2022 Vol. 43, No. 6

Separating and Extracting of Vanadium and Titanium
Study on the extraction performance of V(IV) by P204 in sulfuric acid system
Feng Xueru, Lv Guozhi, Zhang Ting’an, Zhao Qiuyue
2022, 43(6): 1-6. doi: 10.7513/j.issn.1004-7638.2022.06.001
Abstract(424) HTML (82) PDF(23)
Abstract:
The leaching solution was taken as the research object which was obtained from the new process for vanadium production by acid leaching with titanium white waste acid under the pressure without roasting. V(IV) solution in sulfuric acid system was prepared to study on the extraction performance of V(...
Experimental study on precipitation of ammonium metavanadate in NaVO3-H2O system by ammonium bicarbonate and ammonium carbonate
Rao Yuzhong, Fu Zibi
2022, 43(6): 7-13. doi: 10.7513/j.issn.1004-7638.2022.06.002
Abstract(355) HTML (145) PDF(27)
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For the NaVO3-H2O solution system obtained by extracting vanadium from vanadium slag by sodium method, the effects of precipitation pH value, precipitation temperature, crystallization time, ammonium addition coefficient on the crystallization of ammonium metavanadate were investigated using ammoniu...
Extraction of vanadium from high-chromium vanadium-bearing titanomagnetite pellets by oxidation roasting-HCl leaching process
Wu Enhui, Li Jun, Xu Zhong, Hou Jing, Huang Ping, Li Hong
2022, 43(6): 14-23. doi: 10.7513/j.issn.1004-7638.2022.06.003
Abstract(282) HTML (88) PDF(38)
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The relationship between crushing strength of pellets and leaching behaviors of vanadium in oxidation roasting-HCl leaching process from high-chromium vanadium-bearing titanomagnetite concentrates were investigated in this work. The results of the thermodynamic analysis of oxidizing roasting process...
Hydrothermal synthesis and phase transformation properties of W-doped VO2(M) nanoparticles
Yang Xue, Zou Jian
2022, 43(6): 24-30. doi: 10.7513/j.issn.1004-7638.2022.06.004
Abstract(792) HTML (231) PDF(53)
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In this paper, using ammonium metavanadate as the vanadium source, hydrazine monohydrate as the reducing agent and ammonium metatungstate as the dopant, the VO2 powder doped with W from 0.0 to 2.0 at% was prepared by one-step hydrothermal method at 280 ℃, and was added to polyurethane to prepare VO2...
Effect of Sc3+ doping on lithium storage performance of Li3V2(PO4)3/C cathode material synthesized by carbothermal reduction method
Feng Xuegang, Li Nali, Liu Tiantian
2022, 43(6): 31-37. doi: 10.7513/j.issn.1004-7638.2022.06.005
Abstract(321) HTML (108) PDF(26)
Abstract:
In this paper, Sc3+ doped Li3V2(PO4)3/C cathode material was successfully prepared by carbothermal reduction method. The effects of Sc3+ doping amount on the structure, morphology and lithium storage properties of Li3V2(PO4)3 were systematically investigated. Although Sc3+ doping does not change the...
Effect of manganese on vanadium extraction by calcification from vanadium slag
Ye Lu, Du Guangchao, Li Yuepeng, Peng Yi, Liu Yan
2022, 43(6): 38-44. doi: 10.7513/j.issn.1004-7638.2022.06.006
Abstract(327) HTML (131) PDF(32)
Abstract:
In this paper, two batches of vanadium slag with different Mn content were taken as the research object. XRD and SEM-EDS were used to explore the phase composition and microstructure of vanadium slag, and to find out the phase change of calcified roasted clinker with different Mn content and its eff...
Application of Vanadium and Titanium
Hot deformation behavior and processing maps of TA18 titanium alloy
Peng Li, Jiang Jian, Luo Xiaofeng, Shen Xueliang, Wang Ying, Xing Yuan
2022, 43(6): 45-50. doi: 10.7513/j.issn.1004-7638.2022.06.007
Abstract(426) HTML (158) PDF(35)
Abstract:
The hot deformation behavior of TA18 Titanium alloy was investigated using the Gleeble-3500 test machine at 750 − 1050 ºC with strain rates from 0.001 s−1 to 10 s−1, and the constitutive equation including Zener-Hollomon parameter (Z parameter) and processing map was established. The results reveale...
