Research on Recovery of Iron from Ti-bearing Blast Furnace Slag by Wet Low-intensity Magnetic Separation
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摘要: 基于攀钢高钛型含钛高炉渣综合利用现状,提出"磁选收铁-活化脱铝—酸浸提钛"的技术途径,以期实现含钛高炉渣中Fe、Al、Ti等有价元素的综合回收。采用X射线衍射仪和矿相显微镜研究了含钛高炉渣中矿物相的组成和金属铁在含钛高炉渣中的赋存状态。采用单一弱磁选和阶段磨矿-阶段弱磁选的工艺回收含钛高炉渣中的金属铁。结果表明:高炉渣中的主要矿物相为钙钛矿、透辉石和镁铝尖晶石,金属铁多以球粒状分布于透辉石等矿物颗粒中,含少量磁铁矿。采用阶磨、阶选的工艺在节约磨矿成本的同时可获得铁精矿的品位为63.5%,回收率为64.2%,有效回收了高炉渣中的金属铁,并为后续工艺中活化脱铝和酸浸提钛创造了有利条件。
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关键词:
- 含钛高炉渣 /
- 金属铁 /
- 阶段磨矿—阶段弱磁选 /
- 综合利用
Abstract: Based on research status of comprehensive utilization of titanium rich blast furnace slag(BF slag)in Pangang,the technical approach of "Fe recycling by magnetic separation-dealuminizing by activation-Ti leaching by acidolysis "was proposed to recycle valuable elements including Fe,Al,and Ti in the slag.Mineral phases and iron occurrence in the Ti-bearing BF slag were analyzed by means of XRD and metallographic microscope.The technologies of single low-intensity magnetic separation and staged grinding and low-intensity magnetic separation were adopted respectively for iron recycling.The results show that the main mineral phases of the BF slag are perovskite,diopside and spinel,and metallic iron existing as globularity mostly distributes in the diopside.Except grinding cost saving,the utilization of the staged grinding and low-intensity magnetic separation also boosts an iron concentrate of 63.5% with a recovery rate of total iron at 64.2%,which creates favorable conditions for subsequent dealuminizing and Ti leaching. -
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