Research progress and prospects of Ti particle-reinforced magnesium matrix composites: A review on microstructure and mechanical properties
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摘要: Ti颗粒增强镁基复合材料作为一种兼具轻量化与高性能的理想材料,在航空航天、生物医疗等前沿领域展现出重要的应用潜力。近年来,国内外研究者们在Ti颗粒增强镁基复合材料的制备方法、合金系开发及强韧化机理理解等方面均取得了显著的研究进展。为此,从制备Ti颗粒增强镁基复合材料的基体合金角度展开叙述,讨论了基体合金体系、增强体特征、制备手段、变形方法等因素对镁基复合材料微观结构和力学性能的影响规律,综合讨论了Ti颗粒增强镁基复合材料的强韧化机制,最后对未来研究内容和发展方向进行了具有现实意义的展望。Abstract: Ti particle-reinforced magnesium matrix composites have emerged as ideal materials combining lightweight design and high performance, demonstrating significant application potential in frontier fields such as aerospace and biomedical engineering. In recent years, researchers worldwide have made remarkable progress in the fabrication methods, alloy system development, and understanding of strengthening and toughening mechanisms of these composites. In this regard, this review starts from the perspective of the matrix alloys used for preparing Ti particle-reinforced magnesium matrix composites, discusses the influencing laws of factors including matrix alloy systems, reinforcement characteristics, preparation techniques, and deformation methods on the microstructure and mechanical properties of magnesium matrix composites, comprehensively summarizes the strengthening and toughening mechanisms of Ti particle-reinforced magnesium matrix composites, and finally presents a practically meaningful prospect for future research contents and development directions.
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Key words:
- Ti particles /
- magnesium matrix composites /
- microstructures /
- mechanical properties
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图 2 Ti/AZ31复合材料的界面结构和晶粒细化机理示意[46-47]。
(a)Ti/AZ31-CPS复合材料的Ti/Mg界面结构;(b)图(a)中TiAl/MgO界面及TiAl、MgO的快速傅里叶变换(FFT)图;(c)图(a)中MgO/Mg界面及Mg的FFT图;(d)Ti/AZ31-CPS复合材料晶粒细化机理示意及光学显微组织(OM)图;(e)Ti/AZ31-HPS复合材料晶粒细化机理示意及OM图
Figure 2. Interface structure and schematic diagrams of the grain refinement mechanism of Ti/AZ31 composites[46-47]
图 3 累积挤压粘结(AEB)工艺示意及不同道次产物的显微组织与织构分析[52]
(a)累积挤压粘结(AEB)工艺示意;(b)拉伸取样位置示意;(c)~(c2)TAZ/AZ@2P的OM图;(d)~(d2)TAZ/AZ@3P的OM图;(e)(g)TAZ/AZ@2P的反极图(IPF)与极图(PF);(f)(h)TAZ/AZ@3P的IPF与PF
Figure 3. Schematic of the accumulative extrusion bonding (AEB) process and microstructure/texture analysis of products from different passes[52]
图 6 5Ti/VW92复合材料的界面微观结构和元素分布[79]
(a)~(i)Ti颗粒界面局部区域的元素分布;(j)Mg/Ti界面产物形貌;(k)图(j)中齿轮状$ {\left(\mathrm{Gd},\mathrm{Y}\right)\mathrm{H}}_{2} $相的HRTEM图像;(l)齿轮状$ {\left(\mathrm{Gd},\mathrm{Y}\right)\mathrm{H}}_{2} $相的SAED图谱
Figure 6. Interfacial microstructure and elemental distribution of the 5Ti/VW92 composite[79]
表 1 Ti/Mg-Al系复合材料力学性能
Table 1. Mechanical properties of Ti/Mg-Al composites
Matrix Addition Particle
size/μmMethods Mechanical properties Refs. Particles Contents/
%YS/
MPaUTS/
MPaEL./% AZ31 TC4 1 0.063 SC+Ext. 205,193 272,280 17.7,23.2 [40] TC4 6 8 SC+Ext. 245 327 20.4 [41] Ti 1.5 0.05~0.1 PM 143 243 11.5 [42] Ti 6 8 HPS+Ext. 199 290 [46] CPS+Ext. 255 304 Ti 9 10 CPS+Ext. 264 294 8 [47] Ti 0.5 0.05~0.1 CPS+Ext. 201 304 8.4 [48] TC4 1 0.06 PM+Ext. 195 306 9.2 [49] Ti 6 20 HPS+AE 183.8 317.1 11.5 [50] Ti 1.2 70 HPS+AEB 207.3 315.2 7.8 [51] Ti 3 10 PM+AEB 222.7 332.5 12.8 [52] AZ91 Ti 5 15 PM 123 211 21.8 [66] Ti 5 5~20 SC 185 313 7.87 [54] Ti 2 1.15 SC+Ext. 217 345 23.4 [55] Ti 1* 10 SC+Ext. 366 456 14.6 [56] Ti 10 15 SC+Ext.+
Rol.365 12 [57] Ti 4* 6.5 SC 150 217 1.84 [58] Ti 4* 4.5 SC+Ext. 257 370 18.7 [59] Ti 5 45 HPS 98 221.1 10.9 [60] TC4 10 15~53 PM+Ext. 335 370 6.4 [61] Ti 5 53~75 HPS+Ext. 211 303 18.7 [62] GNPs+Ti 1.6 10 EPD+Rol. 160 243 20.8 [63] Cu@Ti 5 10 PM+Ext. 238 368 12 [64] Zn@Ti 5 10~20 PM+Ext. 248 378 15 [65] 注:*指代体积百分数。 表 2 Ti/Mg-Zn系复合材料力学性能
Table 2. Mechanical properties of Ti/Mg-Zn composites
表 3 Ti/Mg-RE系复合材料力学性能
Table 3. Mechanical properties of Ti/Mg-Al composites
Matrix Addition Particle
size/μmMethods Mechanical properties Refs. Particles Contents/% YS/
MPaUTS/
MPaEL./
%Mg-Y-Nd Ti 3 15 SC+Ext. 241 283 17.30 [71] Ti 6 20 SC+MDC 255 316 8.90 [72] Ti 6 12~15 HPS+Ext. 267 337 15.10 [73] Ti、Al、Sn FSP 224 32.70 [74] Mg-Gd-Y Ti 3.5 3.3/24.1 SC 162 240 7.70 [68] Ti 5 3.25 SC 173 256 5.90 [76] Ti 5 3.25 SC+Ext. 288 371 9.40 [77] Ti 3 8 SC+Ext.+RS 370 453 3.80 [78] Ti 5 7.8 SC+Ext. 255 378 12.08 [79] Al@Ti 5 1~20 SC+Ext. 319 388 11.70 [80] Ti 3.5 SC+Ext.+SFT 309 383 8.70 [82] -
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