A study on the melting process of novel Ti551 titanium alloy using VAR numerical simulation
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摘要: 为满足深海装备对耐压材料的需要,围绕新型α+β钛合金Ti551的熔炼工艺展开系统研究,在数值模拟优化熔炼参数的基础上,成功实现了从150 kg试验模型到3 t级工业铸锭的放大制备,并采用真空自耗电弧熔炼(VAR)工艺进行验证,最终获得纯净度高、组织均匀性良好的3 t级Ti551工业铸锭。研究重点考察了熔炼电流与稳弧电流对铸锭成分均匀性和熔池形貌的影响,通过五种不同熔炼工艺的对比试验,得出在熔炼电流为21~24 kA、稳弧电流为15 A、稳弧交流时间为30 s的优化工艺条件下,所获效果最优的结论。基于该工艺制备的3 t工业铸锭表面光洁,无冷隔、皮下气孔及夹渣等缺陷,成分均匀性良好,其中Cr、Fe、Sn、V、Zr等关键元素的极差均不超过0.03,未出现明显宏观偏析,综合性能满足深海装备对原材料的严苛要求。
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关键词:
- 新型Ti551钛合金 /
- 真空自耗电弧熔炼 /
- 数值模拟 /
- 成分均匀
Abstract: To meet the demand for pressure-resistant materials in deep-sea equipment, this study investigated the melting process of a novel α+β titanium alloy Ti551 based on Vacuum Arc Remelting (VAR) numerical simulation. By optimizing parameters through numerical simulation, the melting process was directly scaled up from a 150 kg model to produce 3-ton industrial-scale ingots via VAR. The results demonstrate the successful production of high-purity, highly homogeneous 3-ton Ti551 industrial ingots. The study focused on the effects of melting current and arc-stabilizing current on compositional homogeneity and pool profile, identifying reduced melting current as the optimal parameter. Through comparative experiments of five different melting processes, it was concluded that the optimized process conditions—a melting current of 21~24 kA, an arc-stabilizing current of 15 A, and an AC arc stabilization time of 30 s—yielded the best results. Based on this optimized process, the produced 3-ton industrial ingots exhibited a smooth surface free from defects such as cold shuts, subsurface porosity, and slag inclusions. The ingots demonstrated good compositional uniformity, with the range of key elements including Cr, Fe, Sn, V, and Zr all within 0.03, indicating no significant macrosegregation. The overall properties meet the stringent requirements for raw materials used in deep-sea equipment. -
表 1 计算采用的Ti551钛合金物性参数
Table 1. Physical parameters of Ti551 titanium alloy used in calculation
Liquid density/(kg·m−3) Solid density/(kg·m−3) Volume expansion
coefficient×105/K−1Solidus
temperature/KLiquidus
temperature/KLatent heat×
10−5/(J·kg−1)Electrical conductivity×
10−5/(A·V−1·m−1)4060 4510 9.35 1947 2000 3.20 8.5 表 2 3 t Ti551钛合金第三次VAR熔炼的不同模拟计算工艺参数
Table 2. Different simulation calculation process parameters for the third VAR melting of 3 t Ti551 titanium alloy
Melting condition Electric current/kA Arc stabilizing current /A Arc stabilizing AC time/s Process 1 Benchmark process 23~26 15 30 Process 2 Increase melting current 25~28 15 30 Process 3 Reduce melting current 21~24 15 30 Process 4 Increase arc stabilizing current 23~26 20 30 Process 5 Reduce arc stabilizing current 23~26 10 30 表 3 Ti551钛合金铸锭成分分析结果
Table 3. Composition analysis results of Ti551 titanium alloy ingot
% Cr Fe Sn V Zr Standard value 0.8~1.2 ≤0.20 0.8~1.2 0.8~1.2 0.8~1.2 Maximum value 0.96 0.16 1.04 1.03 1.01 Minimum value 0.93 0.15 1.03 1.00 0.98 Average value 0.96 0.15 1.04 1.02 1.00 Extreme difference 0.03 0.01 0.01 0.03 0.03 -
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