Research progress on preparation methods and hot forming of TiAl alloy ingots
-
摘要: TiAl合金密度低且在600~900 ℃范围内具有较高的比强度,已在航空发动机低压涡轮叶片等部件实现应用。但受室温塑性不足、热加工窗口窄及凝固偏析与缺陷敏感等因素影响,大尺寸铸锭的稳定制备仍是工程化推广的关键瓶颈。文章综述了TiAl合金体系的成分设计演进,并对VAR、ISM、VIM与PAM等典型铸锭制备工艺的特点、优势与局限进行了对比,重点讨论大尺寸条件下的成分均匀性、夹杂与缺陷控制问题,以及混合熔炼路线在质量稳定性提升方面的作用。同时总结了锻造、挤压与轧制等后续热加工在致密化、组织细化与性能提升中的关键意义,为大尺寸TiAl铸锭的工艺优化与规模化制造提供参考。Abstract: TiAl alloys feature low density and high specific strength in the 600-900 ℃ temperature range and have been implemented in aero-engine components such as low pressure turbine blades. However, restricted by factors such as lacked room temperature ductility, a narrow hot working window, and strong sensitivity to solidification segregation and defects, the stable production of large scale ingots remains a key bottleneck for wider engineering application. This paper reviews the evolution of composition design in TiAl alloy systems and compares the characteristics, advantages, and limitations of typical ingot preparation routes including vacuum arc remelting, induction skull melting, vacuum induction melting, and plasma arc melting. Emphasis is placed on composition uniformity, inclusion and defect control at large ingot sizes, as well as the role of hybrid melting routes in improving quality stability. In addition, the critical roles of subsequent thermomechanical processing such as forging, extrusion, and rolling in densification, microstructure refinement, and property enhancement are summarized, providing references for process optimization and scalable manufacturing of large TiAl ingots.
-
Key words:
- TiAl alloy /
- ingot preparation /
- hot working
-
表 1 TiAl合金现有铸锭制备方法总结
Table 1. Summary of existing ingot preparation methods for TiAl alloy
Alloy system Melting
processIngot
specification/mmTi-43Al-9V-0.3Y[24] VAR Ø160 Ti-46Al-4Nb-1.8Cr-0.2Ta[18] VAR Ø220 Ti-47Al-2V-0.2Y[23] VAR Ø90 Ti-47Al-2Nb-2Cr[29] VAR+ISM Ø280 Ti-44Al-8Nb-0.2W-0.2B-0.5Y[26] VAR Ø220 Ti-43.5Al-4Nb-1Mo-0.1B[18] VAR+ISM Ø280 Ti-48Al-2Cr-2Nb-0.05Y2O3[31] ISM Ø90 Ti-43Al-9V-0.3Y[32] ISM Ø110 Ti-45Al-2W-xC[33] VIM Ø20 Ti-46Al-8Nb[16] VIM Ø85 表 2 TiAl合金板材的加工路径及板材尺寸
Table 2. Processing routes and dimensions of TiAl alloy sheets
Alloying component Preparation technology Sheet size/mm TiAl alloy[3] Sintering metallurgy + Rolling 1800 ×500×1Ti-44Al-8Nb-0.2W-0.2B-Y[67] Sintered metal casting + near-isothermal encapsulation rolling 410×70×2.1 Ti-43Al-9V-0.2Y[66] Sintered metal casting + near-isothermal encapsulation rolling 875×70×(2~3) Ti-45Al-8.5Nb-0.2W-0.2B-0.2Y[68] Soft cover with hot-rolled material 300×80×3 Ti-44Al-5Nb-1Mo-2V-0.2B[69] Soft cover with hot-rolled material 330×115×3 -
[1] 陈玉勇, 吴敬玺. β相凝固TiAl合金的制备、加工、组织、性能及工业应用研究进展[J]. 钢铁钒钛, 2021, 42(6): 1-16. Chen Yuyong, Wu Jingxi. Research progress on preparation, processing, microstructure, properties and industrial application of β-solidifying TiAl alloys[J]. Iron Steel Vanadium Titanium, 2021, 42(6): 1-16.Chen Yuyong, Wu Jingxi. Research progress on preparation, processing, microstructure, properties and industrial application of β-solidifying TiAl alloys[J]. Iron Steel Vanadium Titanium, 2021, 42(6): 1-16. [2] Appel H F, Paul J D H, Oehring M. Gamma titanium aluminide alloys: science and technology[M]. Weinheim: Wiley-VCH, 2011. [3] Clemens H, Kestler H. Processing and applications of intermetallic γ‐TiAl‐based alloys[J]. Adv. Eng. Mater., 2000, 2: 551. doi: 10.1002/1527-2648(200009)2:9<551::AID-ADEM551>3.0.CO;2-U [4] Bewlay B P, Weimer M, Kelly T, et al. The science, technology, and implementation of TiAl alloys in commercial aircraft engines[J]. MRS Online Proceedings Library Archive, 2013, 1516: 49-58. doi: 10.1557/opl.2013.44 [5] Bartolotta P, Barrett J, Kelly T, et al. The use of cast Ti-48Al-2Cr-2Nb in jet engines[J]. JOM, 1997, 49(5): 48-50. doi: 10.1007/BF02914685 [6] Bystrzanowaki S, Bartels A, Clemens H, et al. Creep behaviour and high temperature microstructural stability of Ti-46Al-9Nb sheet material[J]. Intermetallics, 2005, 13(5-6): 515-524. doi: 10.1016/j.intermet.2004.09.001 [7] Xiao Shulong, Chen Yuyong, Li Minggang, et al. The improved properties and microstructure of β-solidify Ti-43Al-6Nb-1Mo-1Cr-0.6B alloy[J]. Scientific Reports, 2019, 9: 12393. doi: 10.1038/s41598-019-47530-9 [8] Zhang Yu, Chang Shuai, Chen Yuyong, et al. Low temperature superplasticity of β stabilizedTi-43Al-9V-Y alloy sheet with bimodal γ grain size distribution[J]. Journal of Materials Science & Technology, 2021, 95: 225-236. doi: 10.1016/j.jmst.2021.03.077 [9] Li Tianrui, Liu Guohui, Xu Ming, et al. Flow stress prediction and hot deformation mechanisms in Ti-44Al-5Nb (Mo, V, B) alloy[J]. Materials, 2018, 11(10): 2044. doi: 10.3390/ma11102044 [10] Dowson A L, Loretto M H, Gogfrey A. Plasma arc melting of gamma titanium aluminides[J]. Intermetallics, 1999, 7(1): 1-9. doi: 10.1016/S0966-9795(98)00003-X [11] Clemens H. Processing of γ-TiAl-based alloys[J]. Advanced Engineering Materials, 2001, 3(8): 551-570. [12] Lütjering G. Influence of melting techniques on titanium alloy quality[J]. Materials Science and Engineering A, 1998, 243(1-2): 32-45. [13] Loretto M H, Godfrey A. Microstructural development of titanium aluminides[M]. London: The Institute of Materials, 1994. [14] 刘欣欣. 真空自耗电弧熔炼制备钛合金技术的研究进展[J]. 工业加热, 2019, 48(3): 67-69. Liu Xinxin. Research progress on titanium alloy preparation by vacuum consumable arc melting[J]. Industrial Heating, 2019, 48(3): 67-69. doi: 10.3969/j.issn.1002-1639.2019.03.018Liu Xinxin. Research progress on titanium alloy preparation by vacuum consumable arc melting[J]. Industrial Heating, 2019, 48(3): 67-69. doi: 10.3969/j.issn.1002-1639.2019.03.018 [15] Zhu S X, Wang Q J, Liu J R, et al. Zr and Mo macrosegregation in Ti6246 titanium alloy industrial-scale ingot by vacuum arc remelting[EB/OL]. (2021-05-08)[2026-03-10]. https://www.alphaxiv.org/abs/2105.03555. [16] Duan Baohua, Mao Lu, Yang Yuchen, et al. Preparation of Ti-46Al-8Nb alloy ingots beyond laboratory scale based on BaZrO3 refractory crucible[J]. Metals, 2022, 12(3): 524. doi: 10.3390/met12030524 [17] Kothari K, Radhakrishnan R, Wereley N M. Advances in gamma titanium aluminides and their manufacturing techniques[J]. Progress in Aerospace Sciences, 2012, 55(11): 1-16. doi: 10.1016/j.paerosci.2012.04.001 [18] AMG GfE Advanced Alloys GmbH. TNM™ alloy product handbook: Ti-43.5Al-4Nb-1Mo-0.1B[R]. Nürnberg: AMG GfE Advanced Alloys GmbH, 2017. [19] Yang Guang, Li Ruobing, Park J, et al. Synergistic enhancement of strength and ductility in TiB