摘要:
通过烧结杯试验结合热力学计算,分析烧结矿显微结构,研究承德中钛型钒钛烧结矿液相生成量的影响因素。结果表明,碱度提高促进Fe2O3与CaO发生反应形成铁酸钙,液相量增多,改善烧结矿的质量;随着配碳量的增加,烧结过程中产生的热量增加,有利于硅酸盐类高温液相的生成;TiO2含量增加,TiO2会优先与CaO反应生成钙钛矿,抑制性能较好的铁酸钙的生成,生成的钙钛矿分散在渣相与铁矿物之间,削弱了硅酸盐的黏结作用以及钛赤铁矿与钛磁铁矿的连晶作用,导致烧结矿的液相量随之减少。
关键词:
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钒钛烧结矿 /
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液相 /
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铁酸钙 /
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钙钛矿 /
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显微结构
Abstract:
The factors influencing liquid phase generation of vanadium titanium-sinter with moderate titanium content had been investigated by sintering cup test combining with thermodynamic calculations and sinter microstructure observations.The results show that increasing alkalinity promotes Fe2O3 reaction with CaO leading to calcium ferrite formation and thus increase the amount of liquid phase,ie,improve the quality of sinter.With the increase of carbon content,the heat generated during sintering process would increase and then benefit to the generation of liquid silicate.As TiO2 content increases,TiO2 will take preferential reaction with CaO,which promotes perovskite generation and inhibit generation of calcium ferrite with better performance.The resulting perovskite dispersed between the slag phase and iron minerals weakens the bonding of silicate and crystal stock effect of hematite and magnetite containing titanium,and thus cause the reduction in liquid amount of sinter.