Study on Indirect Reduction Law in Carbothermal Reduction Process for Iron Oxide
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摘要: 为了研究碳热还原过程的间接还原规律,在20 kg/h推舟炉加热装备上开展试验,借助在线气体分析仪和金属铁产品的化学成分检测,探讨了煤种、煤粉粒度以及铁精矿粉制备方式等因素对间接还原反应的影响,最后从理论上解析了该反应过程的间接还原来源和定量关系。研究表明:间接还原主要来源于碳热直接还原过程产生的CO与氧化铁间发生的化学反应;步进还原过程中,煤中部分挥发分参与间接反应,使得稳定期煤气中的CO2/(CO+CO2)比例超过20%;铁精矿粉粒度越小,还原效果越好,间接还原比例越高。Abstract: In order to study the law of indirect reduction in the process of carbothermal reduction,experiments were carried out on a 20 kg/h pushing boat heating furnace.The changes of gas composition in the process were recorded by on-line gas analyzer,and composition of reduced samples was measured.The influence of coal type,particle size of pulverized coal and preparation method of iron concentrate on indirect reduction reaction was discussed.Finally,the source and quantitative relationship of indirect reduction process were analyzed theoretically.The results show that indirect reduction mainly comes from the chemical reaction between iron oxide and CO produced by direct carbothermal reduction process.During the step reduction process,some volatiles of coal are involved in the reaction,leading to the proportion of CO2/(CO+CO2) in the stable gas more than 20%.In a certain range,the smaller size of iron ore concentrate powder achieve better the reduction effect.
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Key words:
- iron concentrate /
- carbothermic reduction /
- indirect reduction /
- iron oxide
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