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含钒酸浸液净化与富集的研究进展

朱思琴 叶国华 亢选雄 梁雪崟

朱思琴, 叶国华, 亢选雄, 梁雪崟. 含钒酸浸液净化与富集的研究进展[J]. 钢铁钒钛, 2022, 43(5): 10-22. doi: 10.7513/j.issn.1004-7638.2022.05.002
引用本文: 朱思琴, 叶国华, 亢选雄, 梁雪崟. 含钒酸浸液净化与富集的研究进展[J]. 钢铁钒钛, 2022, 43(5): 10-22. doi: 10.7513/j.issn.1004-7638.2022.05.002
Zhu Siqin, Ye Guohua, Kang Xuanxiong, Liang Xueyin. Research progress on purification and enrichment of vanadium-bearing acid leaching solution[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(5): 10-22. doi: 10.7513/j.issn.1004-7638.2022.05.002
Citation: Zhu Siqin, Ye Guohua, Kang Xuanxiong, Liang Xueyin. Research progress on purification and enrichment of vanadium-bearing acid leaching solution[J]. IRON STEEL VANADIUM TITANIUM, 2022, 43(5): 10-22. doi: 10.7513/j.issn.1004-7638.2022.05.002

含钒酸浸液净化与富集的研究进展

doi: 10.7513/j.issn.1004-7638.2022.05.002
基金项目: 国家自然科学基金资助项目(51964028)
详细信息
    作者简介:

    朱思琴,1999年出生,女,硕士研究生,研究方向:钒的提取,E-mail:zhusiqinf@163.com

    通讯作者:

    叶国华,男,博士,教授,长期从事钒资源物理分选与化学提取的研究工作,E-mail:ghye581@163.com

  • 中图分类号: TF841.3

Research progress on purification and enrichment of vanadium-bearing acid leaching solution

  • 摘要: 在分析含钒酸浸液性质特征的基础上,评述了含钒酸浸液净化与富集的研究进展情况。认为目前研究最多的是溶剂萃取法和离子交换法,其中酸性磷类萃取剂选择性差,中性含磷萃取剂一般是作为协萃剂或改性剂使用,碱性胺类萃取剂在操作过程中容易产生第三相,离子液体在萃取领域展示出良好的应用前景,但其规模化制备等问题尚有待解决;阴离子交换树脂在大部分pH条件下都适用,但强酸(pH<2)环境时还是螯合树脂较为适合;传统的化学沉淀法比较适合作为初步处理或者含钒酸浸液体系较为单一时使用;电吸附法虽萃取率较高,但尚且处于实验室研究阶段;溶剂浸渍树脂在实际使用时,树脂中的萃取剂很容易流失而难以大规模推广。最后提出了今后含钒酸浸液净化与富集的研究方向。
  • 图  1  V(V)、V(IV)在不同pH下的存在形式[8]

    Figure  1.  The existence forms of V(V) and V(IV) at different pH

    图  2  酸性磷类萃取剂结构示意

    注:结构示意图由Materials Studio绘制,其中粉色为P原子、红色为O原子、灰色为C原子、白色为H原子,下同

    Figure  2.  Structure of acid phosphorus extractants

    图  3  P204、P507、cyanex272协同萃取结合形式[25]

    Figure  3.  Combination forms of P204、P507 and cyanex272 by synergistic extraction