whisker-reinforced high Nb-containing TiAl alloys via hot extrusion and subsequent heat treatment[J]. Materials Science and Engineering: A, 2025, 945: 149008. doi: 10.1016/j.msea.2025.149008 [20] Güther V, Chatterjee A, Kettner H. Processing of gamma titanium aluminides[C]//KIM Y W, CLEMENS H, ROSENBERGER A H, eds. Gamma Titanium Aluminides 2003. Warrendale, PA: TMS, 2003: 241. [21] Güther V, Joos R, Clemens H. Plasma arc melting of γ-TiAl alloys[C]//HEMKER K J, DIMIDUK D M, CLEMENS H, et al, eds. Structural Intermetallics 2001. Warrendale, PA: TMS, 2001: 167. [22] 郭杰, 黄立清, 吴静阳, 等. 钛合金三次真空自耗电弧熔炼过程中的宏观偏析传递行为[J]. 金属学报, 2024, 60(11): 1531-1544. Guo Jie, Huang Liqing, Wu Jingyang, et al. Evolution of macrosegregation during three-stage vacuum arc remelting of titanium alloys[J]. Acta Metallurgica Sinica, 2024, 60(11): 1531-1544. doi: 10.11900/0412.1961.2022.00544Guo Jie, Huang Liqing, Wu Jingyang, et al. Evolution of macrosegregation during three-stage vacuum arc remelting of titanium alloys[J]. Acta Metallurgica Sinica, 2024, 60(11): 1531-1544. doi: 10.11900/0412.1961.2022.00544 [23] Nath P, Bar H N, Bhattacharjee, et al. Designing of novel microstructure and its impact on the improved service-temperature mechanical performance of 2nd and 3rd generation advanced intermetallic TiAl alloys[J]. Materials Science and Engineering A, 2024, 893: 146108. doi: 10.1016/j.msea.2024.146108 [24] Kong Fantao, Xu Xingchen, Chen Yuyong, et al. Microstructure and mechanical properties of large-size as-cast Ti-43Al-9V-0.3Y alloy ingot from brim to centre[J]. Materials & Design, 2012, 33: 485-490. doi: 10.1016/j.matdes.2011.04.053 [25] Martin P L, Hardwick D A, Clemens D R, et al. Large-scale processing of titanium aluminides[C]//Nathal M V, Darolia R, Liu C T, et al. Structural Intermetallics 1997. Warrendale, PA: TMS, 1997: 387. [26] Wang Xiaopeng, Kong Fantao, Cao Xiaoping, et al. Effect of heat treatment and thermomechanical processing on microstructure and tensile property of Ti 44Al-8Nb-0.2W-0.2B-0.5Y alloy[J]. China Foundry, 2020, 17(6): 447-454. doi: 10.1007/s41230-020-0097-0 [27] Xiang Lin, Tang Bin, Xue Xiangyi, et al. Characteristics of the dynamic recrystallization behavior of Ti-45Al-8.5Nb-0.2W-0.2B-0.3Y alloy during high temperature deformation[J]. Metals, 2017, 7(7): 261. doi: 10.3390/met7070261 [28] Burtscher M, Klein T, Lindemann J, et al. An advanced TiAl alloy for high performance racing applications[J]. Materials, 2020, 13(21): 4720. doi: 10.3390/ma13214720 [29] Ding Xianfei, Zhao Yiqun, Zuo Jiabin, et al. Chemical composition analysis on industrial scale ingots and castings of TiAl alloys[J]. China Foundry, 2020, 17: 441-446. doi: 10.1007/s41230-020-0091-6 [30] Lochbichler C, Friedrich B, Jarczyk G, et al. Cost reduction of TiAl by alternative production and integration of TiAl scrap recycling—concepts and vacuum-metallurgical equipment[J]. Advances in Materials Sciences, 2008, 8(1): 72-79. doi: 10.2478/v10077-008-0009-2 [31] Guo Yue, Xiao Shulong, Chen Yuyong, et al. High temperature tensile properties and fracture behavior of Y2O3-bearing Ti-48Al-2Cr-2Nb alloy[J]. Intermetallics, 2020, 126: 106933. doi: 10.1016/j.intermet.2020.106933 [32] Li B H, Chen Y Y, Hou Z Q, et al. Microstructure and mechanical properties of as-cast Ti-43Al-9V-0.3Y alloy[J]. Journal of Alloys and Compounds, 2009, 473(1-2): 123-126. doi: 10.1016/j.jallcom.2008.05.104 [33] Čegan T, Kamyshnykova K, Lapin J, et al. Processing and microstructure of as-cast Ti-45Al-2W-xC alloys[J]. Materials, 2022, 15(14): 5049. doi: 10.3390/ma15145049 [34] 刘彬. TiAl基合金的制备及高温变形行为研究[D]. 