Volume 44 Issue 6
Dec.  2023
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Wu Pingchuan, Liu Zhibing, Liu Jing, Ping Haoyan, Ma Jintao, Wang Changlong, Zheng Yongchao, Jing Jianlin, Qi Yang, Zhai Yuxin, Liu Feng. Preparation and properties of high-strength fired water permeable brick containing vanadium-titanium iron ore tailings[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(6): 98-109. doi: 10.7513/j.issn.1004-7638.2023.06.015
Citation: Wu Pingchuan, Liu Zhibing, Liu Jing, Ping Haoyan, Ma Jintao, Wang Changlong, Zheng Yongchao, Jing Jianlin, Qi Yang, Zhai Yuxin, Liu Feng. Preparation and properties of high-strength fired water permeable brick containing vanadium-titanium iron ore tailings[J]. IRON STEEL VANADIUM TITANIUM, 2023, 44(6): 98-109. doi: 10.7513/j.issn.1004-7638.2023.06.015

Preparation and properties of high-strength fired water permeable brick containing vanadium-titanium iron ore tailings

doi: 10.7513/j.issn.1004-7638.2023.06.015
  • Received Date: 2023-05-23
    Available Online: 2024-01-11
  • Publish Date: 2023-12-30
  • In order to promote the efficient comprehensive utilization of vanadium-titanium iron ore tailings (VTIOTs), the basic properties and firing mechanism of high-strength fired water permeable bricks (HSFWPB) containing VTIOTs were investigated by using orthogonal test method, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy spectrum analysis (EDS). The results show that when the content of VTIOTs in HSFWPB is 77%, the firing temperature (FT) is 1070 ℃ and the holding time is 110 min, the compressive strength and permeability coefficient of the fired product reach 65.7 MPa and 0.063 cm/s, respectively, which meet the requirements of Cc60 grade products set by “water permeable brick” standard (JC/T 945—2005). The products of HSFWPB containing VTIOTs after firing are diopside (CaMgSi2O6) and augite (Ca(Mg,Fe,Al)(Si,Al)2O6). With the increase of FT and the extension of HT, the low melting point elements of P, Na, K dissolve out, and the contents of Fe and Al in the firing products increase; most of Ca2+ in diopside is replaced by Fe3+, and thus, augite becomes the main crystal phase. With the increase of FT, the pores in the fired products change as follows: closed holes with different sizes→connected pores with irregular diameters→irregular collapse pores→small and uniform circular pores, which provides a guarantee for the permeability of HSFWPB containing VTIOTs. The research has improved the utilization rate of VTIOTs and provides a new approach for the large-scale application of VTIOTs.
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