2023 Vol. 44, No. 4

Separating and Extracting of Vanadium and Titanium
Study on migration and transformation behavior of elements during vanadium extraction by calcification
Liu Xi, Pu Yuwen, Xu Zongyuan, Tang Kang, Zheng Guocan, Chen Yan, Liu Zuohua, Du Jun, Peng Yi, Tao Changyuan
2023, 44(4): 1-9. doi: 10.7513/j.issn.1004-7638.2023.04.001
Abstract(376) HTML (68) PDF(46)
Abstract:
Combined with XRD, XPS, SEM-EDS and ICP-OES characterizations, the phase composition and morphology of acid ammonium salt precipitation vanadium products under different pH values were studied; also the migration and transformation behavior of V, Fe and Mn were analyzed when the pH value of vanadium...
Study on the preparation of spherical TiC nanopowder by molten salt method
Li Wenjing, Guo Yun, Yang Yadong, Liu Bo, Xin Yanan
2023, 44(4): 10-17. doi: 10.7513/j.issn.1004-7638.2023.04.002
Abstract(362) HTML (112) PDF(24)
Abstract:
In combination with the national strategic deployment of the 14th Five-Year Plan, based on the enterprise resource background and the downstream market demand, this paper proposes to prepare spherical titanium carbide (TiC) nanopowder through the short process of molten salt method. The process does...
Research on the leaching characteristics of Ca, Mg, Al elements in high titanium blast furnace slag
Huangfu Lin, Jiang Yang, Qiu Zhengqiu, Wang Kui
2023, 44(4): 18-24. doi: 10.7513/j.issn.1004-7638.2023.04.003
Abstract(325) HTML (60) PDF(19)
Abstract:
To make full use of the valuable elements in high titanium blast furnace slag, the physical and chemical properties were analyzed. The method of hydrochloric acid hydrothermal leaching was proposed to separate Ca and Mg elements from high titanium blast furnace slag. And the influence of reaction co...
Study on the effect and mechanism of Al3+ during the calcination of metatitanic acid
Lu Ruifang, Yang Fang, Liu Chan, Hao Lin
2023, 44(4): 25-32. doi: 10.7513/j.issn.1004-7638.2023.04.004
Abstract(260) HTML (95) PDF(15)
Abstract:
In the production of titanium dioxide by sulfate process, obtaining rutile titanium dioxide with suitable particle size through different salt treatments and high-temperature calcination of metatitanic acid is the basis for preparing titanium pigments. Aluminum salt treatment is currently one of the...
Research progress in vanadium extraction from stone coal vanadium ore by roasting
Song Changxu, Ye Guohua, Kang Xuanxiong, Zhang Yun, Rong Yiyang, Xiang Xinyue
2023, 44(4): 33-40. doi: 10.7513/j.issn.1004-7638.2023.04.005
Abstract(550) HTML (141) PDF(65)
Abstract:
The research progress of vanadium extraction from stone coal vanadium ore by roasting was reviewed. The possible application scenarios of roasting process were discussed. The advantages and disadvantages of different roasting processes were discussed through examples. The development status and indu...
Effect of glucose content on the lithium storage performance of Li3V2(PO4)3/C cathode materials prepared by sol-gel combustion method
Li Nali, Zhang Renjie
2023, 44(4): 41-47. doi: 10.7513/j.issn.1004-7638.2023.04.006
Abstract(203) HTML (49) PDF(8)
Abstract:
In this paper, submicrometer porous Li3V2(PO4)3 (LVP)/C composites with different carbon contents were successfully prepared by a modified sol-gel combustion method by changing the amount of glucose added. The effects of glucose addition on the structure, morphology and electrochemical properties of...
Application of Vanadium and Titanium
Study on the microstructure and properties of the transition region of IN625/TC4 bimetallic structure by laser melting deposition with Cu interlayer
Wang Wenbo, Xu Nuo, Xu Guojian, Jing Zhicheng, Zhang Guoyu, Zhao Xue, Xiang Zhuo
2023, 44(4): 48-54. doi: 10.7513/j.issn.1004-7638.2023.04.007
Abstract(276) HTML (109) PDF(20)
Abstract:
The bimetallic structure composed of IN625 nickel-based high-temperature alloy with excellent high-temperature properties and lightweight and high-strength TC4 titanium alloy has broad application prospects in the aerospace field. However, due to the large differences in physical and chemical proper...