长沙: 中南大学, 2008. Liu Bin. Preparation and high-temperature deformation behavior of TiAl-based alloys[D]. Changsha: Central South University, 2008.Liu Bin. Preparation and high-temperature deformation behavior of TiAl-based alloys[D]. Changsha: Central South University, 2008. [35] Shagñay S, Cornide J, Ruiz-Navas E M. Sliding wear behavior of intermetallic Ti-45Al-2Nb-2Mn-0.8 vol% TiB2 processed by centrifugal casting and hot isostatic pressing[J]. Materials, 2022, 15(22): 8052. doi: 10.3390/ma15228052 [36] Matsuwaka D, Nishimura T, Kudo F, et al. Melting and casting technologies for titanium aluminide intermetallics[J]. Kobe Steel Technology Review, 2021, 39: 65-69. [37] 刘翔鹏. 氧化钇材料与钛合金的界面反应[D]. 沈阳: 东北大学, 2009. Liu Xiangpeng. Interfacial reactions between yttria materials and titanium alloys[D]. Shenyang: Northeastern University, 2009.Liu Xiangpeng. Interfacial reactions between yttria materials and titanium alloys[D]. Shenyang: Northeastern University, 2009. [38] Li Shu, Zhao Zhankui, Zhang Tao, et al. Integrated simulation method and experimental validation for the vacuum induction melting process[J]. Journal of Materials Researchand Technology, 2024, 33: 1764-1775. doi: 10.1016/j.jmrt.2024.09.183 [39] Dowson A L, Godfrey A, Loretto M H. Production of large γ-TiAl ingots by plasma arc melting[C]// Proceedings of the International Symposium on Gamma Titanium Aluminides. Warrendale, PA: TMS, 1999: 215–224. [40] Clemens H, Kestens L, Mayer S. Design, processing, microstructure, and properties of advanced intermetallic TiAl alloys[J]. Advanced Engineering Materials, 2016, 18(4): 551-570. doi: 10.1002/adem.201200231 [41] Appenzeller J, Schwaiger R, Clemens H. Industrial processing of TiAl alloys—Status and perspectives[J]. Materials Science and Engineering A, 2017, 708: 184-191. [42] Güther V, Allen M, Klose J, et al. Metallurgical processing of titanium aluminides on industrial scale[J]. Intermetallics, 2018, 103: 12-22. [43] Mayers S, Erdely P, Fischer F D, et al. Intermetallic β-solidifying γ-TiAl based alloys—From fundamental research to application[J]. Advanced Engineering Materials, 2017, 19(4): 1600735. [44] Lütjering G, Williams J C. Titanium[M]. 2nd ed. Berlin: Springer, 2007. [45] Blackburn M J, Malley R J. Plasma arc melting of titanium alloys[J]. Metallurgical Transactions B, 1981, 12(2): 273-280. [46] Godfrey A, Loretto M H. Chemical homogeneity in plasma arc melted TiAl ingots[J]. Intermetallics, 1998, 6(7-8): 641-649. [47] Wu X, Huang Z, Lin J. Processing and microstructural control of TiAl alloys for aero-engine applications[J]. Progress in Materials Science, 2020, 113: 100675. doi: 10.1016/j.pmatsci.2020.100675 [48] 杨锐. TiAl金属间化合物的进展与挑战[J]. 金属学报, 2015, 51(2): 129-147. Yang Rui. Progress and challenges of TiAl intermetallic compounds[J]. Acta Metallurgica Sinica, 2015, 51(2): 129-147. doi: 10.11900/0412.1961.2014.00396Yang Rui. Progress and challenges of TiAl intermetallic compounds[J]. Acta Metallurgica Sinica, 2015, 51(2): 129-147. doi: 10.11900/0412.1961.2014.00396 [49] 孔凡涛, 崔宁, 陈玉勇, 等. Ti-43Al-9V-Y合金的高温变形行为研究[J]. 