Volume 43 Issue 2
May  2022
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Liu Chan, Lu Ruifang, Sun Qiang, Shi Ruicheng, Wu Jianchun. Study on the correlation between particle size and blue phase indicators of rutile titanium dioxide[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(2): 15-20. doi: 10.7513/j.issn.1004-7638.2022.02.003
Citation: Liu Chan, Lu Ruifang, Sun Qiang, Shi Ruicheng, Wu Jianchun. Study on the correlation between particle size and blue phase indicators of rutile titanium dioxide[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(2): 15-20. doi: 10.7513/j.issn.1004-7638.2022.02.003

Study on the correlation between particle size and blue phase indicators of rutile titanium dioxide

doi: 10.7513/j.issn.1004-7638.2022.02.003
  • Received Date: 2021-01-14
    Available Online: 2022-05-11
  • Publish Date: 2022-04-28
  • In this paper, different K2O-P2O5-ZnO salt treatment formulas were used to treat meta-titanic acid, and eligible rutile titanium dioxide was obtained after calcination. SCX value as the blue phase indicators, Z-Ave value as the ZS90 mean particle size and SEM mean particle size were detected. The linear correlation among them was analyzed by means of linear fitting and regression. The results show that as the correlation indicators, the Pearson correlation coefficients of Z-Ave value and SCX value, SEM mean particle size and SCX value are respectively −0.957 and −0.935. There is a negative linear correlation between the two particle size indicators and SCX value. The R-Sq value of the linear regression equation between SCX value and Z-Ave is 91.6%, while this value between SCX value and SEM mean particle size is 87.5%. The linear regression results show that the prediction effectiveness of the SCX value for Z-Ave value is slightly better than that for SEM mean particle size. Manufacturers can put the conventional monitoring index SCX value into the corresponding fitting equation to carry out statistical analysis and tracking of product particle size, and adjust the process technology accordingly.
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  • [1]
    陈朝华, 刘长河. 钛白粉生产及应用技术[M]. 北京: 化学工业出版社, 2005: 35−48.

    Chen Zhaohua, Liu Changhe. Production and application technology of titanium dioxide pigment[M]. Beijing: Chemical Industry Press, 2005: 35−48.
    [2]
    邓捷, 吴立峰. 钛白粉应用手册[M]. 北京: 化学工业出版社, 2005: 1−35.

    Deng Jie, Wu Lifeng. Application handbook of titanium dioxide pigment[M]. Beijing: Chemical Industry Press, 2005: 1−35.
    [3]
    Vargas W E, Greenwood P, Otterstedt J E, et al. Light scattering in pigmented coatings: experiments and theory[J]. Solar Energy, 2000,68(6):553−561. doi: 10.1016/S0038-092X(00)00024-4
    [4]
    Saila Karvinen. The effects of trace elements on the crystal properties of TiO2[J]. Solid State Sciences, 2003,5:811−819. doi: 10.1016/S1293-2558(03)00082-7
    [5]
    Grzmil B, Kic B, Rabe M. Inhibition of the anatase-Rutile phase transformation with addition of K2O, P2O5, and Li2O[J]. Chemical Papers- Slovak Academy of Sciences, 2004,58(6):410−414.
    [6]
    Tian Yingzi, Chen Kefu, Zhang Heng. Study of the particles of nanometric SiO2, CaCO3 and Al2O3 with Malvern Mastersizer[J]. China Pulp and Paper, 2003,17(3):33−35. (田英姿, 陈克复, 张恒. Malvern粒度仪的使用和测试分析[J]. 中国造纸, 2003,17(3):33−35.
    [7]
    Gesenhues U. Doping of TiO2 pigments by Al3+[J]. Solid State Ionics, 1997,101-103(11):1171−1180.
    [8]
    Gesenhues U. Calcination of metatitanic acid to titanium dioxide white pigments[J]. Chemical Engineering & Technology, 2001,24(7):685−694.
    [9]
    Xu C, Lai X, Zajac G W, et al. Scanning tunneling microscopy studies of the TiO2(110) surface: Structure and the nucleation growth of Pd[J]. Physical Review B, 1997,56(20):13464−13482. doi: 10.1103/PhysRevB.56.13464
    [10]
    Francisco M S P, Mastelaro V R. Inhibition of the anatase-rutile phase transformation with addition of CeO2 to CuO-TiO2 system:   Raman spectroscopy, X-ray diffraction, and textural studies[J]. Chem. Mater., 2002,16(4):2514−2518.
    [11]
    Lydia D N . Photostable rutile titanium dioxide: WO, WO2003006559 A1[P]. 2003.
    [12]
    Ratajska H. The effect of certain promoters on TiO2 crystal structure transformation[J]. Journal of Thermal Analysis, 1992,38(9):2109−2114. doi: 10.1007/BF01979623
    [13]
    José Criado, Concha Real. Mechanism of the inhibiting effect of phosphate on the anatase→rutile transformation induced by thermal and mechanical treatment of TiO2[J]. Journal of the Chemical Society, 1983,79(1):2765−2771.
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