    图  4  TBP结构示意

    Figure  4.  TBP structure

    图  5  碱性胺类萃取剂结构示意

    注:结构示意图由Materials Studio绘制,其中灰色为C原子、白色为H原子,蓝色为N原子、绿色为Cl原子

    Figure  5.  Structures of alkaline amine extractants

  • [1] Chen Ziyang, Ye Guohua, Zuo Qi, et al. Structure-activity relationship of organic amine extractants and their solvent extraction of vanadium[J]. Iron Steel Vanadium Titanium, 2020,41(3):8−15. (陈子杨, 叶国华, 左琪, 等. 有机胺类萃取剂构效关系及其萃钒的研究进展[J]. 钢铁钒钛, 2020,41(3):8−15. doi: 10.7513/j.issn.1004-7638.2020.03.001
    [2] Ye Guohua, Zhu Siqin, Chen Ziyang, et al. Review on beneficiation preconcentration of stone coal vanadium ore[J]. Chinese Journal of Rare Metals, 2022,46(1):120−130. (叶国华, 朱思琴, 陈子杨, 等. 石煤钒矿的选矿预富集研究评述[J]. 稀有金属, 2022,46(1):120−130. doi: 10.13373/j.cnki.cjrm.XY20090026
    [3] Lai Yongchuan, Yang Xinglong, Sun Jianzhi, et al. Research status of selective extraction of vanadium from acid leaching solution of vanadium-bearing shale[J]. Chinese Journal of Rare Metals, 2022,46(1):109−119. (赖永传, 杨鑫龙, 孙建之, 等. 含钒页岩酸浸液中钒的选择性萃取研究现状[J]. 稀有金属, 2022,46(1):109−119. doi: 10.13373/j.cnki.cjrm.XY21050003
    [4] Chen Ziyang, Ye Guohua, Xiang Pengzi, et al. Effect of activator on kinetics of direct acid leaching of vanadium from clay vanadium ore[J]. Separation and Purification Technology, 2022,281:119937. doi: 10.1016/j.seppur.2021.119937
    [5] Zhang Hao, Ye Guohua, Chen Ziyang, et al. Complexation and activation of fluoride ion and its acceleration for dissolution of cations on the surface of vanadium-containing biotite (002)[J]. Applied Surface Science, 2022,586:152767. doi: 10.1016/j.apsusc.2022.152767
    [6] Hu Yibo, Ye Guohua, Wang Heng, et al. Market analysis of vanadium and progress on technologies of vanadium extraction from stone coal[J]. Iron Steel Vanadium Titanium, 2019,40(2):31−40. (胡艺博, 叶国华, 王恒, 等. 钒市场分析与石煤提钒工艺进展[J]. 钢铁钒钛, 2019,40(2):31−40. doi: 10.7513/j.issn.1004-7638.2019.02.006
    [7] Ye Guohua, Xie Yu, Hu Yibo, et al. Study on vanadium extraction by low-temperature sulfation roasting-water leaching of low-grade rock coal vanadium ore[J]. Chinese Journal of Rare Metals, 2020,44(7):753−761. (叶国华, 谢禹, 胡艺博, 等. 低品位石煤钒矿低温硫酸化焙烧-水浸提钒研究[J]. 稀有金属, 2020,44(7):753−761. doi: 10.13373/j.cnki.cjrm.xy19020024
    [8] Zhang Yimin, Bao Shenxu. Current research state and prospect of purification and enrichment of vanadium from aqueous solutions[J]. Metal Mine, 2016,(7):64−70. (张一敏, 包申旭. 含钒浸出液净化富集技术现状及前景[J]. 金属矿山, 2016,(7):64−70. doi: 10.3969/j.issn.1001-1250.2016.07.010
    [9] Li Wang, Zhang Yimin, Liu Tao, et al. Comparison of ionexchange and solvent extraction in recovering vanadium from sulfuric acid leach solutions of stone coal[J]. Hydrometallurgy, 2013,131-132:1−7. doi: 10.1016/j.hydromet.2012.09.009
    [10] Zhang Yimin, Zhu Xiaobo, Liu Tao, et al. Effect of colloidal potassium alum formation on vanadium recovery from acid leach solutions of stone coal[J]. Hydrometallurgy, 2013,138:54−58. doi: 10.1016/j.hydromet.2013.06.014
    [11] Tian Maoming, Tang Dajun, Zhang Qi, et al. Vanadium extraction process from vanadium-containing steel slag and its main technology[J]. Journal of Chongqing Institute of Science and Technology (Natural Science Edition), 2009,11(2):59−60,75. (田茂明, 唐大均, 张奇, 等. 含钒钢渣提钒工艺及其主要技术[J]. 重庆科技学院学报(自然科学版), 2009,11(2):59−60,75. doi: 10.19406/j.cnki.cqkjxyxbzkb.2009.02.019