金属学报, 2013, 49(5): 513-518. Kong Fantao, Cui Ning, Chen Yuyong, et al. The hot deformation behavior of Ti-43Al-9V-Y alloy[J]. Acta Metallurgica Sinica, 2013, 49(5): 513-518.Kong Fantao, Cui Ning, Chen Yuyong, et al. The hot deformation behavior of Ti-43Al-9V-Y alloy[J]. Acta Metallurgica Sinica, 2013, 49(5): 513-518. [50] Yuan Yuan, Zhang Yu, Chen Yuyong, et al. Designing a hybrid microstructure of Ti-43Al-9V-0.3Y alloy via two-step forging[J]. Journal of Materials Science & Technology, 2024, 192: 251-264. doi: 10.1016/j.jmst.2023.12.049 [51] Su Yongjun, Kong Fantao, Chen Yuyong, et al. Microstructure and mechanical properties of large-size Ti-43Al-9V-0.2Y alloy pancake produced by pack-forging[J]. Intermetallics, 2013, 34: 29-34. doi: 10.1016/j.intermet.2012.11.004 [52] 谢华生, 刘时兵, 赵军, 等. TiAl合金精密成形技术发展现状及展望[J]. 精密成形工程, 2022, 14(1): 44-54. Xie Huasheng, Liu Shibing, Zhao Jun, et al. Development status and prospects of precision forming technology for TiAl alloys[J]. Journal of Netshape Forming Engineering, 2022, 14(1): 44-54. doi: 10.3969/j.issn.1674-6457.2022.01.006Xie Huasheng, Liu Shibing, Zhao Jun, et al. Development status and prospects of precision forming technology for TiAl alloys[J]. Journal of Netshape Forming Engineering, 2022, 14(1): 44-54. doi: 10.3969/j.issn.1674-6457.2022.01.006 [53] 陈玉勇, 叶园, 孙剑飞. TiAl合金板材轧制研究现状[J]. 金属学报, 2022, 58(8): 965-978. Chen Yuyong, Ye Yuan, Sun Jianfei. Research status of rolling of TiAl alloy sheets[J]. Acta Metallurgica Sinica, 2022, 58(8): 965-978. doi: 10.11900/0412.1961.2021.00438Chen Yuyong, Ye Yuan, Sun Jianfei. Research status of rolling of TiAl alloy sheets[J]. Acta Metallurgica Sinica, 2022, 58(8): 965-978. doi: 10.11900/0412.1961.2021.00438 [54] Seetharaman V, Semiatin S L. Deformation and microstructure development duringhot-pack rolling of a near-gamma titanium aluminide alloy[J]. Scripta Materialia, 1995, 32(8): 1133-1138. doi: 10.1016/0956-716X(94)00016-B [55] Tetsui T, Shindo K, Kaji S, et al. Fabrication of TiAl components by means of hot forging and machining[J]. Intermetallics, 2005, 13(9): 971-978. doi: 10.1016/j.intermet.2004.12.012 [56] Zhang S Z, Zhang C J, Du Z X, et al. Microstructure and tensile properties of hot forged high Nb-containing TiAl-based alloy with initial near-lamellar microstructure[J]. Materials Science and Engineering: A, 2015, 642: 16-21. doi: 10.1016/j.msea.2015.06.066 [57] 刘先锋. β凝固TiAl合金挤压变形组织与力学性能研究[D]. 合肥: 中国科学技术大学, 2020. Liu Xianfeng. Microstructure and mechanical properties of β-solidifying TiAl alloy during extrusion deformation[D]. Hefei: University of Science and Technology of China, 2020.Liu Xianfeng. Microstructure and mechanical properties of β-solidifying TiAl alloy during extrusion deformation[D]. Hefei: University of Science and Technology of China, 2020. [58] Xu W C, Shan D B, Zhang H, et al. Effects of extrusion deformation on microstructure, mechanical properties and hot workability of β containing TiAl alloy[J]. Materials Science and Engineering: A, 2013, 571: 199-206. doi: 10.1016/j.msea.2013.02.005 [59] Jia Mengyu, Qiang Fengming, Yu Yonghao, et