摘要:
为进一步分析钛矿护炉条件下,渣铁成分及温度对钛分配比的影响规律,对国内某高炉的生产数据进行统计分析,并借助Fact Sage热力学软件的计算,建立钛分配比的计算模型。结果表明,钛分配比随炉渣碱度的增大而增大,随渣中TiO2含量的升高而降低;钛分配比与铁水温度、硅含量和钛含量呈正相关性,与铁水硫含量呈负相关性。当入炉钛负荷增大时,为保证护炉效果,应适当提高炉渣碱度、增加铁水硅含量,同时控制铁水硫含量并维持较高的铁水温度。模型计算和现场数据计算的钛分配比随渣铁成分及温度的变化规律基本一致,且实际值约为模型计算值的1.7倍。在实际生产中,可依据钛分配比模型来控制和预测渣铁间的钛分配比。
关键词:
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高炉 /
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钛矿护炉 /
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钛分配比 /
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炉渣 /
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铁水 /
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TiO2 /
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模型
Abstract:
In order to further analyze the influence of composition and temperature of slags and hot metal on the titanium distribution ratio under the conditions of furnace protection with titanium ore,the production data of a blast furnace in China was statistically analyzed. And with the help of thermodynamic software Fact Sage,the calculation model of titanium distribution ratio was established.The results indicate that the distribution ratio of titanium increases with the increase of basicity of slags,and decreases with the TiO2 content increasing in slags. The distribution ratio of titanium shows a positive correlation with the temperature of hot metal and the content of silicon and titanium,but is negatively correlated with the sulfur content in the hot metal.In order to ensure the effective furnace protection under higher titanium load,the basicity of slags and the content of silicon in hot metal should be appropriately increased while controlling the sulfur content and maintaining a higher temperature of hot metal.The distribution ratios of titanium calculated by the model and the on-site data have the same variation with the composition and temperature of slags and hot metal,and the actual value is about 1.7 times of the calculated value. In actual production,the titanium distribution ratio between slags and hot metal can be controlled and predicted based on the established model.