Effect of Titanium Liquid Index on Hydrolysis Rate
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摘要: 以工业钛液为原料,采用外加晶种工艺进行水解,考察钛液关键指标:总钛浓度、F值、铁钛比、三价钛浓度对水解率的影响,然后通过水解平衡反应理论推导水解达到平衡时水解率与钛液指标的关系式。试验结果表明:随着总钛浓度的增加,水解率呈现降低趋势;随F值的增加,水解率急剧下降;随铁钛比的增加,水解率也呈下降趋势;随三价钛的增加,水解率呈下降趋势。理论推导的结果表明,在相同稀释比下,水解达到平衡时的水解率与总钛浓度和F值平方乘积成线性关系,其截距与三价钛含量有关。Abstract: Using the industrial titanium liquid as the raw material,the hydrolysis was carried out by external seeding.The effects of titanium liquid index including TiO2 concentration,F value,Fe/TiO2 ratio and Ti3+ concentration on the hydrolysis rate were investigated.Then,the relationship between the hydrolysis rate and the index of titanium liquid was deduced by hydrolysis equilibrium theory.The results show that with the increase of TiO2 concentration,the hydrolysis rate decreases.With the increase of F value,the hydrolysis rate decreases sharply.With the increase of Fe/TiO2,the hydrolysis rate also decreases.With the increase of Ti3+ concentration,the hydrolysis rate is on a downward trend.The theoretical derivation results show that at the same dilution ratio,the hydrolysis rate at the equilibrium is linear with the product of the total titanium concentration and the square F value,and the intercept is related to the concentration of Ti3+.
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Key words:
- titanium dioxide /
- industrial titanium liquid /
- hydrolysis /
- external seeding /
- hydrolysis rate
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