Study on Dephosphorization of Coke Reduction Converter Slag by Gasification
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摘要: 为解决炉渣中磷含量过高而不能直接转炉内循环利用的问题,通过实验室进行了相关热态试验,系统研究了不同温度、碱度、FeO含量、氮气流量对气化脱磷率的影响规律。试验结果表明:气化脱磷率随着温度和氮气流量的增加而逐渐升高,当温度和氮气流量分别控制在1 923 K和0.45 m3/h时,气化脱磷率分别可达76.26%和64.57%;气化脱磷率随着碱度的降低而逐渐增加,当碱度控制为1.8时气化脱磷率可以达70.35%;FeO含量在16%~32%范围变化时,气化脱磷率随着FeO含量的增加先升高后降低,FeO含量为24%时气化脱磷率最高可以达到66.75%。为实现气化脱磷率在60%以上,应控制分别控制温度、碱度、FeO含量以及氮气流量分别为1 873 K、1.8、24%和0.45 m3/h。Abstract: In order to solve the problem that phosphorus content in slag is too high to be recycled directly in converter,the influence of different temperature,alkalinity,FeO content and nitrogen flow rate on gasification dephosphorization rate was systematically studied by means of related hot state experiments in laboratory.The results show that the dephosphorization rate increases with the increase of temperature and nitrogen flow rate.When the temperature and nitrogen flow rate are controlled at 1 923 K and 0.45 m3/h,respectively,the dephosphorization rate can reach 76.26% and 64.57%.The gasification dephosphorization rate increases gradually with the decrease of alkalinity.When the alkalinity is controlled at 1.8,the gasification dephosphorization rate of 70.35% can be achieved.When the FeO content ranges from 16% to 32%,the dephosphorization rate increases first and then decreases with the increase of FeO content.When the FeO content is 24%,the dephosphorization rate is 66.75%.Therefore,in order to achieve the gasification dephosphorization rate more than 60%,the temperature should be controlled at about 1 873 K,alkalinity at 1.8,FeO content at 24%,and nitrogen flow rate at 0.45 m3/h.The experimental results provide theoretical and technical support for the development of slag recycling process.
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Key words:
- converter /
- slag /
- recycling /
- slag splashing /
- gasification dephosphorization
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