    [12] Ye Guohua, Tang Yue, Zuo Qi, et al. Study on the extraction of vanadium and iron from the direct acid leaching solution of vanadium-containing steel slag by tertiary amine TOA[J]. Conservation and Utilization of Mineral Resources, 2021,41(3):17−24. (叶国华, 唐悦, 左琪, 等. 叔胺TOA从含钒钢渣直接酸浸液中萃钒除铁的研究[J]. 矿产保护与利用, 2021,41(3):17−24. doi: 10.13779/j.cnki.issn1001-0076.2021.03.003
    [13] Ye Guohua, Hu Yibo, Tong Xiong, et al. Extraction of vanadium from direct acid leaching solution of clay vanadium ore using solvent extraction with N235[J]. Hydrometallurgy,2018, 177:27−33.
    [14] Yu Bin, Sun Zhaohui, Xian Yong, et al. Study on extraction separation of non-roasting acid leachate of vanadium slag[J]. Iron Steel Vanadium Titanium, 2014,35(5):1−6. (余彬, 孙朝晖, 鲜勇, 等. 钒渣无焙烧酸浸液萃取分离试验研究[J]. 钢铁钒钛, 2014,35(5):1−6. doi: 10.7513/j.issn.1004-7638.2014.05.001
    [15] Cao Wei, Zhang Yimin, Bao Shenxu, et al. Vanadium selective extraction with N235 from acid leaching solution of stone coal[J]. Non-ferrous Metals (Smelting Part), 2015,(4):34−37. (曹威, 张一敏, 包申旭, 等. N235从石煤提钒酸浸液中直接萃取钒[J]. 有色金属(冶炼部分), 2015,(4):34−37.
    [16] Zhang Guozhi, Chen Desheng, Zhao Wei, et al. A novel synergistic extraction method for recovering vanadium(V) from high-acidity chloride leaching liquor[J]. Separation and Purification Technology, 2016,165:166−172. doi: 10.1016/j.seppur.2016.04.008
    [17] Hu Yibo, Ye Guohua, Zuo Qi, et al. Research progress and prospects of vanadium extraction from acid leach solution of stone coal vanadium ore[J]. Multipurpose Utilization of Mineral Resources, 2020,(1):10−15. (胡艺博, 叶国华, 左琪, 等. 石煤钒矿酸浸液中萃取提钒的研究进展与前景[J]. 矿产综合利用, 2020,(1):10−15. doi: 10.3969/j.issn.1000-6532.2020.01.002
    [18] Wang Hongjun, Feng Yali, Li Hailong, et al. Recovery of vanadium from acid leaching solutions of spent oil hydrotreating catalyst using solvent extraction with D2EHPA (P204)[J]. Hydrometallurgy, 2020,195:304−386.
    [19] Hu Guoping, Chen Desheng, Wang Lina, et al. Extraction of vanadium from chloride solution with high concentration of iron by solvent extraction using D2EHPA[J]. Separation and Purification Technology, 2014,125:59−65. doi: 10.1016/j.seppur.2014.01.031
    [20] Cheng Qian, Wang Ming, Ning Xinxia, et al. Experimental study on vanadium extraction by acid leaching-extraction-ammonia precipitation from a low-grade carbonaceous vanadium ore[J]. Multipurpose Utilization of Mineral Resources, 2021,(3):17−21. (程倩, 王明, 宁新霞, 等. 从某低品位炭质钒矿石中酸浸-萃取-氨沉淀提钒实验研究[J]. 矿产综合利用, 2021,(3):17−21.
    [21] Mehdi Noori, Fereshteh Rashchi, Ataollah Babakhani, et al. Selective recovery and separation of nickel and vanadium in sulfate media using mixtures of D2EHPA and Cyanex 272[J]. Separation and Purication Technology, 2014,136:265−273. doi: 10.1016/j.seppur.2014.08.038
    [22] Li Cunxiong, Chang Wei, Deng Zhigan, et al. Recovery of vanadium from black shale[J]. Transactions of Nonferrous Metals Society of China, 2010,20(s):127−131.
    [23] Guo Shuanghua, Hong Yin, Jiang Ye, et al. Solvent extraction of vanadium from leaching solution containing vanadium[J]. Hydrometallurgy of China, 2020,39(4):309−312. (郭双华, 洪颖, 姜晔, 等. 用P204从某含钒浸出液中萃取钒试验研究[J]. 湿法冶金, 2020,39(4):309−312. doi: 10.13355/j.cnki.sfyj.2020.04.008
