, et al. Extraction of vanadium from LD converter slag by pressure leaching process with titanium white waste acid[J]. Rare Metal Materials Engineering, 2015,44(8):1894−1898. doi: 10.1016/S1875-5372(15)30120-X
[17]	Liu Z H, Li Y, Chen M L, et al. Enhanced leaching of vanadium slag in acidic solution by eletro-oxidation[J]. Hydrometallurgy, 2016,159:1−5.
[18]	Yu Tangxia, Wen Jing, Sun Hongyan, et al. Effect of phase structure of vanadium slag with different calcium content on vanadium extraction by calcification[J]. Iron Steel Vanadium Titanium, 2021,42(5):18−23. (余唐霞, 温婧, 孙红艳, 等. 不同钙含量钒渣的物相结构对钙化提钒的影响[J]. 钢铁钒钛, 2021,42(5):18−23. Yu Tangxia, Wen Jing, Sun Hongyan, et al. Effect of phase structure of vanadium slag with different calcium content on vanadium extraction by calcification [J] . Iron Steel Vanadium Titanium, 2021, 42 (5): 18-23.
[19]	Tao Changyuan, Yu Qiang, Liu Zuohua, et al. Directional conversion and removal of complex phosphorus compounds from acidic leaching solution containing vanadium[J]. Journal of Water Process Engineering, 2020,37:101−131.
[20]	Liu Hong, Zhang Yimin, Huang Jing. N235 supported liquid membrane separation of vanadium extraction from shale and mass transfer mechanism[J]. Chinese Journal of Nonferrous Metals, 2020,30(9):2216−2223. (刘红, 张一敏, 黄晶. N235支撑液膜分离页岩提钒酸浸液及传质机理[J]. 中国有色金属学报, 2020,30(9):2216−2223. Liu Hong, Zhang Yimin, Huang Jing. N235 supported liquid membrane separation of vanadium extraction from shale and mass transfer mechanism [J]. Chinese Journal of Nonferrous Metals, 2020, 30 (9): 2216-2223.
[21]	Selling A, Andersson I, Pettersson L, et al. Multicomponent polyanions. 47. The aqueous vanadophosphate system[J]. Inorganic Chemistry, 2002,33(14):3141−3150.
[22]	Zhang Weiguang, Zhang Ting^,an, Lü Guozhi, et al. Thermodynamic study on the V(V)-P(V)-H₂O system in acidic leaching solution of vanadium-bearing converter slag[J]. Separation & Purification Technology, 2019,218:164−172.
[23]	Zhang Weiguang, Zhang Ting'an, Sun Ying, et al. Thermodynamic analysis of vanadium extraction from acidic solution of phosphorus-sulfur-vanadium-water system[J]. Rare Metal Materials and Engineering, 2021,50(12):4265−4271. (张伟光, 张廷安, 孙颖, 等. 磷-硫-钒-水体系酸性溶液中钒的提取热力学分析[J]. 稀有金属材料与工程, 2021,50(12):4265−4271. Zhang Weiguang, Zhang Ting'an, Sun Ying, et al. Thermodynamic analysis of vanadium extraction from acidic solution of phosphorus-sulfur-vanadium-water system [J]. Rare Metal Materials and Engineering, 2021, 50 (12): 4265-4271.
[24]	Zhang J H, Zhang W, Zhang L, et al. A critical review of technology for selective recovery of vanadium from leaching solution in V₂O₅ production[J]. Solvent Extraction and Ion Exchange, 2014,32(3):221−248. doi: 10.1080/07366299.2013.877753
[25]	Zhang J H, Zhang W, Xue Z L. An environment-friendly process featuring calcified roasting and precipitation purification to prepare vanadium pentoxide from the converter vanadium slag[J]. Metals, 2018,9(1):103390.
[26]	肖亮. 钒溶液沉钒工艺研究进展 [C]// 第三届钒产业先进技术研讨与交流会论文集. 西昌: 钒钛资源综合利用产业技术创新战略联盟, 钒钛资源综合利用国家重点实验室, 2015. Xiao Liang. Research progress of vanadium solution vanadium precipitation process [C]//Proceedings of the 3rd Vanadium Industry Advanced Technology Seminar and Exchange Conference. Xichang: Strategic Alliance for Technological Innovation of Vanadium and Titanium Resources Comprehensive Utilization Industry, State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, 2015.
[27]	杨保祥, 何金勇, 张桂芳. 钒基材料制造[M]. 北京: 冶金工业出版社, 2014: 104. Yang Baoxiang, He Jinyong, Zhang Guifang. Vanadium-based material manufacturing[M]. Beijing: Metallurgical Industry Press, 2014: 104.
[28]	Murthy G V R, Reddy T S, Rao S B. Extraction and simultaneous spectro photometric determination of vanadium(IV) and vanadium(V) in admixture with 2-hydroxyacetophenone oxime[J]. Analyst, 1989,114(4):493. doi: 10.1039/an9891400493
[29]	Al Rawahi W A, Ward N I. Field-based application of developed solid phase extraction with inductively coupled plasma mass spectrometry for vanadium speciation analysis of groundwaters from Argentina[J]. Talanta, 2017,165:391−397. doi: 10.1016/j.talanta.2016.12.078
[30]	Jen J F, Wu M H, Yang T C. Simultaneous determination of vanadium(IV) and vanadium(V) as EDTA complexes by capillary zone electrophoresis - ScienceDirect[J]. Analytica Chimica Acta, 1997,339(3):251−257. doi: 10.1016/S0003-2670(96)00482-5