Effect of self-induced magnetic field on liquid flow and segregation during VAR process for titanium alloys
Huang Liqing, Wu Jingyang, Guo Jie, Fan Kai, Li Chao, Li Zhihong, Li Junjie, Wang Jincheng
2023, 44(4): 55-61. doi: 10.7513/j.issn.1004-7638.2023.04.008
Abstract(288) HTML (194) PDF(30)
Abstract:
A continuum model for alloy solidification was used to simulate the temperature evolution, solute distribution, liquid flow, and self-induced magnetic field during VAR process for titanium alloys. The work reveals the influence of self-induced magnetic force and/or buoyancy force on the melt flow an...
Effect of ball milling time on the microstructure and mechanical properties of porous Ti-5Cu alloys
Mai Ping
2023, 44(4): 62-67. doi: 10.7513/j.issn.1004-7638.2023.04.009
Abstract(220) HTML (56) PDF(7)
Abstract:
Biomedical porous Ti-5Cu alloys were prepared by mechanical ball milling and space holder method through vacuum sintering. The metal powders ball milled with different time were analyzed by scanning electron microscopy, X-ray diffractometer and laser particle size analyzer, and the effects of ball m...
Effect of compression deformation on the microstructure and properties of TA18 titanium alloy
Huo Sihan, Lv Xiao
2023, 44(4): 68-72. doi: 10.7513/j.issn.1004-7638.2023.04.010
Abstract(534) HTML (132) PDF(16)
Abstract:
In the present study, the compression experiments with compression deformation of 10%, 20%, 30%, 50% and 70% were carried out for the nearly α type TA18 titanium alloy bars after radial precision forging and hot rolling. The bars were subsequently annealed for 2 hours at 510 ℃. The influence of comp...
Preparation and properties of lithium titanate anode materials with different titanium sources
Jiang Xinyu, Ma Guangqiang, Zhu Qinmei, Tian Congxue
2023, 44(4): 73-77. doi: 10.7513/j.issn.1004-7638.2023.04.011
Abstract(185) HTML (273) PDF(15)
Abstract:
Spherical Li4Ti5O12 anode materials were prepared by high temperature solid phase method, and the effects of different titanium sources on the properties of Li4Ti5O12 anode materials were investigated. The structure and morphology of the prepared materials were characterized by XRD and SEM, and the ...
Study on electrical removal of aluminum from Ti-Al alloys in low-temperature molten salt
Xu Peidong, Tan Min, Li Tao, Gao Aimin, Xin Zhaoyang, Liu Wei, Gu Shaopeng
2023, 44(4): 78-84. doi: 10.7513/j.issn.1004-7638.2023.04.012
Abstract(269) HTML (98) PDF(13)
Abstract:
In order to realize the secondary recycling and separation of Al-Ti alloys, the dealloying of Al-Ti alloys was studied with 1-butyl-3-methyl imidazolium chloride (BMIC)-aluminum chloride (AlCl3) as the electrolyte and Ti-Al alloys as the sacrificial anode. Cyclic voltammetry, potentiodynamic polariz...
Study on long time corrosion resistance of titanium welded tube
Li Haiming, Hu Xingguang, Li Junzhao, Liu Wenzheng, Yang Weijun
2023, 44(4): 85-88. doi: 10.7513/j.issn.1004-7638.2023.04.013
Abstract(185) HTML (46) PDF(6)
Abstract:
Simulating different operating conditions the corrosion resistance of titanium welded pipe in tap water, 5% magnesium chloride aqueous solution, seawater and 10% sulfuric acid solution soaked for a long time was studied through macro-size detection, metallographic analysis and mechanical properties ...
Resources Environment and Energy Saving
Experimental research on the recycling of valuable metal elements with the extracted-vanadium residues reduced by biomass
Gao Yang, Xie Huaqing, Zhou Mi, Guo Rui, Qin Mengxin, Wang Zhengyu, Dai Bing
2023, 44(4): 89-95. doi: 10.7513/j.issn.1004-7638.2023.04.014
Abstract(272) HTML (96) PDF(13)
Abstract:
In order to solve the problems of land resources waste and environmental pollution caused by accumulation of vanadium extraction tailings, two kinds of vanadium extraction tailings were studied in this paper. Biomass was used as reducing agent for high temperature reduction experiment, and the compo...
Research on properties of air-quenched steel slag abrasives with different particle sizes
Li Shuo, Xing Hongwei, Liu Chao, Lin Wenlong, Zhang Wei, Gu Shaopeng, Wang Hui, Pei Jingjing
2023, 44(4): 96-102. doi: 10.7513/j.issn.1004-7638.2023.04.015
Abstract(177) HTML (38) PDF(8)
Abstract:
Using solid steel slag as raw material, steel slag with different particle sizes was prepared by air quenching after high-temperature remelting in an electric arc furnace. the differences and similarities of air-quenched steel slag with different particle sizes in terms of phase composition, microst...
Study on hydration reaction of titanium gypsum–titanium slag low clinker cement
Jiang Yong, Su Yaobin, Gao Rui, Wu Maojie, Jiang Yun, Jiao Xiaofei
2023, 44(4): 103-111. doi: 10.7513/j.issn.1004-7638.2023.04.016
Abstract(240) HTML (52) PDF(9)
Abstract:
In order to explore the feasibility of using titanium gypsum and titanium slag to prepare low clinker cement and study its hydration characteristics, 10 groups of cement were prepared with titanium gypsum, titanium slag and cement clinker as the main raw materials and sodium silicate as the activato...
Laboratory study on improving recovery rate of pyrite concentrate in titanium separation process in Panxi region
Wang Hongbin, Shi Zhangliang, Zhao Kaile, Yang Yaohui, Luo Rongfei
2023, 44(4): 112-116. doi: 10.7513/j.issn.1004-7638.2023.04.017
Abstract(207) HTML (47) PDF(10)
Abstract:
In the case of sanding of a titanium flotation inclined plate in Panxi area, the conventional process of “first floating sulfur and then enriching cobalt sulphide” and the recovery of sulphides with the conventional reagent “Butyl xanthate +2# oil” were adopted, the low recovery of cobalt sulphide i...
Ferrous Metallurgy and Materials
Effect of preformed calcium ferrite addition on sintering behavior of vanadium titanomagnetite
Xie Hao, Li Gang, Lv Xuewei, Sun Xiaodong, He Haixi
2023, 44(4): 117-124. doi: 10.7513/j.issn.1004-7638.2023.04.018
Abstract(295) HTML (93) PDF(15)
Abstract:
In view of the problems of low yield, poor strength and high energy consumption in the sintering process of vanadium titanomagnetite, a new sintering technology of preformed calcium ferrite is proposed in this paper, and its feasibility and theoretical basis are revealed through the tablet sintering...
Investigation of multiphase transport behaviors in a FTSR mold during electromagnetic continuous casting process
Xu Lin, Pei Qunwu, Li Yang, Han Zefeng, Yang Shuo, Wang Jianyu
2023, 44(4): 125-134. doi: 10.7513/j.issn.1004-7638.2023.04.019
Abstract(232) HTML (65) PDF(5)
Abstract:
For the research object of flexible thin slab rolling (FTSR) funnel-shaped mold, a three-dimensional (3-D) multi-field coupling mathematical model was established for describing the electromagnetic braking (EMBr) continuous casting process. To investigate the metallurgical effect of Ruler-EMBr devic...
High temperature mechanical properties and hot working properties of high magnetic orientation silicon steel
Shi Pengzhao, Li Jiangbo, Qiao Jialong, Guo Feihu, Qiu Shengtao
2023, 44(4): 135-141. doi: 10.7513/j.issn.1004-7638.2023.04.020
Abstract(326) HTML (109) PDF(10)
Abstract:
In this paper, Gleeble3800 thermal simulation test machine was used to conduct high temperature tensile and high temperature compression experiments on high magnetic induction oriented silicon steel billets. The influence of temperature on high temperature mechanical properties (tensile strength and...
Research on microstructure evolution of GH5188 alloy during plastic processing
Guo Xulong, Jiang Shichuan, Qi Huilin, Fu Jianhui
2023, 44(4): 142-148. doi: 10.7513/j.issn.1004-7638.2023.04.021
Abstract(253) HTML (47) PDF(13)
Abstract:
The Gleeble-3800 thermal simulation testing machine was used to investigate the thermal deformation behavior and structure transfer law of GH5188 superalloy. In the isothermal compression test, the relevant data of stress in the range of deformation temperature of 980~1230 ℃, strain rate of 0.01~10 ...