    [24] Zhang Ying, Zhang Ting, an, Lv Guozhi, et al. Synergistic extraction of vanadium(IV) in sulfuric acid media using a mixture of D2EHPA and EHEHPA[J]. Hydrometallurgy, 2016,166:87−93. doi: 10.1016/j.hydromet.2016.09.003
    [25] Zhang Hao, Ye Guohua, Chen Ziyang, et al. Research progress on synergistic extraction of typical organophosphorus extractant in solvent extraction[J]. The Chinese Journal of Process Engineering, 2021,21(7):741−751. (张豪, 叶国华, 陈子杨, 等. 典型有机磷类萃取剂在溶剂萃取中协同萃取的研究进展[J]. 过程工程学报, 2021,21(7):741−751. doi: 10.12034/j.issn.1009-606X.220179
    [26] Tu Shenghui, Zhang Zhiwen, Zhang Chao, et al. Application of hydrophobic ionic liquid-neutral organophosphorus extractant in extraction of rare earth elements[J]. Chemical Industry and Engineering, 2020,37(5):22−30. (涂盛辉, 张志文, 张超, 等. 疏水性离子液体-中性磷氧萃取剂萃取稀土元素的应用[J]. 化学工业与工程, 2020,37(5):22−30. doi: 10.13353/j.issn.1004.9533.20196001
    [27] Sun Qi, Yang Limei, Huang Songtao, et al. Research and prospect on synergistic solvent extraction mechanism[J]. Chinese Journal of Rare Metals, 2016,40(11):1177−1187. (孙启, 杨丽梅, 黄松涛, 等. 协同萃取机制的研究现状及展望[J]. 稀有金属, 2016,40(11):1177−1187. doi: 10.13373/j.cnki.cjrm.xy15041301
    [28] Qiu Yinxuan, Yang Limei, Huang Songtao, et al. Progress in separation and recycle of heavy metals from wastewater by synergistic solvent extraction method[J]. Chinese Journal of Rare Metal, 2015,39(8):749−758. (邱胤轩, 杨丽梅, 黄松涛, 等. 协同萃取法分离和回收废水中重金属离子的研究现状[J]. 稀有金属, 2015,39(8):749−758. doi: 10.13373/j.cnki.cjrm.2015.08.012
    [29] Li Xingbin, Wei Chang, Deng Zhigan, et al. Selective solvent extraction of vanadium over iron fro-m a stone coal/black shale acid leach solution by D2 EHPA/TBP[J]. Hydrometallurgy, 2011,105:359−363. doi: 10.1016/j.hydromet.2010.10.006
    [30] Benyamin Shakib, RezvanTorkaman, MeisamTorab-Mostaedi, et al. Enhancing the vanadium extraction performance using synergistic mixtures of D2EHPA and TBP in RDC column with the perforated structure[J]. Chemical Engineering and Processing Process Intensification, 2021,166:255−271.
    [31] Chen Chun, Zhang Yimin, Bao Shenxu, et al. Separation and enrichment of vanadium from stone coal acidic leach solution using tertiary amine N235[J]. Chinese Journal of Rare Metal, 2017,41(4):422−428. (谌纯, 张一敏, 包申旭, 等. 叔胺N235从石煤酸浸液中分离富集钒[J]. 稀有金属, 2017,41(4):422−428. doi: 10.13373/j.cnki.cjrm.xy15110303
    [32] Liu Zishuai, Huang Jing, Zhang Yimin, et al. Separation and recovery of vanadium and aluminum from oxalic acid leachate of shale by solvent extraction with Aliquat 336[J]. Separation and Purification Technology, 2020,249:116867. doi: 10.1016/j.seppur.2020.116867
    [33] Xie Qiying, Chen Jing, Yang Xiangjun, et al. Mechanism of third-phase elimination by TBP in N235 /HCl solvent extraction system[J]. Chinese Journal of Inorganic Chemistry, 2007,(1):57−62. (谢琦莹, 陈景, 杨项军, 等. N235萃取HCl体系中TBP消除第三相的作用机理[J]. 无机化学学报, 2007,(1):57−62. doi: 10.3321/j.issn:1001-4861.2007.01.009
    [34] Wang Liupei, Zhang Guiqing, Guan Wenjuan, et al. Complete removal of trace vanadium from ammonium tungstate solutions by solvent extraction[J]. Hydrometallurgy, 2018,179:268−273. doi: 10.1016/j.hydromet.2018.06.016
    [35] Thanh Tuan Tran, Man Seung Lee. Separation of Mo(VI), V(V), Ni(II), Al(III) from synthetic hydrochloric acidic leaching solution of spent catalysts by solvent extraction with ionic liquid[J]. Separation and Purification Technology, 2020,247:117005. doi: 10.1016/j.seppur.2020.117005