al. Tailoring lamellar orientation and tensile properties of TNM alloy via extrusion[J]. Journal of Materials Research and Technology, 2024, 28: 363-370. doi: 10.1016/j.jmrt.2023.11.245 [60] Jia Mengyu, Wang Yarong, Xu Xiaoxuan, et al. Mechanistic origins of lamellar orientation-dependent strength-ductility duality in polycrystalline γ-TiAl alloys at elevated temperatures[J]. Materials Science and Engineering: A, 2025, 948: 149319. doi: 10.1016/j.msea.2025.149319 [61] Jia Mengyu, Wang Yarong, Xu Xiaoxuan, et al. Tailoring strong basal texture and enhanced strength in a β-solidifying TNM alloy via two-step hot extrusion[J]. Materials Letters, 2026, 405: 139814. doi: 10.1016/j.matlet.2025.139814 [62] Li Jintao, Wang Xiaopeng, Gong Minyu, et al. Microstructure evolution of extruded TiAl alloy during vacuum isothermal superplastic forging process[J]. Metals, 2025, 15(2): 123. doi: 10.3390/met15020123 [63] 刘江平, 苏彦庆, 郭景杰, 等. γ-TiAl基合金薄板制备技术[J]. 特种铸造及有色合金, 2010, 30(2): 127-130. Liu Jiangping, Su Yanqing, Guo Jingjie, et al. Preparation technology of γ-TiAl-based alloy sheets[J]. Special Casting & Nonferrous Alloys, 2010, 30(2): 127-130. doi: 10.3870/tzzz.2010.02.009Liu Jiangping, Su Yanqing, Guo Jingjie, et al. Preparation technology of γ-TiAl-based alloy sheets[J]. Special Casting & Nonferrous Alloys, 2010, 30(2): 127-130. doi: 10.3870/tzzz.2010.02.009 [64] 黄财林. TiAl合金板材的制备与组织性能研究[D]. 哈尔滨: 哈尔滨工业大学, 2014. Huang Cailin. Preparation, microstructure and properties of TiAl alloy sheets[D]. Harbin: Harbin Institute of Technology, 2014.Huang Cailin. Preparation, microstructure and properties of TiAl alloy sheets[D]. Harbin: Harbin Institute of Technology, 2014. [65] 罗媛媛, 杨帆, 赵彬, 等. 新型γ-TiAl合金板材显微组织与拉伸性能研究[J]. 稀有金属与硬质合金, 2018, 46(4): 64-68. Luo Yuanyuan, Yang Fan, Zhao Bin, et al. Microstructure and tensile properties of a novel γ-TiAl alloy sheet[J]. Rare Metals and Cemented Carbides, 2018, 46(4): 64-68.Luo Yuanyuan, Yang Fan, Zhao Bin, et al. Microstructure and tensile properties of a novel γ-TiAl alloy sheet[J]. Rare Metals and Cemented Carbides, 2018, 46(4): 64-68. [66] Zhou Haitao, Kong Fantao, Wang Xiaopeng, et al. High strength in high Nb containing TiAl alloy sheet with fine duplex microstructure produced by hot pack rolling[J]. Journal of Alloys and Compounds, 2017, 695: 3495-3502. doi: 10.1016/j.jallcom.2016.12.005 [67] Zhang Yu, Wang Xin, Kong Fantao, et al. A high-performance β-stabilized Ti-43Al-9V-0.2Y alloy sheet with a nano-scaled antiphase domain[J]. Materials Letters, 2018, 214: 182-185. doi: 10.1016/j.matlet.2017.12.002 [68] 陈林. 含β稳定元素TiAl合金的组织优化及蠕变性能研究[D]. 北京: 北京科技大学, 2021. Chen Lin. Microstructure optimization and creep properties of TiAl alloy containing β-stabilizing elements[D]. Beijing: University of Science and Technology Beijing, 2021.Chen Lin. Microstructure optimization and creep properties of TiAl alloy containing β-stabilizing elements[D]. Beijing: University of Science and Technology Beijing, 2021. [69] Li Tianrui, Liu Guohui, Xu Ming, et al. High temperature deformation and control of homogeneous microstructure during hot pack rolling of Ti-44Al-5Nb-(Mo, V, B) alloys: The impact on mechanical properties[J]. Materials Science and Engineering: A, 2019, 751: 1. doi: 10.2139/ssrn.6299044 -
下载: