Mu Hongbo. Study on the Reaction of Ti0 and Ti3+ Ions in Molten Salt[J]. IRON STEEL VANADIUM TITANIUM, 2018, 39(5): 5-8. doi: 10.7513/j.issn.1004-7638.2018.05.002
Citation:
Mu Hongbo. Study on the Reaction of Ti0 and Ti3+ Ions in Molten Salt[J]. IRON STEEL VANADIUM TITANIUM, 2018, 39(5): 5-8. doi: 10.7513/j.issn.1004-7638.2018.05.002
Mu Hongbo. Study on the Reaction of Ti0 and Ti3+ Ions in Molten Salt[J]. IRON STEEL VANADIUM TITANIUM, 2018, 39(5): 5-8. doi: 10.7513/j.issn.1004-7638.2018.05.002
Citation:
Mu Hongbo. Study on the Reaction of Ti0 and Ti3+ Ions in Molten Salt[J]. IRON STEEL VANADIUM TITANIUM, 2018, 39(5): 5-8. doi: 10.7513/j.issn.1004-7638.2018.05.002
The molten salts containing titanium ions with lower valence state were prepared by the reaction of titanium sponge and TiCl4 in NaCl-KCl molten salts（molar ratio of NaCl∶KCl=1∶1）. The average valence state of titanium ions was calculated, and then the molten salts with Ti3+ and Ti~0 were obtained by reaction between TiCl4 of calculated amount and excess titanium sponge. The ion reaction of Ti and Ti3+ was investigated. It is indicated that the reaction at 0～210 min is of second order. The results in this paper have directive significance on titanium powder preparation by molten salts electrolysis.
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