In this paper mineralogical characteristics of sulfide in vanadium titano-magnetite of Panzhihua Hongge area,Sichuan province had been extensively investigated by the methods of optical microscope,SEM,EMPA,XRF etc. The observation results reveal that metal (Co,Ni,Cu,Fe,etc) sulfide-based pyrrhotite and pyrite present in the ores and distribute in titanium-ferro oxides and silicate minerals in form of irregular granula or aggregates. The content of Co,Ni,Cu and Fe,S are not significantly related with each other. Sulfide is composed of various contents of pyrrhotite,pyrite and chalcopyrite. The results will help to the comprehensive utilizations of the sulfide in this kind of ore.