Effect of different vanadium and nitrogen contents on microstructure and properties of Nb-V microalloyed high-strength seismic reinforcement
Lu Jie, Su Qixiang, Huang Jixiang, Zhang Huanhuan, Lei Ting, Yin Shubiao, Ma Zhenghong
2023, 44(4): 149-157. doi: 10.7513/j.issn.1004-7638.2023.04.022
Abstract(334) HTML (79) PDF(23)
Abstract:
Vanadium and nitrogen can effectively improve the comprehensive performance of Nb-V microalloyed high strength seismic reinforcement. The microstructure of three kinds of Nb-V microalloyed high-strength seismic reinforcement bars with different vanadium and nitrogen contents was characterized and te...
Research progress of biodegradable iron-based materials for vascular stents
Xu Yanan, Wang Weiqiang, Yang Shuaikang, Wang Yinong
2023, 44(4): 158-166. doi: 10.7513/j.issn.1004-7638.2023.04.023
Abstract(611) HTML (83) PDF(57)
Abstract:
Iron-based biodegradable metal material is one of the most potential materials to replace permanent vascular stents. The slow degradation rate is the main problem hindering its development. Many researchers optimized its biocompatibility, corrosion and degradation behaviors, mechanical properties an...
Development and application of high strength complex phase steel HR680/800CP for automobile chassis
Tan Daqing, Zhou Li, Jia Guoxiang, Cao Xiao’en, Wen Caijun, Xue Renjie
2023, 44(4): 167-172. doi: 10.7513/j.issn.1004-7638.2023.04.024
Abstract(283) HTML (59) PDF(9)
Abstract:
Considering lightweight requirement and forming process characteristics of chassis structural parts, a complex alloying system of C-Si-Mn-Nb-Ti-Mo elements had been designed in order to achieve a better performance of weldability, second phase precipitation and bainite transformation at intermediate...
Study on deformation behavior and microstructure evolution at elevated temperatures of nickel based superalloy GH4065A
Shui Lang, Fu Jianhui
2023, 44(4): 173-182. doi: 10.7513/j.issn.1004-7638.2023.04.025
Abstract(343) HTML (74) PDF(23)
Abstract:
This paper performs thermal compression studies on GH4065A samples from a sample disk that is obtained from an industrial plant and has undergone VIM+ESR+VAR and homogenization. This study reveals the impact of thermal compression parameters such as deformation temperature, strain rate and engineeri...
Study on the composite inclusions of MnS-Al2O3 in wheel steel
Ding Xiaoming, Li Tao, Guo Xiaopei, Zhuang Qianyu, Liu Kai
2023, 44(4): 183-189. doi: 10.7513/j.issn.1004-7638.2023.04.026
Abstract(182) HTML (110) PDF(15)
Abstract:
The composite inclusions of MnS-Al2O3 in high-speed railway wheel steel can reduce the effect of Al2O3 on fatigue properties of wheel steel. In this study, the types of inclusions in wheel steel were determined as MnS, Al2O3 and MnS-Al2O3 composite inclusions by testing wheel steel prepared in labor...
Microstructure and properties of vanadium microalloyed cast magnesium alloy for automobile
Gao Yanan, Zheng Lei, Zhang Quanyu
2023, 44(4): 190-195. doi: 10.7513/j.issn.1004-7638.2023.04.027
Abstract(208) HTML (52) PDF(6)
Abstract:
In order to study the microstructure, wear resistance and corrosion resistance of vanadium microalloyed cast magnesium alloy for automobile, different contents of alloy element vanadium were added into the cast Mg-9Al-1Zn magnesium alloy, and the microstructure, wear resistance and corrosion resista...
Research on prediction accuracy of the flow stress of 0Cr17Ni4Cu4Nb stainless steel based on machine learning
Zhao Lidong, Zhang Youming, Zhang Jilin, Dou Jianming, Yao Jiabao
2023, 44(4): 196-204. doi: 10.7513/j.issn.1004-7638.2023.04.028
Abstract(217) HTML (83) PDF(5)
Abstract:
A new model for predicting rheological stresses based on particle swarm optimization BP neural network is proposed for 0Cr17Ni4Cu4Nb stainless steel as an example. Based on the quasi-static (0.001 s−1) compression testing data at room temperature and the impact testing data at four temperatures (25,...