    [36] Yang Xiao, Zhang Yimin, Bao Shenxu, et al. Separation and recovery of vanadiumfrom a sulfuric-acid leaching solution of stone coal by solvent extraction using trialky lamine[J]. Separation and Purification Technology, 2016,164:1399−1405.
    [37] Ye Guohua, Hu Yibo, Tong Xiong, et al. Extraction of vanadium from direct acidleaching solution of clay vanadium ore using solvent extraction with N235[J]. Hydrometallurgy, 2018,177:27−33. doi: 10.1016/j.hydromet.2018.02.004
    [38] Ludmilla Kurbatova, Olga Koryakova, Marina Valova, et al. Examination of extraction of vanadium(Ⅴ) by trioctylamine from sulfuric solutions[J]. Zeitschrift für Anorganische und Allgemeine Chemie, 2015,641(3):617−621.
    [39] Xiao Chao, Xiao Liansheng, Cheng Baohai, et al. New process of vanadium extraction from alkali leach liquor of carbonaceous shale containing vanadium[J]. Rare Metals and Cemented Carbides, 2011,39(1):4−7. (肖超, 肖连生, 成宝海, 等. 石煤钒矿碱性浸出液提取钒新工艺[J]. 稀有金属与硬质合金, 2011,39(1):4−7. doi: 10.3969/j.issn.1004-0536.2011.01.002
    [40] Liu Yanhua, Yang Chao. Direct precipitation of vanadium from vanadium-containing leachate by solvent extraction[J]. Wet Metallurgy, 2010,29(4):263−266. (刘彦华, 杨超. 用溶剂萃取法从含钒浸出液中直接沉淀钒[J]. 湿法冶金, 2010,29(4):263−266. doi: 10.3969/j.issn.1009-2617.2010.04.014
    [41] Zhang Ying, Zhang Ting, an. Extraction of vanadium from the leaching solution from converter vanadium slag without roasting using N1923[J]. Nonferrous Metals Science and Engineering, 2015,6(6):14−19. (张莹, 张廷安. N1923萃取钒渣无焙烧浸出液中钒的实验探究[J]. 有色金属科学与工程, 2015,6(6):14−19. doi: 10.13264/j.cnki.ysjskx.2015.06.003
    [42] Zhao Junmei, Hu Qiaoyu, Li Yingbo, et al. Efficient separation of vanadium from chromium by a novel ionic liquid-based synergistic extraction strategy[J]. Chemical Engineering Journal, 2015,264:487−492. doi: 10.1016/j.cej.2014.11.071
    [43] Tang Yue, Ye Guohua, Hu Yujie. Application status and development trend of ionic liquids in extraction and separation[J]. Mining and Metallurgy, 2021,30(6):54−62. (唐悦, 叶国华, 胡渝杰, 等. 离子液体在萃取分离中的应用现状与发展趋势[J]. 矿冶, 2021,30(6):54−62. doi: 10.3969/j.issn.1005-7854.2021.06.009
    [44] Zhang Yun, Fan Biwei, Lin Hailin, et al. Process of vanadium adsorption from lithic coal acid leach solution by D290 resin[J]. Mineral Petrol, 2000,(4):95−98. (张云, 范必威, 林海玲, 等. D290树脂从石煤酸浸液中吸附钒的工艺[J]. 矿物岩石, 2000,(4):95−98. doi: 10.3969/j.issn.1001-6872.2000.04.018
    [45] Liu Yanhua, Yang Chao. Experimental study on the recovery of vanadium from vanadium-containing extractives using D301 resin[J]. Hydrometallurgy of China, 2010,29(2):96−98. (刘彦华, 杨超. 用D301树脂从含钒萃余液中回收钒的试验研究[J]. 湿法冶金, 2010,29(2):96−98. doi: 10.3969/j.issn.1009-2617.2010.02.008
    [46] Zhu Xiaobo, Wang Li, Tang Sen, et al. Selective recovery of vanadium and scandium by ion exchange with D201 and solvent extraction using P507 from hydrochloric acid leaching solution of red mud[J]. Chemosphere, 2017,175:365−372. doi: 10.1016/j.chemosphere.2017.02.083
    [47] Xu Qiaochu, Cheng Baohai, Yang Lina, et al. Extraction of vanadium from leachate containing vanadium from stone coal by D301R ion exchange resin[J]. Journal of Changchun Normal University, 2021,40(2):195−200. (徐乔楚, 成宝海, 杨丽娜, 等. 用D301R离子交换树脂从石煤含钒浸出液中提钒研究[J]. 长春师范大学学报, 2021,40(2):195−200.
    [48] 张克仑. 含钒铅锌矿湿法提钒技术研究[D]. 昆明: 昆明理工大学, 2021.

