Discussion on Smelting Technology of a High Chromium Vanadium Titanium Magnetite
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摘要: 探讨一种将高铬型钒钛磁铁矿中多种有益金属进行分离、回收、提取的工艺。其主要工艺设备由熔炼炉、氯化炉和数个分离炉及其附属设备组成。矿粉、煤粉、溶剂等在熔炼炉内高温熔融还原,产生的的熔融含钛渣流入氯化炉进行高温氯化。生成的含四氯化钛炉气经净化,得到四氯化钛。熔炼炉内的铁水依次流过数个分离炉。每个分离炉炉底喷入不同的分离助剂或气体,与铁水中的某种有益金属发生反应生成密度较小熔渣,与铁水分层后被排出。由此进行下去,可以得到钒渣、铬渣、钴渣和镍渣等,从最后一个分离炉炉尾排出铁水。从熔炼炉、氯化炉、分离炉连续排出的炉渣、炉气、炉气烟尘中,采用现有工艺提取多种有益金属。介绍了设计思路,工艺流程,主要设备及其结构,主要技术特点,优、缺点,在技术、经济、环保等方面和现行相关工艺进行了对比,对工艺可行性进行了研讨。Abstract: This paper deals with a process for separation,recovery and extraction of various beneficial metals from high chromium vanadium-titanium magnetite.The main equipment of the process consists of a melting furnace,a chlorination furnace,several separation furnaces and their ancillary equipment.The mineral powder,coal powder,solvent powder and so on are reduced in the smelting furnace at high temperature.The resulting molten titanium-bearing slag flows into the chlorination furnace for high temperature chlorination.The resulting titanium tetrachloride gas is purified for production of titanium tetrachloride.The molten iron in the smelting furnace flows through several separate furnaces in turn.Each furnace bottom is sprayed with different separating agents or gases,which reacts with some beneficial metal in molten iron to form a less dense slag separated from the molten iron and discharged.The slag containing titanium slag,vanadium slag,chromium slag,cobalt slag and nickel slag can be obtained.The molten iron is discharged from the tail of the last separation furnace.A variety of beneficial metals are extracted from slag and flue dust discharged from smelting furnace,chlorination furnace and separation furnace by existing processes.This paper introduces the design idea,technological process,main equipment and its structure,main technical features,advantages and disadvantages,and compares the technology,economy and environmental protection with the current relevant technology,and discusses the feasibility of the technology.The main technical problems in the process are also discussed.
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Key words:
- high chromium vanadium titanomagnetite /
- smelting reduction /
- chlorination /
- separation /
- titanium tetrachloride /
- vanadium /
- chromium
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