Constitutive relationship analysis and microstructural evolution of biomedical Ni-Ti alloy during warm deformation
Zhu Shaozhen, Wang Jie
2022, 43(6): 51-57. doi: 10.7513/j.issn.1004-7638.2022.06.008
Abstract(324) HTML (241) PDF(39)
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In order to study warm deformation behavior of the biomedical Ni-Ti alloy, compression tests were performed on a Gleeble-3800 thermal simulator. The true stress-true strain curves were obtained. The constitutive relationship and microstructures evolution during the deformation were analyzed. The pro...
Research on radio frequency plasma spheroidized Ti-25Ta powder and its fabrication by selective laser melting
Pu Yunna, Zhao Dewei, Shi Qi, Tan Chong, Zheng Haizhong, Liu Xin, Ding Zhongyao
2022, 43(6): 58-65. doi: 10.7513/j.issn.1004-7638.2022.06.009
Abstract(263) HTML (141) PDF(46)
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The Ti-25Ta alloy powder was successfully prepared by radio frequency plasma spheroidization, and the Ti-25Ta alloy spherical powder was subsequently formed by selective laser melting. The effect of laser power on the surface morphology, density, microstructure and mechanical properties was studied....
Effect of heat treatment on microstructure and properties of Ti84Al11FeMo4 titanium alloy
Zhang Xuefeng, Chen Min, Liu Xuyang, Gao Youzhi, Wei Liangxiao, Cai Junhao, Ni Zijie, Chen Xincai
2022, 43(6): 66-70. doi: 10.7513/j.issn.1004-7638.2022.06.010
Abstract(371) HTML (140) PDF(29)
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A novel two-phase titanium alloy of Ti84Al11FeMo4 was designed based on d-electron theory and the phase composition as a function of temperature was analyzed. Combined with the thermodynamic calculation results, the evolution relationship between the microstructure and mechanical properties of titan...
Effects of carbon microalloying on microstructure and mechanical properties of low-cost Ti-4.5Al-3.5Zr-2Fe titanium alloy
Wang Andong, Wang Zhitian, Xiang Zhilei, Han Jingyu, Zhou Zongyi, Shen Gaoliang, Huang Jingcun, Chen Ziyong
2022, 43(6): 71-77. doi: 10.7513/j.issn.1004-7638.2022.06.011
Abstract(300) HTML (107) PDF(35)
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Low-cost Ti-4.5Al-3.5Zr-2Fe titanium alloys with different carbon content of 0, 0.1%, 0.15% and 0.3% were prepared in a water-cooled copper crucible vacuum induction levitation melting furnace. The effects of carbon microalloying on the as-cast microstructure and mechanical properties of the titaniu...
Effect of solution aging treatment on microstructure and properties of Ti60 alloy
Zhang Tianxin, Yue Ke, Hu Zhaohua, Guo Jie, Geng Naitao
2022, 43(6): 78-83. doi: 10.7513/j.issn.1004-7638.2022.06.012
Abstract(366) HTML (90) PDF(38)
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The effect of solution and aging treatment on the microstructure of Ti60 alloy was investigated by optical microscope and scanning electron microscope. Combined with the tensile tests at room temperature and 600 ℃, it is found out the 1/2 height area of forged billet is relatively uniform and suitab...
Effect of wall thickness and casting defects on microstructure and properties of ZTA15 titanium alloy
Han Yunfei, Yuan Bingbing, Sun Bing, Liu Yihui, Qiao Haibin, Li Bobo
2022, 43(6): 84-88. doi: 10.7513/j.issn.1004-7638.2022.06.013
Abstract(301) HTML (135) PDF(27)
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In this paper, cylindrical and dumbbell shaped ZTA15 titanium alloy test bars (as cast) were prepared by investment casting technology, and then treated by hot isostatic pressing (HIP). The effects of wall thickness and casting defects on the microstructure and properties of ZTA15 titanium alloy wer...