    Zhang Kelun. Research on wet vanadium extraction technology for vanadium-bearing lead-zinc ore[D]. Kunming: Kunming University of Science and Technology, 2021.
    [49] Gao Guanjin, Peng Yi, Cao Hongbin. Research on vanadium extraction from vanadium-chromium solution by ion-exchange[J]. Iron Steel Vanadium Titanium, 2015,36(5):1−5. (高官金, 彭毅, 曹宏斌. 钒铬溶液离子交换法提钒研究[J]. 钢铁钒钛, 2015,36(5):1−5. doi: 10.7513/j.issn.1004-7638.2015.05.001
    [50] Zeng Li, Li Qinggang, Xiao Lianshen, et al. A study of the vanadium species in an acid leach solution of stone coal using ion exchange resin[J]. Hydrometallurgy, 2010,105(1):176−178.
    [51] Zeng Xiaoming, Huang Huimin, Si Shihui. Study of the adsorption behavior of C-900 amino phosphonic acid resin for vanadium(Ⅳ)[J]. Rare Metals and Cemented Carbides, 2012,40(2):6−9. (曾小明, 黄慧敏, 司士辉. C-900氨基膦酸树脂对钒(Ⅳ)离子的吸附行为研究[J]. 稀有金属与硬质合金, 2012,40(2):6−9. doi: 10.3969/j.issn.1004-0536.2012.02.002
    [52] Vinco J H, Botelho A B J, Duarte H A, et al. Purification of an iron contaminated vanadium solution through ion exchange resins[J]. Minerals Engineering, 2022,176:107337. doi: 10.1016/j.mineng.2021.107337
    [53] 杨小慧, 李望, 朱晓波. D751螯合树脂吸附酸性溶液中钒(IV)离子的机制[J/OL][J]. 中国有色金属学报, 2021, 1-14. http://ysxb.csu.edu.cn/paper/onlinepaperview.aspx?id=paper_777910. DOI: 10.11817/j.ysxb.1004.0609.2021-42589

    Yang Xiaohui, Li Wang, Zhu Xiaobo. Mechanism of vanadium(IV) ion adsorption in acidic solutions by D751 chelating resin[J/OL]. The Chinese Journal of Nonferrous Metals, 2021, 1-14. http://ysxb.csu.edu.cn/paper/onlinepaperview.aspx?id=paper_777910. DOI: 10.11817/j.ysxb.1004.0609.2021-42589
    [54] Ye Puhong, Wang Xuewen, Wang Mingyu, et al. Recovery of vanadium from stone coal acid leaching solution by coprecipitation, alkaline roasting and water leaching[J]. Hydrometallurgy, 2012,117-118:106−115.
    [55] Wang Haixu, Li Lanjie, Xu Congmei, et al. Study on the deep debinding process of salt-free roasted leachate[J]. Chemical Management, 2018,(19):198−202. (王海旭, 李兰杰, 徐从美, 等. 无盐焙烧浸出液深度除杂工艺研究[J]. 化工管理, 2018,(19):198−202. doi: 10.3969/j.issn.1008-4800.2018.19.132
    [56] Porada S, Zhao R, Wal A Vander, et al. Review on the science and technology of water desalination by capacitive deionization[J]. Progress in Materials Science, 2013,58:1388−1442. doi: 10.1016/j.pmatsci.2013.03.005
    [57] Abbas Afkhami, Brian E Conway. Investigation of removal of Cr(VI), Mo(VI), W(VI), V(IV), and V(V) oxy-ions from industrial waste-waters by adsorption and electrosorption at high-area carbon cloth[J]. Journal of Colloid and Interface Science, 2002,251:248−255. doi: 10.1006/jcis.2001.8157
    [58] Wang Junlian, Sun Chunbao, Xu Shengming. Preparation and application of extractive shower resin based on rare earth separation[J]. Journal of the Chinese Society of Rare Earths, 2015,33(2):129−145. (王俊莲, 孙春宝, 徐盛明. 基于稀土分离的萃淋树脂制备与应用研究[J]. 中国稀土学报, 2015,33(2):129−145. doi: 10.1016/S1002-0721(14)60392-6
    [59] Helaly O S, Abdel-Ghany M S, Moustafa M I, et al. Extraction of cerium(IV) using tributyl phosphate impregnated resin from nitric acid medium[J]. Transactions of the Nonferrous Metals Society of China, 2012,22(1):206−214. doi: 10.1016/S1003-6326(11)61162-X
    [60] Liang Liang, Bao Shenxu, Zhang Yimin, et al. Separation and recovery of V(IV) from sulfuric acid solutions containing Fe(III) and Al(III) using bis(2-ethylhexyl) phosphoric acid impregnated resin[J]. Chemical Engineering Research & Design, 2016,111:109−116.
    [61] Tang Yongping, Bao Shenxu, Zhang Yimin, et al. Effect of support properties on preparation process and adsorption performances of solvent impregnated resins[J]. Reactive & Functional Polymers, 2017,113:50−57.
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出版历程
  • 收稿日期:  2022-06-09
  • 网络出版日期:  2022-11-01
  • 刊出日期:  2022-11-01

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