1. Pangang Gorup Research Institute Co. Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China;
The thermodynamic calculations of element-oxidation in the process of vanadium extraction in converter had been done.The calculated results indicatethat the slag containing calcium can keep P2O5 in the slag.The molecular-ion model was established for high calcium vanadium slag system,and the calculations for setted slag shows that effect of the slag on phosphorus-fixation is greatest when P2O5 content in the slag is 2% and basicity is 1.9; under the condition of logPO2=(-5),phosphorus is fixed by CaO in the form of 3 CaO.P2O5,and the effect was the best.It is proved theoretically that it is feasible for simultaneous dephosphorization and extraction of vanadium in vanadium extraction converter.