Resources Environment and Energy Saving
Clean, high efficiency and green utilization of vanadium tailings extracted by calcium process
He Wei, Wang Jian, Ge Wensun, Chen Lian
2022, 43(6): 100-108. doi: 10.7513/j.issn.1004-7638.2022.06.015
Abstract(388) HTML (153) PDF(64)
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Calcium extraction of vanadium tailings was taken as research object, the composition, phase and occurrence state of main elements of the tailings were analyzed. On the basis of combining previous studies, the comprehensive utilization of vanadium-bearing alloy and titanium-bearing furnace slag from...
Performance of pyrite-catalyzed CO reduction of NO
Zhang Zhao, Qi Rui, Xu Yaxin, Gong Zhijun
2022, 43(6): 109-114. doi: 10.7513/j.issn.1004-7638.2022.06.016
Abstract(274) HTML (61) PDF(28)
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Pyrite was used as denitrification catalyst to investigate the performance in catalytic CO reduction of NO. XRF, XRD, SEM-EDS and H2-TPR are used for characterization. The results showed that the NO conversion for pyrite was 78.53% at 400 ℃ and remained constant at 100% in the temperature range of 5...
Experimental study on mineralogy and beneficiation of an iron ore from Australia
Yang Zhaojun, Xie Baohua, Zhong Senlin, Wang Fengyu, Liang Taomao, Li Bo
2022, 43(6): 115-120. doi: 10.7513/j.issn.1004-7638.2022.06.017
Abstract(231) HTML (71) PDF(24)
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Australia is rich in high-quality iron ore resources with high raw ore grade and low content of harmful elements, which can be directly smelted without beneficiation after mining. However, high-quality iron ore resources are not renewable. The development and utilization of lower grade iron ore reso...
Research on forming experiment of Panzhihua pyrite residue pellets with carbon-containing
Li Junhan
2022, 43(6): 121-125. doi: 10.7513/j.issn.1004-7638.2022.06.018
Abstract(194) HTML (59) PDF(23)
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In order to separate and recover iron resources of Panzhihua pyrite residue, using Panzhihua pyrite residue as raw material, pulverized coal as carbon source, and polyvinyl alcohol (PVA) as binding agent, the influences of the content of polyvinyl alcohol, the water content, the pressure and the par...
Ferrous Metallurgy and Materials
Thermodynamic analysis of inclusion control in Mg-Al-Ti system oxide metallurgy technology
Guo Zhihong, Shi Saichao, Wang Qi, Ma Guojin, Wang Genji, Zhu Liguang
2022, 43(6): 126-137. doi: 10.7513/j.issn.1004-7638.2022.06.019
Abstract(394) HTML (88) PDF(49)
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The oxide metallurgy technology with the low aluminum condition is carried out in marine steel and further expands the adjustment range of alloy compositions, which is beneficial to promote the effective inclusion of inducing acicular ferrite. This research has a significant potential application to...
Study on transformation behavior of ultra-high strength steel for construction machinery
Zheng Dongsheng, Fan Caihe, Hu Zeyi, Sun Yaxin, Luo Deng, Liu Dan, Zhang Qingxue
2022, 43(6): 138-142. doi: 10.7513/j.issn.1004-7638.2022.06.020
Abstract(240) HTML (116) PDF(9)
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Transformation behavior of Cr-Mo-Ni-B ultra-high strength steel for construction machinery under continuous cooling condition was studied by means of MMS-200 thermomechanical simulator. The effect of cooling rate (0.5~40 ℃/s) on its transformation temperature and microstructure was analyzed by therm...
Analysis of inclusions in the whole process of 20MnCr5 gear steel
Bai Xuxu, Zhang Min, Zeng Jianhua, Yang Shufeng, Li Jingshe
2022, 43(6): 143-148. doi: 10.7513/j.issn.1004-7638.2022.06.021
Abstract(292) HTML (86) PDF(25)
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In order to effectively improve the cleanliness of gear steel and product quality, it is necessary to clarify the evolution behavior of non-metallic inclusions in the smelting process of gear steel. This paper takes 20MnCr5 gear steel as the research object. Through sampling and analysis of the whol...
Experimental study on HRB500E seismic reinforcement bar produced by microalloying of high nitrogen ferrovanadium alloy
Jia Yihan, Wang Qingchen, Cao Changshan, Weng Yujuan
2022, 43(6): 149-152. doi: 10.7513/j.issn.1004-7638.2022.06.022
Abstract(203) HTML (161) PDF(28)
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Based on the process and equipment of converter, continuous casting and rolling, the experimental study on the production of HRB500E high strength anti-seismic steel rebar by microalloying with high nitrogen ferrovanadium alloy was carried out. The results show that compared with vanadium-nitrogen a...
Study on the evolution law of surface decarburization of Cr-Mo-V cold heading steel
Chen Jilin, Ma Honglei, Huo Liwei, Yan Cong, Zhang Kunyao
2022, 43(6): 153-160. doi: 10.7513/j.issn.1004-7638.2022.06.023
Abstract(308) HTML (63) PDF(9)
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The effects of heating temperature, heating time, and surface treatment on the depth of decarburized layer and microstructure of cold heading 40CrMoV steel were studied, and the evolution mechanism of surface decarburization with temperature was analyzed. The results show that when the cold heading ...
Study on hydrogen embrittlement sensitivity of vanadium microalloyed martensite-bainite steel
Zhang Songqi, Li Yuanyuan, Wang Dejun
2022, 43(6): 161-165. doi: 10.7513/j.issn.1004-7638.2022.06.024
Abstract(215) HTML (66) PDF(28)
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The hydrogen embrittlement sensitivity of vanadium-free and vanadium-containing (0.15%) martensite-bainite steel was studied utilizing a scanning electron microscope and transmission electron microscope. The test results show that adding vanadium will refine the prior austenite structure in martensi...
As-cast microstructure and mechanical properties of Y12Cr18Ni9 free-cutting steel
Wang Yinghu, Zheng Huaibei, Fang Yi, Liu Tingyao, Wang Liwei, Yao Bin
2022, 43(6): 166-172. doi: 10.7513/j.issn.1004-7638.2022.06.025
Abstract(455) HTML (148) PDF(22)
Abstract:
The as-cast structure and mechanical properties of Y12Cr18Ni9 free-cutting steel were studied by means of thermodynamic calculation software FactSage, SEM and Phenom Partical X SEM-EDS. The results show that the main equilibrium phases in Y12Cr18Ni9 free-cutting steel are Liquid, MnS, δFerrite, Aust...
Molecular dynamics simulation of tensile mechanical properties of AlxCoCrFeNi
Zhang Rong, Qi Wenjun, Zhang Shuang
2022, 43(6): 173-179. doi: 10.7513/j.issn.1004-7638.2022.06.026
Abstract(821) HTML (282) PDF(109)
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In this paper, the molecular dynamics method studied the microstructural evolution, deformation mechanism, and mechanical properties of AlxCoCrFeNi high entropy alloy (HEAs) under uniaxial tension. The effects of Al content, high temperature, and high strain rate on the mechanical properties of AlxC...
Research on effects of multi-pass rolling and heat treatment of cast Mn18Cr18N steel
Liu Jie, Li Juan
2022, 43(6): 180-184. doi: 10.7513/j.issn.1004-7638.2022.06.027
Abstract(211) HTML (139) PDF(16)
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Mn18Cr18N electro-slag remelting steel was rolled in three or five passes and subject to solid solution treatment. The microstructure observation by electron back scattering diffraction (EBSD) indicates that with the increase of rolling passes, the recrystallized grains grow along the grain boundari...
Research and application of rail universal pass design method
Tao Gongming, Zhu Jun, Liu Jian, Zhang Xuebin, Hu Xiao, Chen Yuanfu
2022, 43(6): 185-192. doi: 10.7513/j.issn.1004-7638.2022.06.028
Abstract(1957) HTML (158) PDF(42)
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Combined with practical production experience, taking the rail products of seven racks universal production line as an example, this paper studies and deduces the pass design method of the universal zone. According to the finished product size, each pass's elongation coefficient, the local size defo...
Accelerated search for solid lithium-ion conductor materials based on material genome engineering
Shui Lang, Fu Jianhui
2022, 43(6): 193-200. doi: 10.7513/j.issn.1004-7638.2022.06.029
Abstract(202) HTML (128) PDF(33)
Abstract:
We here present a new approach of model construction to search for solid superionic materials in database by using decision tree and random forest algorithms. Based on a data set collected from literature and 20 features computed from lattice parameters, we constructed two decision tree models and a...